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Polycrystalline Sb 2 Te 3-x Se x (0.0 < x < 1.0) samples were synthesized by the solid state reaction method. The structural analysis showed that up to the maximal concentration of Se, the samples possess the Rhombohedral crystal symmetry…

Cu$_3$SbSe$_4$ is a promising thermoelectric material due to high thermopower ($>400\ \mu$V/K) at 300K and higher. Although it has a simple crystal structure derived from zinc blende structure, previous work has shown that the physics of…

Materials Science · Physics 2014-09-17 Dat T. Do , S. D. Manhanti

Thermoelectric materials, enabling the directing conversion between heat and electricity, are one of the promising candidates for overcoming environmental pollution and the upcoming energy shortage caused by the over-consumption of fossil…

Materials Science · Physics 2018-05-09 Min Hong , Zhi-Gang Chen , Jin Zou

The structures and thermoelectric properties of the (Bi2)m(Bi2Te3)n homologous series, derived from stacking hexagonal Bi2 and Bi2Te3 blocks, are reported. The end-members of this series are metallic Bi and semiconducting Bi2Te3; nine…

Materials Science · Physics 2009-11-13 J. W. G. Bos , H. W. Zandbergen , M. -H. Lee , N. P. Ong , R. J. Cava

The correlated couple of electrical and thermal property is the challenge to realize a substantial leap in thermoelectric materials.Synthesis of semiconductor and metal composites is a significant and versatile design strategy to optimize…

Applied Physics · Physics 2018-05-23 Wenwen Zheng , Peng Bi , Fengming Liu , Yong Liu , Jing Shi , Rui Xiong , Ziyu Wang

Defect engineering can improve the linked charge, spin, and lattice behavior of thermoelectric topological insulators. Using density functional theory with spin orbit coupling, we study structural, electronic, optical, thermoelectric,…

Materials Science · Physics 2025-12-15 Muhammad Usman Javed , Sikander Azam , Qaiser Rafiq , Hamdy Khamees Thabet

The potential of Fe2TiSn full-Heusler compounds for thermoelectric applications has been suggested theoretically, but not yet grounded experimentally, due to the difficulty of obtaining reproducible, homogeneous, phase pure and defect free…

(Bi1-xSbx)2Te3 (x=0.60, 0.65, 0.68, 0.70, 0.75 and 0.80) mixed crystals have been synthesized by solid state reaction. In depth structural, thermal, transport and electronic properties are reported. Defect and disorder play a crucial role…

Applied Physics · Physics 2021-08-03 K. Malik , S. Mahakal , Diptasikha Das , Aritra Banerjee , S. Chatterjee , Anusree Das

Materials with ring-shaped electronic bands are promising thermoelectric candidates, since their unusual dispersion shape is predicted to give large power factors. While previous calculations of these materials have relied on the assumption…

Mesoscale and Nanoscale Physics · Physics 2021-04-14 Cameron Rudderham , Jesse Maassen

Layered chalcogenides including Bi2Te3, Sb2Te3, Bi-Sb-Te ternary alloys and heterostructures are known as great thermoelectric, topological insulators and recently highlighted as plasmonic building blocks beyond noble metals. Here, we…

With a large band gap and a single Dirac cone responsible for the topological surface states, Bi2Se3 is widely regarded as a prototypical 3D topological insulator. Further applications of the bulk material has, however, been hindered by…

Materials Science · Physics 2023-06-02 Rodrigo T. Paulino , Marcos A. Avila

We report a strategy based on introduction of point defects for improving the thermoelectric properties of FeSb2, a promising candidate for low temperature applications. Introduction of Sb deficiency to the tune of 20% leads to enhancement…

Materials Science · Physics 2015-05-01 Anup V. Sanchela , Ajay D. Thakur , C. V. Tomy

We have investigated the effect of Sb-deficiency on the thermoelectric figure of merit (zT) of Zn4Sb3 prepared by solid state reaction route. At high temperatures, the Seebeck coefficient (S) and electrical conductivity ({\sigma}) increase…

Materials Science · Physics 2015-05-06 Anup V. Sanchela , Ajay D. Thakur , C. V. Tomy

The results of ultra-high vacuum low-temperature scanning-tunneling microscopy (STM) and spectroscopy (STS) of atomically clean (111) surface of the topological insulator Bi$_2$Se$_3$ are presented. We observed several types of new…

Mesoscale and Nanoscale Physics · Physics 2014-12-12 A. Yu. Dmitriev , N. I. Fedotov , V. F. Nasretdinova , S. V. Zaitsev-Zotov

The binary chalcogenides Bi2Te3 and Bi2Se3 are the most widely studied topological insulators. Although the quantum anomalous Hall effect has recently been observed in magnetically doped Sb2Te3 this compound has been studied to a much…

Mesoscale and Nanoscale Physics · Physics 2016-02-17 P. Sessi , O. Storz , T. Bathon , S. Wilfert , K. A. Kokh , O. E. Tereshchenko , G. Bihlmayer , M. Bode

Topological insulators embody a new state of matter characterized entirely by the topological invariants of the bulk electronic structure rather than any form of spontaneously broken symmetry. Unlike the 2D quantum Hall or quantum…

The growth and elementary properties of p-type Bi2Se3 single crystals are reported. Based on a hypothesis about the defect chemistry of Bi2Se3, the p-type behavior has been induced through low level substitutions (1 percent or less) of Ca…

Materials Science · Physics 2015-05-13 Y. S. Hor , A. Richardella , P. Roushan , Y. Xia , J. G. Checkelsky , A. Yazdani , M. Z. Hasan , N. P. Ong , R. J. Cava

The recent discovery of topological insulator (TI) offers new opportunities for the development of thermoelectrics, because many TIs (like Bi$_2$Te$_3$) are excellent thermoelectric (TE) materials. In this review, we will first describe the…

Materials Science · Physics 2016-10-26 Yong Xu

We have studied the electron transport properties of topological insulator-related material Bi2Se3 near the superconducting Pb-Bi2Se3 interface, and found that a superconducting state is induced over an extended volume in Bi2Se3. This state…

Superconductivity · Physics 2012-06-28 Fan Yang , Fanming Qu , Jie Shen , Yue Ding , Jun Chen , Zhongqing Ji , Guangtong Liu , Jie Fan , Changli Yang , Liang Fu , Li Lu

Thermoelectric (Bi1-x Sbx)2Te3 (BST-x) compounds with x=0.2, 0.7 and 0.9 have been studied using synchrotron angle-dispersive powder x-ray diffraction in a diamond anvil cell up to 25 GPa (at room temperature). The results clearly indicate…

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