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We show the successful intercalation of large area (1 cm$^2$) epitaxial few-layer graphene grown on 4H-SiC with FeCl$_3$. Upon intercalation the resistivity of this system drops from an average value of $\approx 200 \ \Omega/sq$ to $\approx…

Mesoscale and Nanoscale Physics · Physics 2015-06-17 T. H. Bointon , I. Khrapach , R. Yakimova , A. V. Shytov , M. F. Craciun , S. Russo

Graphene has attracted great attentions since its first discovery in 2004. Various approaches have been proposed to control its physical and electronic properties. Here, we report that graphene based intercalation compounds is an efficient…

Materials Science · Physics 2010-11-04 Da Zhan , Li Sun , Zhenhua Ni , Lei Liu , Xiaofeng Fan , Yingying Wang , Ting Yu , Yeng Ming Lam , Wei Huang , Zexiang Shen

Graphene has exceptional optical, mechanical and electrical properties, making it an emerging material for novel optoelectronics, photonics and for flexible transparent electrode applications. However, the relatively high sheet resistance…

Mesoscale and Nanoscale Physics · Physics 2013-02-06 Guang-Xin Ni , Yi Zheng , Sukang Bae , Chin Yaw Tan , Orhan Kahya , Jing Wu , Byung Hee Hong , Kui Yao , Barbaros Özyilmaz

In this letter, we report the discovery of superconductivity in Li3Ca2C6. Several graphite intercalation compounds (GICs) with electron donors, are well known as superconductors. It is probably not astonishing, since it is generally…

Future wearable electronics, displays and photovoltaic devices rely on highly conductive, transparent and yet mechanically flexible materials. Nowadays indium tin oxide (ITO) is the most wide spread transparent conductor in optoelectronic…

The effects of humidity on the electronic properties of quasi-free standing one layer graphene (QFS 1LG) are investigated via simultaneous magneto-transport in the van der Pauw geometry and local work function measurements in a controlled…

We use anhydrous ferric chloride (FeCl3) to intercalate graphite flakes consisting of 2 to 4 graphene layers and to dope graphene monolayers. The intercalant, staging, stability and doping of the resulting intercalation compounds (ICs) are…

Materials Science · Physics 2011-06-07 W. J. Zhao , P. H. Tan , J. Liu , A. C. Ferrari

Close to charge neutrality, the low-energy properties of high-quality suspended devices based on atomically thin graphene layers are determined by electron-electron interactions. Bernal-stacked layers, in particular, have shown a remarkable…

Strongly Correlated Electrons · Physics 2016-10-20 Youngwoo Nam , Dong-Keun Ki , Mikito Koshino , Edward McCann , Alberto F. Morpurgo

In the pursuit of developing routes to enhance magnetic Kitaev interactions in {\alpha}-RuCl3, as well as probing doping effects, we investigate the electronic properties of {\alpha}-RuCl3 in proximity to graphene. We study…

Strongly Correlated Electrons · Physics 2019-12-11 Sananda Biswas , Ying Li , Stephen M. Winter , Johannes Knolle , Roser Valenti

Graphene exhibits extraordinary electronic and mechanical properties, and extremely high thermal conductivity. Being a very stable atomically thick membrane that can be suspended between two leads, graphene provides a perfect test platform…

We report on the first measurement of the thermal conductivity of a suspended single layer graphene. The measurements were performed using a non-contact optical technique. The near room-temperature values of the thermal conductivity in the…

Materials Science · Physics 2008-03-15 A. A. Balandin , S. Ghosh , W. Bao , I. Calizo , D. Teweldebrhan , F. Miao , C. N. Lau

Metal intercalation in epitaxial graphene enables the emergence of proximity-induced superconductivity and modified quantum transport properties. However, systematic transport studies of intercalated graphene have been hindered by…

Ultrafast carrier dynamics of pristine bilayer graphene (BLG) and bilayer graphene intercalated with FeCl3 (FeCl3-G), were studied using time-resolved transient differential reflection (delta R/R). Compared to BLG, the FeCl3-G data showed…

Mesoscale and Nanoscale Physics · Physics 2010-10-12 Xingquan Zou , Da Zhan , Xiaofeng Fan , Dongwook Lee , Saritha K. Nair , Li Sun , Zhenhua Ni , Zhiqiang Luo , Lei Liu , Ting Yu , Zexiang Shen , Elbert E. M. Chia

Heterostructures of graphene in proximity to magnetic insulators open the possibility to investigate exotic states emerging from the interplay of magnetism, strain and charge transfer between the layers. Recent reports on the growth of…

Strongly Correlated Electrons · Physics 2024-06-13 Aleksandar Razpopov , Roser Valentí

We investigate the structural and electronic properties of Li-intercalated monolayer graphene on SiC(0001) using combined angle-resolved photoemission spectroscopy and first-principles density functional theory. Li intercalates at room…

Intercalation is an established technique for tailoring the electronic structure of epitaxial graphene. Moreover, it enables the synthesis of otherwise unstable two-dimensional (2D) layers of elements with unique physical properties…

Mesoscale and Nanoscale Physics · Physics 2022-06-29 Bharti Matta , Philipp Rosenzweig , Olaf Bolkenbaas , Kathrin Küster , Ulrich Starke

A recent ab initio investigation of Na-C binary compounds under moderate pressures has uncovered a possible stable NaC$_4$ superconductor with an estimated critical temperature up to 41K. We revisit this promising binary system by…

Previous experimental observations for H intercalation under graphene on SiC surfaces motivate clarification of configuration stabilities and kinetic processes related to intercalation. From first-principles density-functional-theory (DFT)…

Mesoscale and Nanoscale Physics · Physics 2021-12-08 Yong Han , James W. Evans , Michael C. Tringides

The calculated results of FeCl3 graphite intercalation compounds show the detailed features. The stage-1 FeCl3-graphite intercalation compounds present diversified electronic properties due to the intercalant. The first-principles…

Materials Science · Physics 2021-01-01 Li Wei-Bang , Lin Shih-Yang , Tsai Ming-Shuei , Lin Ming-Fa , Lin Kuang-I

Various bandstructure engineering methods have been studied to improve the performance of graphitic transparent conductors; however none demonstrated an increase of optical transmittance in the visible range. Here we measure in situ optical…

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