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Particle dynamics in supercooled liquids are often dominated by string-like motions in which lines of particles perform activated hops cooperatively. The structural features triggering these motions, crucial in understanding glassy…

We introduce a coarse-grained model for atomic glass formers. Its elements are physically motivated local microscopic dynamical rules parameterized by observables. Results of the model are established and used to interpret the measured…

Statistical Mechanics · Physics 2009-11-10 Juan P. Garrahan , David Chandler

The dynamics of confined glassforming liquids is discussed on the basis of the recent extension of the mode coupling theory for the liquid-glass transition to the model of the quenched-annealed binary mixture. It is in particular shown…

Disordered Systems and Neural Networks · Physics 2007-05-23 V. Krakoviack

The Random First Order Transition (RFOT) theory of glasses provides a unified framework for explaining the observed correlations of the kinetic and thermodynamic behaviors of glass-forming liquids having a wide variety of chemical…

Soft Condensed Matter · Physics 2025-07-29 M. H. Brown , P. G. Wolynes

We perform molecular-dynamics simulations of a molecular system in supercooled states for different values of inertia parameters to provide evidence that the long-time dynamics depends only on the equilibrium structure. This observation is…

Soft Condensed Matter · Physics 2009-11-10 S. -H. Chong , F. Sciortino

We study theoretically and numerically a family of multi-point dynamic susceptibilities that quantify the strength and characteristic lengthscales of dynamic heterogeneities in glass-forming materials. We use general theoretical arguments…

We propose that the dynamics of supercooled liquids and the formation of glasses can be understood from the existence of a zero temperature dynamical critical point. To support our proposal, we derive from simple physical assumptions a…

Soft Condensed Matter · Physics 2009-11-10 Stephen Whitelam , Ludovic Berthier , Juan P. Garrahan

We assess the validity of "microscopic" approaches of glass-forming liquids based on the sole k nowledge of the static pair density correlations. To do so we apply them to a benchmark provided by two liquid models that share very similar…

Statistical Mechanics · Physics 2011-10-10 Ludovic Berthier , Gilles Tarjus

Glass formers exhibit a viscoelastic behavior: at the laboratory timescale, they behave like (glassy) solids at low temperatures, and like liquids at high temperatures. Based on this observation, elastic models relate the long time…

Chemical Physics · Physics 2017-08-01 Emmanuel Guillaud , Laurent Joly , Dominique De Ligny , Samy Merabia

An equilibrated model glass-forming liquid is studied by mapping successive configurations produced by molecular dynamics simulation onto a time series of inherent structures (local minima in the potential energy). Using this ``inherent…

Soft Condensed Matter · Physics 2012-03-27 Thomas B. Schroeder , Srikanth Sastry , Jeppe C. Dyre , Sharon C. Glotzer

We compare dynamical heterogeneities in equilibrated supercooled liquids and in the nonequilibrium glassy state within the framework of the random first order transition theory. Fluctuating mobility generation and transport in the glass are…

Statistical Mechanics · Physics 2014-01-21 Apiwat Wisitsorasak , Peter G. Wolynes

Theoretical challenges in understanding the nature of glass and the glass transition remain significant open questions in statistical and condensed matter physics. As a prototypical example of complex physical systems, glasses and the…

Disordered Systems and Neural Networks · Physics 2026-01-21 Xin-Jia Zhou , Feng Yang , Xiao-Dong Yang , Lin Ma , Zhen-Wei Wu

We explore the glassy dynamics of soft colloids using microgels and charged particles interacting by steric and screened Coulomb interactions, respectively. In the supercooled regime, the structural relaxation time $\tau_\alpha$ of both…

Glass-like materials are nonequilibrium systems where the relaxation time may exceed reasonable time scales of observations. In the present paper a dynamic percolation model is introduced in order to explain the principal properties of…

Condensed Matter · Physics 2007-05-23 A. Vazquez , O. Sotolongo-Costa

The understanding of thermodynamic glass transition has been hindered by the lack of proper models beyond mean-field theories. Here, we propose a three-dimensional lattice glass model on a simple cubic lattice that exhibits the typical…

Statistical Mechanics · Physics 2020-08-07 Yoshihiko Nishikawa , Koji Hukushima

The existence of heterogeneity in the dynamics of supercooled liquids is believed to be one of the hallmarks of the glass transition. Intense research has been carried out in the past to understand the origin of this heterogeneity in…

Soft Condensed Matter · Physics 2020-07-01 Indrajit Tah , Smarajit Karmakar

The random first-order transition (RFOT) theory of the structural glass transition is reviewed in a pedagogical fashion. The rigidity that emerges in crystals and glassy liquids is of the same fundamental origin. In both cases, it…

Disordered Systems and Neural Networks · Physics 2015-11-20 Vassiliy Lubchenko

We use event driven simulations to analyze glassy dynamics as a function of density and energy dissipation in a two-dimensional bidisperse granular fluid under stationary conditions. Clear signatures of a glass transition are identified,…

Statistical Mechanics · Physics 2011-10-05 Iraj Gholami , Andrea Fiege , Annette Zippelius

In molecular liquids such as water, time-delayed influences between microscopic or mesoscopic variables are typically probed using time-correlation functions, which are symmetric under detailed balance and therefore blind to dynamical…

Chemical Physics · Physics 2026-04-22 Leon Huet , Vittorio Del Tatto , Debarshi Banerjee , Alessandro Laio , Ali A. Hassanali

The understanding of glassy dynamics above the devitrification temperature of a glass remains poorly understood. Here, we use real-time AFM imaging to build a spatio-temporal map of the relaxation dynamics of a highly stable glass into its…

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