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We report a Monte Carlo finite-size scaling study of the demixing transition of a symmetrical Lennard-Jones binary fluid mixture. For equal concentration of species, and for a choice of the unlike-to-like interaction ratio delta=0.7, this…

Statistical Mechanics · Physics 2009-11-10 Nigel B. Wilding

The present work is aimed at investigating the behavior of Morse fluids in the immediate vicinity of the critical point within the framework of a cell model. This region is of both fundamental and practical importance, yet presents…

Statistical Mechanics · Physics 2025-05-20 I. V. Pylyuk , M. P. Kozlovskii , R. V. Romanik

The equilibrium density distribution and thermodynamic properties of a Lennard-Jones fluid confined to nano-sized spherical cavities at constant chemical potential was determined using Monte Carlo simulations. The results describe both a…

Mesoscale and Nanoscale Physics · Physics 2010-04-27 James F. Lutsko , Julien Laidet , Patrick Grosfils

Molecular dynamics simulations of two-dimensional soft Yukawa fluids are performed to analyze the effect that the range of interaction has on coexisting densities and line tension. The attractive one-component fluid and equimolar mixtures…

Soft Condensed Matter · Physics 2012-07-16 G. A. Méndez-Maldonado , M. González-Melchor , J. Alejandre

A novel mathematical rigorous method to obtain the vapor-liquid equilibrium curves near the critical point has been proposed covering the cases of well-known and commonly used equations of state for real gases - Van der Waals and Dieterici,…

Statistical Mechanics · Physics 2015-11-03 Beata Staśkiewicz , Robert Stańczy

We have carried out extensive equilibrium molecular dynamics (MD) simulations to study the structure and the interfacial properties in the liquid-vapor (LV) phase coexistence of partially miscible binary Lennard-Jones (LJ) mixtures. By…

Soft Condensed Matter · Physics 2009-11-10 Enrique Díaz-Herrera , José A. Moreno-Razo , Guillermo Ramírez-Santiago

Kinetics of crystal-growth is investigated along the solid-liquid coexistence line for the (100), (110) and (111) orientations of the Lennard-Jones and Weeks-Chandler-Andersen fcc crystal-liquid interface, using non-equilibrium molecular…

Statistical Mechanics · Physics 2015-04-29 Ronald Benjamin , Jürgen Horbach

We study the kinetics of vapor-liquid and vapor-solid phase separation of a hydrodynamics preserving three-dimensional one component Lennard Jones system in the presence of external gravitational field using extensive molecular dynamic…

Soft Condensed Matter · Physics 2024-01-23 Daniya Davis , Bhaskar Sen Gupta

We analyze the interrelation between the coexistence curve of the Lennard-Jones fluid and the Ising model in two and three dimensions within the global isomorphism approach proposed earlier [V. L. Kulinskii, J. Phys. Chem. B \textbf{114}…

Statistical Mechanics · Physics 2013-04-26 Vladimir Kulinskii

We present a computer simulation study of a (6,12)-Lennard-Jones fluid confined to a slit pore, formed by two uniform planes. These interact via (3,9)-Lennard-Jones potential with the fluid particles. When the fluid approaches the…

Soft Condensed Matter · Physics 2009-02-20 N. Gribova , H. Maleki , A. Arnold , C. Holm , T. Schilling

The influence of the unlike Lennard-Jones (LJ) parameters on vapor-liquid equilibria of mixtures is investigated and the performance of eleven combining rules is assessed. In the first part of the work, the influence of the unlike LJ size…

Chemical Physics · Physics 2009-04-29 T. Schnabel , J. Vrabec , H. Hasse

The critical point affects the coexistence behavior of the vapor-liquid equilibrium densities. The length of the critical influence zone is under debate because for some properties, like shear viscosity, the extension is only a few degrees,…

Chemical Physics · Physics 2015-04-17 Jose Luis Rivera , Homero Nicanor-Guzman , Roberto Guerra-Gonzalez

Specialized Monte Carlo simulations and the moment free energy (MFE) method are employed to study liquid-gas phase equilibria in size-disperse fluids. The investigation is made subject to the constraint of fixed polydispersity, i.e. the…

Soft Condensed Matter · Physics 2009-11-10 Nigel B. Wilding , Moreno Fasolo , Peter Sollich

Molecular dynamics simulations of a Lennard-Jones binary mixture confined in a disordered array of soft spheres are presented. The single particle dynamical behavior of the glass former is examined upon supercooling. Predictions of mode…

Statistical Mechanics · Physics 2009-11-07 P. Gallo , R. Pellarin , M. Rovere

We report an extensive Monte Carlo study of critical end point behaviour in a symmetrical binary fluid mixture. On the basis of general scaling arguments, singular behaviour is predicted in the diameter of the liquid-gas coexistence curve…

Statistical Mechanics · Physics 2009-10-30 Nigel B. Wilding

We report the results of a molecular dynamics simulation of a supercooled binary Lennard-Jones mixture. By plotting the self intermediate scattering functions vs. rescaled time, we find a master curve in the $\beta$-relaxation regime. This…

Condensed Matter · Physics 2009-10-22 Walter Kob , Hans C. Andersen

A Theorem on the minimal specific energy for a system with \pm 1 charged particles interacting through the Yukawa pair potential v is proved which may stated as follows. Let v be represented by scale mixtures of d-dimensional Euclid's hat…

Mathematical Physics · Physics 2019-10-02 Wilhelm Kroschinsky , Domingos H. U. Marchetti

A molecular dynamics study of a two dimensional system of particles interacting through a Lennard-Jones pairwise potential is performed at fixed temperature and vanishing external pressure. As the temperature is increased, a solid-to-liquid…

Statistical Mechanics · Physics 2015-05-27 Daniel Asenjo , Fernando Lund , Simón Poblete , Rodrigo Soto , Marcos Sotomayor

Results for the kinetics of vapor-liquid transitions, following temperature quenches with different densities, are presented from the molecular dynamics simulations of a Lennard-Jones system. For critical density, bicontinuous liquid and…

Statistical Mechanics · Physics 2018-03-09 Sutapa Roy , Subir K. Das

Molecular dynamics simulations are used to examine the relationship between water-like anomalies and the liquid-liquid critical point in a family of model fluids with multi-Gaussian, core-softened pair interactions. The core-softened pair…

Soft Condensed Matter · Physics 2015-05-27 Evy Salcedo , Alan B. de Oliveira , Ney M. Barraz , Charusita Chakravarty , Marcia C. Barbosa