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We present an example counter to the widely-accepted concept on equilibrium states that "Any thermodynamic equilibrium state of two component systems is determined by specifying 4 thermodynamic variables that include at least 1 extensive…

Soft Condensed Matter · Physics 2018-05-16 Yuki Norizoe , Toshihiro Kawakatsu

Typically, the entropy of an isolated system in equilibrium is calculated by counting the number of accessible microstates, or in more general cases by using the Gibbs formula. In irreversible processes entropy spontaneously increases and…

Statistical Mechanics · Physics 2020-04-16 Taha A Malik , Rafael Lopez-Mobilia

A thermo field dynamics approach for calculating the entropy of a spacetime is suggested. It is exemplified through the Rindler spacetime, the Milne spacetime, the Boulware spacetime, and the Minkowski spacetime with a moving mirror that…

General Relativity and Quantum Cosmology · Physics 2015-11-03 Yu-Zhu Chen , Wen-Du Li , Wu-Sheng Dai

Thermodynamics is a science concerning the state of a system, whether it is stable, metastable, or unstable. The combined law of thermodynamics derived by Gibbs about 150 years ago laid the foundation of thermodynamics. In Gibbs combined…

Statistical Mechanics · Physics 2023-08-03 Zi-Kui Liu

The presented paper is an attempt to investigate the dynamical states of an hydrodynamical isothermal turbulent self-gravitating system using some powerful tools of the classical thermodynamics. Our main assumption, inspired by the work of…

Astrophysics of Galaxies · Physics 2023-11-21 Sava Donkov , Ivan Zh. Stefanov , Todor V. Veltchev

This work examines some aspects related to the existence of negative mass. The requirement for the partition function to converge leads to two distinct approaches. Initially, convergence is achieved by assuming a negative absolute…

Statistical Mechanics · Physics 2026-02-25 S. D. Campos

Using a minimal algebraic model for the thermodynamics of binary rod--polymer mixtures, we provide evidence for a quintuple phase equilibrium; an observation that seems to be at odds with the Gibbs phase rule for two-component systems. Our…

Soft Condensed Matter · Physics 2020-09-21 V. F. D. Peters , M. Vis , Á. González García , H. H. Wensink , R. Tuinier

The comparison of geometrical properties of black holes with classical thermodynamic variables reveals surprising parallels between the laws of black hole mechanics and the laws of thermodynamics. Since Hawking's discovery that black holes…

History and Philosophy of Physics · Physics 2019-03-18 Carina E. A. Prunkl , Christopher G. Timpson

To the student of thermodynamics the most difficult subject is entropy. In this paper we examine the actual, practical application of entropy to two simple systems, the homogeneous slab with fixed boundary values of the temperature, and an…

Statistical Mechanics · Physics 2015-05-28 Christian Frønsdal , Abhishek Pathak

Based on statistical mechanics, a macroscopically homogeneous system, i.e., a single phase in the present context, is composed of many independent configurations that the system embraces. The macroscopical properties of the system are…

Statistical Mechanics · Physics 2024-02-07 Zi-Kui Liu , Nigel L. E. Hew , Shun-Li Shang

We define, by an integral of geometric quantities over a spherical shell of arbitrary radius, an invariant gravitational entropy. This definition relies on defining a gravitational energy and pressure, and it reduces at the horizon of both…

High Energy Physics - Theory · Physics 2015-06-03 Ram Brustein , A. J. M. Medved

It is argued that a typical many body energy eigenstate has a well defined thermodynamic entropy and that individual eigenstates possess thermodynamic characteristics analogous to those of generic isolated systems. We examine large systems…

Statistical Mechanics · Physics 2015-05-14 J. M. Deutsch

By assuming an appropriate energy composition law between two systems governed by the same non-extensive entropy, we revisit the definitions of temperature and pressure, arising from the zeroth principle of thermodynamics, in a manner…

Statistical Mechanics · Physics 2015-05-18 A. M. Scarfone

We show that states of macroscopic systems with purported absolute negative temperatures are not stable under small, yet arbitrary, perturbations. We prove the previous statement using the fact that, in equilibrium, the entropy takes its…

Statistical Mechanics · Physics 2013-08-30 Victor Romero-Rochin

Recently, it was argued (Eur. Phys. J. C {\bf73}, 2487 (2013)) that the total entropy of a gravitational system should be related to the volume of system instead of the system surface. Here, we show that this new proposal cannot satisfy the…

General Relativity and Quantum Cosmology · Physics 2016-05-17 H. Moradpour

Entropy can signify different things: For instance, heat transfer in thermodynamics or a measure of information in data analysis. Many entropies have been introduced and it can be difficult to ascertain their different importance and…

Mathematical Physics · Physics 2025-07-10 Henrik Jeldtoft Jensen , Piergiulio Tempesta

We extend on ideas from standard thermodynamics to show that temperature can be assigned to a general nonequilibrium quantum system. By choosing a physically motivated complete set of observables and expanding the system state thereupon,…

Quantum Physics · Physics 2021-05-26 S. Alipour , F. Benatti , M. Afsary , F. Bakhshinezhad , M. Ramezani , T. Ala-Nissila , A. T. Rezakhani

In an attempt to derive thermodynamics from classical mechanics, an approximate expression for the equilibrium temperature of a finite system has been derived [M. Bianucci, R. Mannella, B. J. West, and P. Grigolini, Phys. Rev. E 51, 3002…

Statistical Mechanics · Physics 2015-06-24 Artur B. Adib

Our previous works have shown the statistical mechanics of self-gravitating system. In this paper, we will show its thermodynamics and compare our results with observations and simulations. We propose that our statistical mechanics can be…

Cosmology and Nongalactic Astrophysics · Physics 2011-12-30 Dong-Biao Kang

We study spacetime thermodynamics for non-equilibrium processes. We first generalize the formulation of spacetime thermodynamics by using an observer outside the horizon. Then we construct the entropy balance equation of spacetime…

High Energy Physics - Theory · Physics 2015-05-28 Yuki Yokokura