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A calorimeter was built to measure the heat from a porous capacitive working electrode connected in a three-electrode configuration. This makes it possible to detect differences between cathodic and anodic heat production. The…

Instrumentation and Detectors · Physics 2022-12-09 Joren E. Vos , Hendrik P. Rodenburg , Danny Inder Maur , Ties J. W. Bakker , Henkjan Siekman , Ben H. Erné

Aqueous rechargeable batteries are promising energy storage devices for the high safety, environmental friendliness, and easy assembly. However, their cycle stability and low temperature performance are limited by the narrow electrochemical…

Chemical Physics · Physics 2022-06-17 Yuewang Yang , Sijing Liu , Zhaowen Bai , Baoling Huang

Supercapacitors are electric devices able to deliver a large power, enabling their use e.g. for the recovery of breaking energy in cars. This is achieved by using two carbon electrodes and an electrolyte solution or a pure ionic liquid…

Chemical Physics · Physics 2018-11-26 Céline Merlet , Clarisse Péan , Mathieu Salanne , Benjamin Rotenberg

Nanoporous carbon-based supercapacitors store electricity through adsorption of ions from the electrolyte at the surface of the electrodes. Room temperature ionic liquids, which show the largest ion concentrations among organic liquid…

Half of the energy is always lost when charging a capacitor. Even in the limit of vanishing resistance, half of the charging energy is still lost--to radiation instead of heat. While this fraction can technically be reduced by charging…

Applied Physics · Physics 2018-05-14 Justin C. Wong , Sayeef Salahuddin

Harvesting waste heat with temperatures lower than 100 oC can improve system efficiency and reduce greenhouse gas emissions, yet it has been a longstanding and challenging task. Electrochemical methods for harvesting low-grade heat have…

Applied Physics · Physics 2021-11-03 Xin Qian , Jungwoo Shin , Yaodong Tu , James Han Zhang , Gang Chen

The energy of ionic thermal motion presents universally, which is as high as 4 kJ\bullet kg-1\bullet K-1 in aqueous solution, where thermal velocity of ions is in the order of hundreds of meters per second at room temperature1,2. Moreover,…

Mesoscale and Nanoscale Physics · Physics 2012-03-13 Zihan Xu , Guoan Tai , Yungang Zhou , Fei Gao , Kin Hung Wong

We use the one-dimensional object-oriented particle-in-cell Monte Carlo collision code oopd1 to explore the charged particle densities, the electronegativity, the electron energy probability function (EEPF), and the electron heating…

Plasma Physics · Physics 2017-11-28 Jon Tomas Gudmundsson , David I. Snorrason

Aqueous electrolyte solutions under the influence of a temperature gradient can generate thermoelectric fields, which arise from different responses of the positive and negative charges. This is related to the thermo diffusion effect which…

Soft Condensed Matter · Physics 2022-06-23 André Luiz Sehnem , Antônio Martins Figueiredo Neto

More than half of the waste heat rejected into the environment has temperatures lower than 100 $^\circ C$, which accounts for nearly 85 PWh/year worldwide. Efficiently harvesting low-grade heat could be a promising step toward carbon…

Chemical Physics · Physics 2024-01-11 Xin Qian , Zhihao Ma , Qiangqiang Huang , Haoran Jiang , Ronggui Yang

Adding thermal conductivity enhancements to increase thermal power in solid-liquid phase-change thermal energy storage modules compromises volumetric energy density and often times reduces the mass and volume of active phase change material…

Materials Science · Physics 2020-11-26 Darin J. Sharar , Asher C. Leff , Adam A. Wilson , Andrew Smith

Molecular dynamics simulations have been used extensively to determine equilibrium properties of the electrode-electrolyte interface in supercapacitors held at various potentials. While such studies are essential to understand and optimize…

Soft Condensed Matter · Physics 2024-02-26 Nicolas Gaudy , Mathieu Salanne , Céline Merlet

A capacitive thermoelectric device can harvest thermal energy and convert it to electrical energy by employing a temperature-dependent dielectric material whose permittivity sharply changes with temperature. Electricity can be generated by…

Electron transpiration cooling (ETC) can reduce aerothermal loads on sharp hypersonic leading edges, but its performance is governed by whether thermionically emitted electrons escape the hot surface or return as cathode-directed backflow.…

Plasma Physics · Physics 2026-05-11 Wushun Zhang , Weixing Zhou , Yinjian Zhao

In this work, we consider the possibility of energy storage enhancement in electric capacitors using the compensational method. The essence of the proposed approach is the use of inductive voltage V_ind to partially compensate the…

Applied Physics · Physics 2020-10-28 Alexander Khitun

Electrochemical desalination devices that use redox-active cation intercalation electrodes show promise for desalination of salt-rich water resources with high water recovery and low energy consumption. While previous modeling and…

Applied Physics · Physics 2018-04-02 Sizhe Liu , Kyle C. Smith

Flowing electrode capacitive deionization systems (FE-CDI) have recently garnered attention because of their ability to prevent cross contamination and operate in uninterrupted cycles ad infinitum. Typically, FE-CDI electrodes suffer from…

Forced convection cooling is important in numerous technologies ranging from microprocessors in data centers to turbines and engines; active cooling is essential in these situations. However, active transfer of heat or thermal energy under…

Chemical Physics · Physics 2020-01-08 Yutaka Ikeda , Kazuki Fukui , Yoichi Murakami

In this study, we investigated the graphene-ionic liquid (EMImBF4) interface to clarify the effects of ambient temperature and potential on the differential capacitance. We complemented molecular dynamics simulations with density functional…

Materials Science · Physics 2024-05-16 Heigo Ers , Iuliia V. Voroshylova , Piret Pikma , Vladislav B. Ivaništšev

We report the performance of a hydrogen-chlorine electrochemical cell with a chlorine electrode employing a low precious metal content alloy oxide electrocatalyst for the chlorine electrode: (Ru_0.09Co_0.91)_3O_4. The cell employs a…

Materials Science · Physics 2012-06-14 Brian Huskinson , Jason Rugolo , Sujit K. Mondal , Michael J. Aziz
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