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We aim to understand how the van der Waals force between neutral adatoms and a graphene layer is modified by uniaxial strain and electron correlation effects. A detailed analysis is presented for three atoms (He, H, and Na) and graphene…

Mesoscale and Nanoscale Physics · Physics 2016-05-11 Nathan S. Nichols , Adrian Del Maestro , Carlos Wexler , Valeri N. Kotov

Quantum coherence and control is foundational to the science and engineering of quantum systems. In van der Waals (vdW) materials, the collective coherent behavior of carriers has been probed successfully by transport measurements. However,…

Van der Waals (vdW) heterostructures host many-body quantum phenomena that can be tuned in situ using electrostatic gates. These gates are often microstructured graphite flakes that naturally form plasmonic cavities, confining light in…

For the moment, there is no exact description of van der Waals (vdW) interactions. ACFD-RPA \cite{Gould1} is expected to better describe vdW bonding, but it is not exact. The PBE/DFT-D2 method is less satisfactory, however, its results are…

Materials Science · Physics 2014-07-15 Xiaobin Chen , Fuyang Tian , Clas Persson , Wenhui Duan , Nanxian Chen

Two dimensional layered van der Waals (vdW) magnets have demonstrated their potential to study both fundamental and applied physics due to their remarkable electronic properties. However, the connection of vdW magnets to spintronics as well…

Mesoscale and Nanoscale Physics · Physics 2021-09-01 H. Y. Yuan , Akashdeep Kamra , Dion M. F. Hartmann , Rembert A. Duine

The confinement of molecules within the van der Waals (vdW) gap between a two-dimensional 2D material and a catalytic substrate offers a promising route toward the development of molecule-selective catalysts with increased reaction rates.…

The DFT/vdW-WF2s1 method based on the generation of localized Wannier functions, recently developed to include the van der Waals interactions in the Density Functional Theory and describe adsorption processes on metal surfaces by taking…

Chemical Physics · Physics 2016-04-06 Pier Luigi Silvestrelli , Alberto Ambrosetti

The van der Waals (vdW) interactions exist in reality universally and play an important role in physics. Here, we show the study on the mechanism of vdW interactions on phonon transport in atomic scale, which would boost developments in…

Mesoscale and Nanoscale Physics · Physics 2021-01-13 Xiaoxiang Yu , Dengke Ma , Chengcheng Deng , Xiao Wan , Meng An , Han Meng , Xiaobo Li , Xiaoming Huang , Nuo Yang

Dispersion interactions such as the van der Waals interaction between atoms or molecules derive from quantum fluctuations of the electromagnetic field and can be understood as the exchange of virtual photons between the interacting…

Quantum Physics · Physics 2015-06-11 Harald R. Haakh , Stefan Scheel

Dynamic wavelength tunability has long been the holy grail of photodetector technology. Because of its atomic thickness and unique properties, graphene opens up new paradigms to realize this concept, but so far this has been elusive…

Mesoscale and Nanoscale Physics · Physics 2017-03-08 François Léonard , Catalin D. Spataru , Michael Goldflam , David W. Peters , Thomas E. Beechem

Electrochemical intercalation is a powerful method for tuning the electronic properties of layered solids. In this work, we report an electro-chemical strategy to controllably intercalate lithium ions into a series of van der Waals (vdW)…

Graphene sandwiched between semiconducting monolayers of ferromagnet Cr$_2$Ge$_2$Te$_6$ and transition-metal dichalcogenide WS$_2$ acquires both spin-orbit (SO), of valley-Zeeman and Rashba types, and exchange couplings. Using…

Mesoscale and Nanoscale Physics · Physics 2020-10-14 Klaus Zollner , Marko D. Petrovic , Kapildeb Dolui , Petr Plechac , Branislav K. Nikolic , Jaroslav Fabian

A simple and computationally efficient scheme to calculate approximate imaginary-frequency dependent polarizability, hence asymptotic van der Waals coefficient, within density functional theory is proposed. The dynamical dipolar…

Materials Science · Physics 2009-04-20 Huy-Viet Nguyen , Stefano de Gironcoli

Interfacial adhesion between graphene and a SiO2 substrate is studied by density functional theory (DFT) with dispersion corrections. The results demonstrate the van der Waals (vdW) interaction as the predominate mechanism for the…

Materials Science · Physics 2015-06-19 Wei Gao , Penghao Xiao , Graeme Henkelman , Kenneth M. Liechti , Rui Huang

It is shown that it is now possible to include van der Waals interactions via a nonempirical implementation of density functional theory to describe the correlation energy in electronic structure calculations on infinite systems of no…

Materials Science · Physics 2009-11-11 Svetla D. Chakarova Kack , Elsebeth Schroder , Bengt I. Lundqvist , David C. Langreth

We present a new scheme to include the van der Waals (vdW) interactions in approximated Density Functional Theory (DFT) by combining the Quantum Harmonic Oscillator model with the Maximally Localized Wannier Function technique. With respect…

Materials Science · Physics 2015-06-16 Pier Luigi Silvestrelli

The DFT/vdW-WF2s1 method, recently developed to include the van der Waals interactions in the Density Functional Theory and describe adsorption processes on metal surfaces by taking metal-screening effects into account, is applied to the…

Materials Science · Physics 2015-06-11 Pier Luigi Silvestrelli , Alberto Ambrosetti

Large area van der Waals (vdW) thin films are assembled materials consisting of a network of randomly stacked nanosheets. The multi-scale structure and the two-dimensional nature of the building block mean that interfaces naturally play a…

Strongly correlated materials possess a complex energy landscape and host many interesting physical phenomena, including charge density waves (CDWs). CDWs have been observed and extensively studied in many materials since their first…

Materials Science · Physics 2020-09-14 Weijian Li , Gururaj V. Naik

Accurate modeling of electronic and structural properties of organic molecule-metal interfaces are challenging problems because of the complicated electronic distribution of molecule and screening of charges at the metallic surface. This is…

Materials Science · Physics 2019-07-24 Abhirup Patra , Adrienn Ruzsinszky