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The electrostatic Schwinger-Dyson equations are derived and solved for an electrolyte mixture composed of mono- and multivalent ions confined to a negatively charged nanoslit. The closure of these equations is based on an asymmetric…

Soft Condensed Matter · Physics 2020-01-06 Sahin Buyukdagli

The recently developed modified Donnan (mD) model provides a simple and useful description of the electrical double layer in microporous carbon electrodes, suitable for incorporation in porous electrode theory. By postulating an attractive…

Chemical Physics · Physics 2014-01-22 P. M. Biesheuvel , S. Porada , M. Levi , M. Z. Bazant

Long-ranged attractions across water between two surfaces that are randomly covered with (mobile) positive and negative charge domains have been attributed to induced correlation of the charges (positive lining up with negative) as the…

Soft Condensed Matter · Physics 2012-10-30 Gilad Silbert , Dan Ben-Yaakov , Yael Dror , Susan Perkin , Nir Kampf , Jacob Klein

The electrostatic potential of a highly charged disc (clay platelet) in an electrolyte is investigated in detail. The corresponding non-linear Poisson-Boltzmann (PB) equation is solved numerically, and we show that the far-field behaviour…

Soft Condensed Matter · Physics 2009-11-10 R. Agra , E. Trizac , L. Bocquet

The charge distribution at the interface between two electrolytes is studied for the case of non-vanishing ion fluxes. The analysis is an extension of the established Verwey-Niessen theory to non-equilibrium situations. Applying matched…

Soft Condensed Matter · Physics 2011-05-03 Steffen Hardt , Tobias Baier

The interaction between surface patches of proteins with different surface properties has a vital role to play driving conformational changes of proteins in different salt solutions. We demonstrate the existence of ion-specific attractive…

Soft Condensed Matter · Physics 2012-01-06 Eduardo R. A. Lima , Mathias Boström , Nadine Schwierz , Bo E. Sernelius , Frederico W. Tavares

We investigate the effective interaction between two randomly charged but otherwise net-neutral, planar dielectric slabs immersed in an asymmetric Coulomb fluid containing a mixture of mobile monovalent and multivalent ions. The presence of…

Soft Condensed Matter · Physics 2016-01-25 Malihe Ghodrat , Ali Naji , Haniyeh Komaie-Moghaddam , Rudolf Podgornik

Interfacial properties of colloid--polymer mixtures are examined within an effective one--component representation, where the polymer degrees of freedom are traced out, leaving a fluid of colloidal particles interacting via polymer--induced…

Soft Condensed Matter · Physics 2007-05-23 A. Moncho-Jorda' , J. Dzubiella , J. P. Hansen , A. A. Louis

We investigate the effect of quenched surface charge disorder on electrostatic interactions between two charged surfaces in the presence of dielectric inhomogeneities and added salt. We show that in the linear weak-coupling regime (i.e., by…

Soft Condensed Matter · Physics 2007-05-23 Rudolf Podgornik , Ali Naji

We show that application of voltage between two electrically conducting bodies separated by a thin dielectric layer is equivalent to an adhesive contact with an effective separation energy depending quadratically on the applied stress.…

Soft Condensed Matter · Physics 2018-05-24 Valentin L. Popov , Markus Hess

Using integral equation theory of liquids to a binary mixed fluid lipid membrane, we study the membrane-mediated interactions between the macroions and the redistribution of neutral and charged lipids due to binding macroions. We find that…

Soft Condensed Matter · Physics 2015-06-25 Xia-qing Shi , Yu-qiang Ma

We study a classical system of identically charged counter-ions near a planar wall carrying a uniform surface charge density. The equilibrium statistical mechanics of the system depends on a single dimensionless coupling parameter. A new…

Soft Condensed Matter · Physics 2019-01-21 I. Palaia , M. Trulsson , L. Samaj , E. Trizac

There exists a generic relationship between the thermodynamics of a continuous polymer with a generic self-interaction and the two-point function of an interacting field-theory. In addition, the (2N)-point function of the resulting field…

chem-ph · Physics 2008-02-03 Bo Soderberg

According to conventional wisdom electric double-layer forces normally decay exponentially with separation distance. Here we present experimental evidence of algebraically decaying double-layer interactions. We show that algebraic…

Soft Condensed Matter · Physics 2020-01-01 Biljana Stojimirovic , Mark Vis , Remco Tuinier , Albert P. Philipse , Gregor Trefalt

In this paper, we study electrostatic properties between two similar or oppositely charged surfaces immersed in an electrolyte solution by using mean-field approach accounting for solvent polarization and non-uniform size effect. Applying a…

Soft Condensed Matter · Physics 2022-02-11 Jun-Sik Sin

We calculate theoretically the Coulomb drag resistivity for two graphene monolayers spatially separated by a distance "$d$". We show that the frictional drag induced by inter-layer electron-electron interaction goes asymptotically as…

Mesoscale and Nanoscale Physics · Physics 2012-01-04 E. H. Hwang , S. Das Sarma

We study two models of ringlike polyions which are two-dimensional versions of simple models for colloidal particles (model A) and for rodlike segments of DNA (model B), both in solution with counterions. The counterions may condensate on Z…

Statistical Mechanics · Physics 2009-11-07 Silvia Martins , Jurgen Stilck

Conditions at which a quasi-one-dimensional (1D) electron system can be considered as a quantum liquid of impenetrable charged particles are theoretically analyzed. In the presence of an inert, neutralizing background, a motion of…

Superconductivity · Physics 2024-06-21 Yu. P. Monarkha

The Poisson-Boltzmann equation for a strongly charged plate inside a generic charge-asymmetric electrolyte is solved using the method of asymptotic matching. Both near field and far field asymptotic behaviors of the potential are…

Soft Condensed Matter · Physics 2015-06-05 Ming Han , Xiangjun Xing

We theoretically calculate the interaction-induced frictional Coulomb drag resistivity between two graphene monolayers as well as between two graphene bilayers, which are spatially separated by a distance "$d$". We show that the drag…

Mesoscale and Nanoscale Physics · Physics 2011-12-23 E. H. Hwang , Rajdeep Sensarma , S. Das Sarma