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Recent experimental observations of time-dependent beatings in the two-dimensional echo-spectra of light-harvesting complexes at ambient temperatures have opened up the question whether coherence and wave-like behaviour plays a significant…

Biological Physics · Physics 2012-02-08 Birgit Hein , Christoph Kreisbeck , Tobias Kramer , Mirta Rodríguez

Recently, the coherent modified Redfield theory (CMRT) has been widely used to simulate the excitation-energy-transfer (EET) processes in photosynthetic systems. However, the numerical simulation of the CMRT is computationally expensive…

Chemical Physics · Physics 2025-11-24 Rui Li , Yi Li , Kai-Ya Zhang , Qing Ai

We present a detailed theoretical study of the transfer of electronic excitation energy through the Fenna-Matthews-Olson (FMO) pigment-protein complex, using the new developed modified scaled hierarchical approach [Shi Q. et al, J Chem Phys…

Chemical Physics · Physics 2011-03-17 Jing Zhu , Sabre Kais , Patrick Rebentrost , Alán Aspuru-Guzik

The accuracy of approximate methods for calculating linear optical spectra depends on many variables. In this study, we fix most of these parameters to typical values found in photosynthetic light-harvesting complexes of plants and…

Chemical Physics · Physics 2022-09-21 J. A. Nöthling , Tomáš Mančal , T. P. J. Krüger

We propose a trajectory-based quasiclassical method for approximating dynamics in condensed phase systems. Building upon the previously developed Optimized Mean Trajectory (OMT) approximation that has been used to compute linear and…

Chemical Physics · Physics 2024-08-23 Kritanjan Polley

We have developed an effective mathematical model to calculate the coherent population trapping (CPT) resonance in periodically modulated light, when the modulation frequency $f$ varies near the fractional part of hyperfine splitting in the…

Atomic Physics · Physics 2025-05-29 V. I. Yudin , M. Yu. Basalaev , A. V. Taichenachev , O. N. Prudnikov

We theoretically investigate polarization-filtered two-photon correlations for the light emitted by a multichromophoric system undergoing excitation transport under realistic exciton-phonon interactions, and subject to continuous incoherent…

Chemical Physics · Physics 2024-04-29 Charlie Nation , Hallmann Oskar Gestsson , Alexandra Olaya-Castro

The idea that excitonic state (electronic) coherences are of fundamental importance to natural photosynthesis gained popularity when, a decade ago, slowly dephasing quantum beats were observed in the two-dimensional electronic spectra of…

Mean-field molecular dynamics based on path integrals is used to approximate canonical quantum observables for particle systems consisting of nuclei and electrons. A computational bottleneck is the sampling from the Gibbs density of the…

Numerical Analysis · Mathematics 2023-11-30 Xin Huang , Petr Plechac , Mattias Sandberg , Anders Szepessy

Linear-response quantum electrodynamical density functional theory (QEDFT) enables the description of molecular spectra under strong coupling to quantized photonic modes, such as those in optical cavities. Recently, this approach was…

Chemical Physics · Physics 2025-07-11 Lukas Konecny , Valeriia P. Kosheleva , Michael Ruggenthaler , Michal Repisky , Angel Rubio

The dynamical mean field theory (DMFT) has become a standard technique for the study of strongly correlated models and materials overcoming some of the limitations of density functional approaches based on local approximations. An important…

Strongly Correlated Electrons · Physics 2015-10-28 K. Hallberg , D. J. García , Pablo S. Cornaglia , Jorge I. Facio , Y. Núñez-Fernández

We compare the performance of an approach using real frequency dependent polarizability to compute optical absorption spectra to linear-response time-dependent density functional theory (TD-DFT) for small organic dyes, oligomers of…

Materials Science · Physics 2018-05-22 Ang Siong Tuan , Amrita Pal , Sergei Manzhos

Conventional cell tracking methods detect multiple cells in each frame (detection) and then associate the detection results in successive time-frames (association). Most cell tracking methods perform the association task independently from…

Computer Vision and Pattern Recognition · Computer Science 2020-02-27 Junya Hayashida , Kazuya Nishimura , Ryoma Bise

We introduce an almost analytical method to simulate 2D electronic spectra as a double Fourier transform of the the non-linear response function (NRF) corresponding to a particular optical pulse sequence. We employ a unitary transformation…

Quantum Physics · Physics 2017-05-18 Pallavi Bhattacharyya , Nandini Ananth

The primary steps of photosynthesis rely on the generation, transport, and trapping of excitons in pigment-protein complexes (PPCs). Generically, PPCs possess highly structured vibrational spectra, combining many discrete intra-pigment…

Chemical Physics · Physics 2022-06-07 F. Caycedo-Soler , A. Mattioni , J. Lim , T. Renger , S. F. Huelga , M. B. Plenio

We employ two-dimensional (2D) coherent, nonlinear spectroscopy to investigate couplings within individual InAs quantum dots (QD) and QD molecules. Swapping pulse ordering in a two-beam sequence permits to distinguish between rephasing and…

We introduce a computational framework leveraging universal machine learning interatomic potentials (MLIPs) to dramatically accelerate the calculation of photoluminescence (PL) spectra of atomic or molecular emitters with ab initio…

A remarkable amount of theoretical research has been carried out to elucidate the physical origins of the recently observed long-lived quantum coherence in the electronic energy transfer process in biological photosynthetic systems.…

Quantum Physics · Physics 2015-03-19 Sangwoo Shim , Patrick Rebentrost , Stéphanie Valleau , Alan Aspuru-Guzik

Methods to efficiently determine the relative stability of polymorphs of organic crystals are highly desired in crystal structure predictions (CSPs). Current methodologies include use of static lattice phonons, quasi-harmonic approximation…

Materials Science · Physics 2020-06-08 Nathan S. Abraham , Michael R. Shirts

Double excitations are crucial to understanding numerous chemical, physical, and biological processes, but accurately predicting them remains a challenge. In this work, we explore the particle-particle random phase approximation (ppRPA) as…

Chemical Physics · Physics 2024-11-26 Jincheng Yu , Jiachen Li , Tianyu Zhu , Weitao Yang
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