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Combining density functional theory (DFT) and embedded dynamical mean-field theory (DMFT) methods, we study the metal-insulator transition in $R_2$Ir$_2$O$_7$ ($R$=Y, Eu, Sm, Nd, Pr, and Bi) and the topological nature of the insulating…

Strongly Correlated Electrons · Physics 2017-01-18 Hongbin Zhang , Kristjan Haule , David Vanderbilt

The one-particle reduced density-matrix (1-RDM) functional theory is a promising alternative to density-functional theory (DFT) that uses the 1-RDM rather than the electronic density as a basic variable. However, long-standing challenges…

Quantum Physics · Physics 2024-08-20 Matthieu Vladaj , Quentin Marécat , Bruno Senjean , Matthieu Saubanère

Spin-orbit coupling has been reported to be responsible for the insulating nature of the 5d$^1$ osmate double perovskite Ba$_2$NaOsO$_6$ (BNOO). However, whether spin-orbit coupling indeed drives the metal-to-insulator transition (MIT) in…

Strongly Correlated Electrons · Physics 2024-01-17 Dario Fiore Mosca , Hermann Schnait , Lorenzo Celiberti , Markus Aichhorn , Cesare Franchini

We present a muon spin relaxation study of the Mott transition in BaCoS_2 using two independent control parameters: (i) pressure p to tune the electronic bandwidth and (ii) Ni-substitution x on the Co site to tune the band filling. For both…

Motivated by the puzzling report of the observation of a ferromagnetic insulating state in LaMnO$_3$/SrTiO$_3$ heterostructures, we calculate the electronic and magnetic state of LaMnO$_3$, coherently matched to a SrTiO$_3$ square substrate…

Materials Science · Physics 2019-09-25 Hrishit Banerjee , Oleg Janson , Karsten Held , Tanusri Saha-Dasgupta

Achieving the full understanding and control of the insulator-to-metal transition in Mott materials is key for the next generation of electronics devices, with applications ranging from ultrafast transistors, volatile and non-volatile…

Strongly Correlated Electrons · Physics 2024-10-02 Alessandra Milloch , Michele Fabrizio , Claudio Giannetti

The insulator-bad metal transition observed in the Jahn-Teller (JT) magnets orthonickelates RNiO$_3$ (R = rare earth or yttrium Y) is considered to be a canonical example of the Mott transition, traditionally described in the framework of…

Strongly Correlated Electrons · Physics 2025-08-12 A. S. Moskvin

We study the effects of electronic correlations on fragile topology using dynamical mean-field theory. Fragile topological insulators (FTIs) offer obstruction to the formation of exponentially localized Wannier functions, but they can be…

Strongly Correlated Electrons · Physics 2021-04-28 Ashish Joshi , Robert Peters

Multi-configurational wave-function theory (MC-WFT) that combines complete active space self-consistent field (CASSCF) approach with subsequent state interaction (SI) treatment of spin-orbit coupling (SOC), abbreviated as CASSCF-SO, plays…

Chemical Physics · Physics 2025-03-11 Zhe-Bin Guan , Hong Jiang

In Mott insulators the evolution of antiferromagnetic order to superconducting or charge-density-wave-like states upon chemical doping underpins the control of quantum phases. Photo-doping can induce similar transitions on the ultrafast…

While the phase diagrams of the one- and multi-orbital Hubbard model have been well studied, the physics of real Mott insulators is often much richer, material dependent, and poorly understood. In the prototype Mott insulator…

Strongly Correlated Electrons · Physics 2018-09-06 Frank Lechermann , Noam Bernstein , I. I. Mazin , Roser Valentí

We address the concomitant metal-insulator transition (MIT) and antiferromagnetic ordering in the novel pyrochlore iridate Eu2Ir2O7 by combining x-ray absorption spectroscopy, x-ray and neutron diffractions and density functional theory…

Unusual metallic states involving breakdown of the standard Fermi-liquid picture of long-lived quasiparticles in well-defined band states emerge at low temperatures near correlation-driven Mott transitions. Prominent examples are…

Materials Science · Physics 2018-11-14 L. Craco , M. S. Laad , S. Leoni

In two-dimensional van der Waals magnetic materials, the interplay between magnetism and electron correlation can give rise to new ground states and lead to novel transport and optical properties. A fundamental question in these materials…

Achieving fundamental understanding of insulator-to-metal transitions (IMTs) in strongly correlated systems and their persistent and reversible control via nonequilibrium drive are prime targets of current condensed matter research.…

Strongly Correlated Electrons · Physics 2022-11-29 K. S. Rabinovich , A. N. Yaresko , R. D. Dawson , M. J. Krautloher , T. Priessnitz , Y. -L. Mathis , B. Keimer , A. V. Boris

Density Functional Theory (DFT) has become a cornerstone in the modeling of metals. However, accurately simulating metals, particularly under extreme conditions, presents two significant challenges. First, simulating complex metallic…

Chemical Physics · Physics 2024-03-08 Jake P. Vu , Ming Chen

Electron correlation and long-range magnetic ordering have a significant impact on the electronic structure and physical properties of solids. Here, we investigate the electronic structure of ilmenite MnTiO$_{3}$ using room temperature…

Strongly Correlated Electrons · Physics 2025-06-13 Asif Ali , R. K. Maurya , Sakshi Bansal , B. H. Reddy , Ravi Shankar Singh

Electrons in zero external magnetic field can be studied with density functional theory (DFT) or with spin-DFT (SDFT). The latter is normally used for open shell systems because its approximations appear to model better the exchange and…

Chemical Physics · Physics 2022-04-06 Timothy Callow , Benjamin Pearce , Nikitas Gidopoulos

The existence of band gaps in Mott insulators such as perovskite oxides with partially filled 3d shells has been traditionally explained in terms of strong, dynamic inter-electronic repulsion codified by the on-site repulsion energy U in…

Materials Science · Physics 2019-07-24 Julien Varignon , Manuel Bibes , Alex Zunger

We develop a real space theory of the voltage bias driven transition from a Mott insulator to a correlated metal. Within our Keldysh mean field approach the problem reduces to a self-consistency scheme for the charge and spin profiles in…

Strongly Correlated Electrons · Physics 2020-07-01 Arijit Dutta , Pinaki Majumdar