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Bubble nucleation at catalyst surfaces plays a critical role in the operation of electrolyzers. However, achieving controlled bubble nucleation remains challenging due to limited understanding of the underlying mechanisms. Here, we present…

Soft Condensed Matter · Physics 2026-04-13 Qingguang Xie , Paolo Malgaretti , Othmane Aouane , Simon Thiele , Jens Harting

We provide a field-theoretical description of thermal nucleation in a one-dimensional ferromagnetic superfluid, a quantum-gas analogue of false-vacuum decay. The rate at which ground-state domains nucleate follows an Arrhenius law, with an…

Quantum Gases · Physics 2026-01-13 Enrique Rozas Garcia , Johannes Hofmann

Surface tension is a macroscopic manifestation of the cohesion of matter, and its value $\sigma_\infty$ is readily measured for a flat liquid-vapor interface. For interfaces with a small radius of curvature $R$, the surface tension might…

Chemical Physics · Physics 2016-02-04 Nicolas Bruot , Frédéric Caupin

The classical nucleation theory finds the rate of nucleation proportional to the monomer concentration raised to the power, which is the `critical nucleaus size', ${n_c}$. The implicit assumption, that amyloids nucleate in the same way, has…

Soft Condensed Matter · Physics 2020-05-19 Cheng-Tai Lee , Eugene M. Terentjev

Transient homogeneous nucleation is studied in the limit of large critical sizes. Starting from pure monomers, three eras of transient nucleation are characterized in the classic Becker-D\"oring kinetic equations with the Turnbull-Fisher…

Statistical Mechanics · Physics 2007-05-23 L. L. Bonilla , A. Carpio , Y. Farjoun , J. C. Neu

The standard vacuum bounce formalism suffers from inconsistencies when applied to thermal bubble nucleation, for which ad hoc workarounds are commonly adopted. Identifying the length scales on which nucleation takes place, we demonstrate…

High Energy Physics - Phenomenology · Physics 2021-12-09 Oliver Gould , Joonas Hirvonen

To calculate the temperature at which a first-order cosmological phase transition occurs, one must calculate $F_c(T)$, the free energy of a critical bubble configuration. $F_c(T)$ is often approximated by the classical energy plus an…

High Energy Physics - Phenomenology · Physics 2009-10-22 David Brahm , Clarence L. Y. Lee

The standard bounce formalism for calculating the decay rate of a metastable vacuum cannot be applied to theories in which the symmetry breaking is due to radiative corrections, because in such theories the tree-level action has no bounce…

High Energy Physics - Phenomenology · Physics 2009-10-22 Erick J. Weinberg

Modulating liquid-to-solid transitions and the resulting crystalline structure for tailored properties is much desired. Colloidal systems are exemplary to this end, but the fundamental knowledge gaps in relating the influence of…

Statistical Mechanics · Physics 2025-11-04 Porhouy Minh , Steven W. Hall , Ryan S. DeFever , Sapna Sarupria

Conditional elimination of degrees of freedom is shown to lead to an exact expression for the rate of turbulent energy dissipation in terms of a renormalized viscosity and a correction. The correction is neglected on the basis of a previous…

Condensed Matter · Physics 2009-10-31 C. Johnston , W. D. McComb

In cosmological first-order phase transitions, the progress of true-vacuum bubbles is expected to be significantly retarded by the interaction between the bubble wall and the hot plasma. It has been claimed that this leads to a significant…

High Energy Physics - Phenomenology · Physics 2009-11-07 Matthew Lilley , Antonio Ferrera

We study by computer simulation the nucleation of a supersaturated Lennard-Jones vapor into the liquid phase. The large free energy barriers to transition make the time scale of this process impossible to study by ordinary molecular…

Statistical Mechanics · Physics 2018-08-15 Pablo M. Piaggi , Omar Valsson , Michele Parrinello

In this article, we present direct numerical simulation results for the expansion of spherical cap bubbles attached to a rigid wall due to a sudden drop in the ambient pressure. The critical pressure drop beyond which the bubble growth…

Fluid Dynamics · Physics 2024-05-28 Mandeep Saini , Xiang Bin Chen , Stephane Zaleski , Daniel Fuster

We perform real-time hydrodynamical simulations of the growth of bubbles formed during cosmological first-order phase transitions under the assumption of local thermal equilibrium. We confirm that pure hydrodynamic backreaction can lead to…

Cosmology and Nongalactic Astrophysics · Physics 2024-05-08 Tomasz Krajewski , Marek Lewicki , Mateusz Zych

We examine the computation of the nucleation barrier used in the expression for false vacuum decay rates in finite temperature field theory. By a detailed analysis of the determinantal prefactor, we show that the correct bounce solution…

High Energy Physics - Phenomenology · Physics 2009-10-22 M. Gleiser , G. C. Marques , R. O. Ramos

We theoretically investigate homogeneous crystal nucleation in a solution containing a solute and a volatile solvent. The solvent evaporates from the solution, thereby continuously increasing the concentration of the solute. We view it as…

Soft Condensed Matter · Physics 2023-11-16 R. de Bruijn , J. J. Michels , P. van der Schoot

The conventional theory of homogeneous and heterogeneous nucleation in a supersaturated vapor is tested by Monte Carlo simulations of the lattice gas (Ising) model with nearest-neighbor attractive interactions on the simple cubic lattice.…

Soft Condensed Matter · Physics 2013-05-07 Fabian Schmitz , Peter Virnau , Kurt Binder

We present a consistent calculation of bubble-nucleation rates in theories of two scalar fields. Our approach is based on the notion of a coarse-grained free energy that incorporates the effects of fluctuations with momenta above a given…

High Energy Physics - Phenomenology · Physics 2009-10-09 Alessandro Strumia , Nikolaos Tetradis

In many systems, nucleation of a stable solid may occur in the presence of other (often more than one) metastable phases. These may be polymorphic solids or even liquid phases. In such cases, nucleation of the solid phase from the melt may…

Materials Science · Physics 2013-04-08 Mantu Santra , Rakesh S. Singh , Biman Bagchi

The theory of vapor bubbles nucleation in single-component liquids developed in [J. Phys. Chem. B 116, 9445 (2012)] for the case of high viscosity (the (V,/rho,T)- theory) is extended to the case of arbitrary viscosity. For this purpose,…

Soft Condensed Matter · Physics 2015-06-15 Nikolay V. Alekseechkin
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