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Master equation could be applied to model various kinds of biochemical systems. A general theory for its time-dependent nonequilibrium thermodynamics is rigorously derived. We not only introduce a concept of general internal energy, but…

Statistical Mechanics · Physics 2009-04-16 Hao Ge

Equilibrium thermodynamics is combined with Jarzynski's irreversible work theorem to quantify the excess entropy produced by irreversible processes. The resulting rectified form of the second law parallels the first law, in the sense that…

Statistical Mechanics · Physics 2007-05-23 Dor Ben-Amotz , J. M. Honig

When a physical system is put in contact with a very large thermal bath, it undergoes a dissipative (i.e., an apparently irreversible) process that leads to thermal equilibrium. This dynamical process can be described fully within quantum…

Quantum Physics · Physics 2015-05-13 Valerio Scarani

The use of statistical methods to model gravitational systems is crucial to physics practice, but the extent to which thermodynamics and statistical mechanics genuinely apply to these systems is a contentious issue. This paper provides new…

History and Philosophy of Physics · Physics 2025-02-04 Lorenzo Lorenzetti

To investigate the consequences of component confinement such as at a glass transition and the well-known energy or enthalpy gap (between the glass and the perfect crystal at absolute zero, see text), we follow our previous approach [Phys.…

Statistical Mechanics · Physics 2015-03-17 P. D. Gujrati

We review and investigate the general theory of thermodynamics of computation, and derive the fundamental inequalities that set the lower bounds of the work requirement and the heat emission during a computation. These inequalities…

Statistical Mechanics · Physics 2015-06-17 Takahiro Sagawa

We establish that entropy production, which is crucial to the characterization of thermodynamic irreversibility, is obtained through a variational principle involving the Kulback-Leibler divergence. A simple application of this…

Statistical Mechanics · Physics 2021-03-11 Naoto Shiraishi , Keiji Saito

The purpose of this work is to discuss recent progress in deriving the fundamental laws of thermodynamics (0th, 1st and 2nd-law) from nonequilibrium quantum statistical mechanics. Basic thermodynamic notions are clarified and different…

Mathematical Physics · Physics 2007-05-23 Walid K. Abou Salem

Development of thermodynamic induction up to second order gives a dynamical bifurcation for thermodynamic variables and allows for the prediction and detailed explanation of nonequilibrium phase transitions with associated spontaneous…

Statistical Mechanics · Physics 2021-10-07 S. N. Patitsas

Time-reversal symmetry plays an essential role in the thermodynamic uncertainty relations, which bound the fluctuations of observables in terms of the associated dissipation. In fact, thermodynamic uncertainty relations are typically…

Statistical Mechanics · Physics 2026-05-28 Tetta Indo , Yoshihiko Hasegawa

We propose a new measure of relative incompatibility for a quantum system with respect to two non-commuting observables, and call it quantumness of relative incompatibility. In case of a classical state, order of observation is…

Quantum Physics · Physics 2019-09-30 Manish Kumar Shukla , Rounak Mundra , Arun K Pati , Indranil Chakrabarty , Junde Wu

The wide-spread opinion is that original quantum mechanics is a reversible theory, but this statement is only true for undecomposed systems, that are those systems which sub-systems are out of consideration. Taking sub-systems into account,…

Quantum Physics · Physics 2022-11-24 Wolfgang Muschik

The training algorithms for AI systems all introduce far-from-equilibrium dynamical processes, and understanding the irreversibility of these algorithms is a fundamental step towards understanding the learning dynamics of modern AI systems.…

Statistical Mechanics · Physics 2026-05-22 Liu Ziyin , Yuanjie Ren , Adam Levine , Isaac Chuang

The irreversibility of the dynamics of the conservative systems on example of hard disks and potentially of interacting elements is investigated in terms of laws of classical mechanics. The equation of the motion of interacting systems and…

Statistical Mechanics · Physics 2007-05-23 V. M. Somsikov

This article aims at revisiting, with the aid of simple and neat numerical examples, some of the basic features of macroscopic irreversibility, and, thus, of the mechanical foundation of the second principle of thermodynamics as drawn by…

Statistical Mechanics · Physics 2015-11-12 Luca Cerino , Fabio Cecconi , Massimo Cencini , Angelo Vulpiani

To describe the nonequilibrium states of a system we introduce a new thermodynamic parameter - the lifetime of a system. The statistical distributions which can be obtained out of the mesoscopic description characterizing the behaviour of a…

Statistical Mechanics · Physics 2007-05-23 V. V. Ryazanov , S. G. Shpyrko

The concept of a uniform set is introduced for an ergodic, measure-preserving transformation on a non-atomic, infinite Lebesgue space. The uniform sets exist as much as they generate the underlying $\sigma$-algebra. This leads to the result…

Dynamical Systems · Mathematics 2011-08-22 Hisatoshi Yuasa

Formalising the confrontation of opinions (models) to observations (data) is the task of Inferential Statistics. Information Theory provides us with a basic functional, the relative entropy (or Kullback-Leibler divergence), an asymmetrical…

Information Theory · Computer Science 2015-03-13 François Bavaud

This thesis develops a new divergence that generalizes relative entropy and can be used to compare probability measures without a requirement of absolute continuity. We establish properties of the divergence, and in particular derive and…

Probability · Mathematics 2020-11-18 Yixiang Mao

Some measurements in quantum mechanics disturb each other. This has puzzled physicists since the formulation of the theory, but only in recent decades has the incompatibility of measurements been analyzed in depth and detail, using the…

Quantum Physics · Physics 2023-02-14 Otfried Gühne , Erkka Haapasalo , Tristan Kraft , Juha-Pekka Pellonpää , Roope Uola