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We investigate electro-osmosis in aqueous solutions of polyelectrolytes using mean-field equations. A solution of positively charged polyelectrolytes is confined between two negatively charged planar surfaces, and an electric field is…

Soft Condensed Matter · Physics 2015-06-16 Yuki Uematsu , Takeaki Araki

In this paper we report the theory describing the electro-osmotic flow in charged nanopores with constant radius and charge density driven by alternating current. We solve the ion and solution transport in unsteady conditions as described…

Chemical Physics · Physics 2018-10-17 J. Catalano , P. M. Biesheuvel

The electro-osmotic flow through a channel between two undulated surfaces induced by an external electric field is investigated. The gap of the channel is very small and comparable to the thickness of the electrical double layers. A lattice…

Soft Condensed Matter · Physics 2016-05-24 Hiroaki Yoshida , Tomoyuki Kinjo , Hitoshi Washizu

We introduce a theoretical and numerical method to investigate the properties of electro-osmotic flows under conditions of extreme confinement. The present approach, aiming to provide a simple modeling of electrolyte solutions described as…

Mesoscale and Nanoscale Physics · Physics 2015-05-28 Simone Melchionna , Umberto Marini Bettolo Marconi

Electroosmotic pumping of fluid through a nanopore that traverses an insulating membrane is considered. The density of surface charge on the membrane is assumed uniform, and sufficiently low for the Poisson-Boltzmann equation to be…

Fluid Dynamics · Physics 2014-05-15 M. Mao , J. D. Sherwood , S. Ghosal

Nonlinear electrokinetic phenomena, where electrically driven fluid flows depend nonlinearly on the applied voltage, are commonly encountered in aqueous suspensions of colloidal particles. A prime example is the induced-charge…

Soft Condensed Matter · Physics 2024-11-27 Zhanwen Wang , Michael J. Miksis , Petia M. Vlahovska

The movement of the particles in a capillary electrophoretic system under electroosmotic flow was modeled using Monte Carlo simulation with Metropolis algorithm. Two different cases, with repulsive and attractive interactions between…

Soft Condensed Matter · Physics 2021-10-26 Hakan Kaygusuz , F. Bedia Erim , A. Nihat Berker

We theoretically study transient electroosmotic flow of general Maxwell fluids through polyelectrolyte grafted nanochannel with a layered distribution of charges. By applying the method of Laplace transform, we semi-analytically obtain…

Soft Condensed Matter · Physics 2023-09-08 Jun-Sik Sin , Nam-Il Ri , Hyon-Chol Kim , Sin-Hyok Hyon

We revisit the classical problem of flow of electrolyte solutions through charged capillary nanopores or nanotubes as described by the capillary pore model (also called "space charge" theory). This theory assumes very long and thin pores…

Chemical Physics · Physics 2019-08-16 P. B. Peters , R. van Roij , M. Z. Bazant , P. M. Biesheuvel

We give a general theoretical description of electro-osmotic flow at striped super-hydrophobic surfaces in a thin double layer limit, and derive a relation between the electro-osmotic mobility and hydrodynamic slip-length tensors. Our…

Soft Condensed Matter · Physics 2015-05-27 Aleksey V. Belyaev , Olga I. Vinogradova

Advent of nematic liquid crystals flows have attracted renewed attention in view of microfluidic transport phenomena. Among various transport processes, electroosmosis stands as one of the efficient flow actuation method through narrow…

Fluid Dynamics · Physics 2017-08-02 Antarip Poddar , Jayabrata Dhar , Suman Chakraborty

The rectification of electro-osmotic flows is important in micro/nano fluidics applications such as micro-pumps and energy conversion devices. Here, we propose a simple electro-osmotic diode in which colloidal particles are contained…

Mesoscale and Nanoscale Physics · Physics 2021-10-04 Shihori Koyama , Daisuke Inoue , Akihisa Okada , Hiroaki Yoshida

Electroosmosis is a fascinating effect where liquid motion is induced by an applied electric field. Counter ions accumulate in the vicinity of charged surfaces, triggering a coupling between liquid mass transport and external electric…

In this paper, we present a molecular theory analysis of ions and potential distribution, degree of ionization of polyelectrolyte (PE) brushes, velocity profile, volumetric flow rate, ionic selectivity, ionic conduction and advection by…

Soft Condensed Matter · Physics 2020-07-01 Milad Reshadi , Mohammad Hassan Saidi

We show that an electric field parallel to an electrically neutral surface can generate flow of electrolytic mixtures in small channels. We term this solvo-osmotic flow, since the flow is induced by the asymmetric preferential solvation of…

Fluid Dynamics · Physics 2017-05-24 Sela Samin , René van Roij

We derive a mathematical model of a nematic electrolyte based on the Leslie-Ericksen theory of liquid crystal flow. Our goal is to investigate the nonlinear electrokinetic effects that occur because the nematic matrix is anisotropic, in…

Soft Condensed Matter · Physics 2016-06-07 M. Carme Calderer , Dmitry Golovaty , Oleg Lavrentovich , Noel J. Walkington

We experimentally demonstrate the phenomenon of electroosmotic dipole flow that occurs around a localized surface charge region under the application of an external electric field in a Hele-Shaw cell. We use localized deposition of…

Soft Condensed Matter · Physics 2019-06-12 Federico Paratore , Evgeniy Boyko , Govind V. Kaigala , Moran Bercovici

Electrolyte-filled channels with modulated wall charge distribution subjected to an applied DC electric field, form time-independent vortices whose sense of circulation is determined by the field direction [Physical Review Letters $…

Fluid Dynamics · Physics 2026-02-02 A. Shrestha , E. Kirkinis , M. Olvera de la Cruz

The optimal functioning of nanopore-based biosensing tools necessitates rapid polymer capture from the ion reservoir. We identify an ionic correlation-induced transport mechanism that provides this condition without the chemical…

Soft Condensed Matter · Physics 2018-05-10 Sahin Buyukdagli

Theoretically and experimentally, we study electroviscous phenomena resulting from charge-flow coupling in a nanoscale capillary. Our theoretical approach relies on Poisson-Boltzmann mean-field theory and on coupled linear relations for…

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