Related papers: Testing the Foundations of Classical Entropy: Coll…
Identical classical particles are distinguishable. This distinguishability affects the number of ways W a macrostate can be realized on the micro-level, and from the relation S = k ln W leads to a non-extensive expression for the entropy.…
Gibbs paradox in the context of statistical mechanics addresses the issue of additivity of entropy of mixing gases. The usual discussion attributes the paradoxical situation to classical distinguishability of identical particles and credits…
The ``Gibbs Paradox'' refers to several related questions concerning entropy in thermodynamics and statistical mechanics: whether it is an extensive quantity or not, how it changes when identical particles are mixed, and the proper way to…
The issue of the Gibbs paradox is that when considering mixing of two gases within classical thermodynamics, the entropy of mixing appears to be a discontinuous function of the difference between the gases: it is finite for whatever small…
The classical Gibbs paradox concerns the entropy change upon mixing two gases. Whether an observer assigns an entropy increase to the process depends on their ability to distinguish the gases. A resolution is that an "ignorant" observer,…
We develop the framework of classical Observational entropy, which is a mathematically rigorous and precise framework for non-equilibrium thermodynamics, explicitly defined in terms of a set of observables. Observational entropy can be seen…
The analysis of the arguments within the limits of the classical thermodynamics that lead to the Gibbs paradox was made. Features of preconditions used in the derivation of the entropy of mixing of ideal gases that caused the appearance of…
Based on a reconsideration of the Gibbs paradox, we show that a residual, non-extensive term in entropy turns up upon mixing identical particles, whether they are indistinguishable or not. The positive contribution from this residual…
The suggestion that particles of the same kind may be indistinguishable in a fundamental sense, even so that challenges to traditional notions of individuality and identity may arise, has first come up in the context of classical…
In classical Hamiltonian theories, entropy may be understood either as a statistical property of canonical systems, or as a mechanical property, that is, as a monotonic function of the phase space along trajectories. In classical mechanics,…
The Gibbs entropy of a macroscopic classical system is a function of a probability distribution over phase space, i.e., of an ensemble. In contrast, the Boltzmann entropy is a function on phase space, and is thus defined for an individual…
The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…
Indistinguishability of particles is normally considered to be an inherently quantum property which cannot be possessed by a classical theory. However, Saunders has argued that this is incorrect, and that classically indistinguishable…
The Gibbs paradox has frequently been interpreted as a sign that particles of the same kind are fundamentally indistinguishable; and that quantum mechanics, with its identical fermions and bosons, is indispensable for making sense of this.…
The Gibbs paradox is a conventional paradox in classical statistical mechanics, typically resolved by invoking quantum indistinguishability through the 1/N! correction. In this letter, we present a resolution within classical ensemble…
As first shown by H. S. Green in 1952, the entropy of a classical fluid of identical particles can be written as a sum of many-particle contributions, each of them being a distinctive functional of all spatial distribution functions up to a…
In this paper, we investigate and compare two well-developed definitions of entropy relevant for describing the dynamics of isolated quantum systems: bipartite entanglement entropy and observational entropy. In a model system of interacting…
Since its origin in the thermodynamics of the 19th century, the concept of entropy has also permeated other fields of physics and mathematics, such as Classical and Quantum Statistical Mechanics, Information Theory, Probability Theory,…
All entropy is entanglement entropy. This appears as the result of the existence of black holes. The origin of entropy and the way in which it defines the perceived time direction in macroscopic systems has been discussed and can be debated…
Classical linear wave superposition produces the appearance of interference. This observation can be interpreted in two equivalent ways: one can assume that interference is an illusion because input components remain unperturbed, or that…