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Semiconducting transition metal dichalcogenides present a complex electronic band structure with a rich orbital contribution to their valence and conduction bands. The possibility to consider the electronic states from a tight-binding model…

Materials Science · Physics 2016-11-15 J. A. Silva-Guillén , P. San-Jose , R. Roldán

We present a comprehensive study of the electronic structures of 192 configurations of 39 stable, layered, transition-metal dichalcogenides using density-functional theory. We show detailed investigations of their monolayer, bilayer, and…

Applied Physics · Physics 2017-11-10 M. Javaid , Salvy P. Russo , K. Kalantar-Zadeh , Andrew D. Greentree , Daniel W. Drumm

Two-dimensional semiconductors, known as Transition Metal Dichalcogenides (TMDCs), are of great interest among many materials due to their unique 2D characteristics, including exceptional electronic and optical properties. These compounds…

Materials Science · Physics 2023-10-23 Khawla Jaffel

Single- and few-layer transition metal dichalcogenides have recently emerged as a new family of layered crystals with great interest, not only from the fundamental point of view, but also because of their potential application in ultrathin…

Materials Science · Physics 2014-10-14 R. Roldán , J. A. Silva-Guillén , M. P. López-Sancho , F. Guinea , E. Cappelluti , P. Ordejón

In this work, we report an ab initio investigation based on density functional theory of the structural, energetic and electronic properties of 2D layered chalcogenides compounds based in the combination of the transition-metals (Ti, Zr,…

Materials Science · Physics 2019-04-17 Carlos M. O. Bastos , Rafael Besse , Juarez L. F. Da Silva , Guilherme M. Sipahi

Two-dimensional (2D) materials exhibit a wide range of remarkable phenomena, many of which owe their existence to the relativistic spin-orbit coupling (SOC) effects. To understand and predict properties of materials containing heavy…

The optical response of two-dimensional (2D) materials has been customarily calculated ab initio using plane waves and without separating the most important orbitals contributions. In the family of transition metal dichalcogenides (TMDC)…

Mesoscale and Nanoscale Physics · Physics 2025-12-30 Angiolo Huamán

Many-body perturbation theory methods, such as the $G_0W_0$ approximation, are able to accurately predict quasiparticle (QP) properties of several classes of materials. However, the calculation of the QP band structure of two-dimensional…

Materials Science · Physics 2022-06-23 Alberto Guandalini , Pino D'Amico , Andrea Ferretti , Daniele Varsano

Understanding quasiparticle band structures of transition metal dichalcogenides (TMDs) is critical for technological advances of these materials for atomic layer electronics and photonics. Although theoretical calculations to date have…

Mesoscale and Nanoscale Physics · Physics 2015-10-30 Chendong Zhang , Yuxuan Chen , Amber Johnson , Ming-Yang Li , Lain-Jong Li , Patrick C. Mende , Randall M. Feenstra , Chih-Kang Shih

With advances in exfoliation and synthetic techniques, atomically thin films of semiconducting transition metal dichalcogenides have recently been isolated and characterized. Their two-dimensional structure, coupled with a direct band gap…

Mesoscale and Nanoscale Physics · Physics 2014-02-04 Deep Jariwala , Vinod K. Sangwan , Lincoln J. Lauhon , Tobin J. Marks , Mark C. Hersam

We present a comprehensive study of the band alignments of two-dimensional (2D) semiconducting materials and highlight the possibilities of forming momentum-matched type I, II and III heterojunctions; an enticing possibility being atomic…

Materials Science · Physics 2016-07-13 V. Ongun Özçelik , Javad G. Azadani , Ce Yang , Steven J. Koester , Tony Low

The layered transition metal chalcogenides have been a fertile land in solid state physics for many decades. Various MX2-type transition metal dichalcogenides, such as WTe2, IrTe2, and MoS2, have triggered great attention recently, either…

The electronic structure of materials is fundamentally governed by their crystal symmetry. While most research on two-dimensional materials has focused on hexagonal lattices, such as graphene, hexagonal boron nitride, and transition metal…

Materials Science · Physics 2026-04-21 Zhonghui Han , Lanting Feng , Guodong Yu , Shengjun Yuan

Recently, transition metal dichalcogenides (TMDCs) semiconductors have been utilized for investigating quantum phenomena because of their unique band structures and novel electronic properties. In a quantum dot (QD), electrons are confined…

Mesoscale and Nanoscale Physics · Physics 2020-03-04 Gang Luo , Zhuo-Zhi Zhang , Hai-Ou Li , Xiang-Xiang Song , Guang-Wei Deng , Gang Cao , Ming Xiao , Guo-Ping Guo

We analyze a data set comprising 370 GW band structures composed of 61716 quasiparticle (QP) energies of two-dimensional (2D) materials spanning 14 crystal structures and 52 elements. The data results from PAW plane wave based one-shot…

Materials Science · Physics 2021-01-05 Asbjørn Rasmussen , Thorsten Deilmann , Kristian S. Thygesen

We calculate from first principles the electronic structure and optical properties of a number of transition metal dichalcogenide (TMD) bilayer heterostructures consisting of MoS2 layers sandwiched with WS2, MoSe2, MoTe2, BN, or graphene…

Mesoscale and Nanoscale Physics · Physics 2013-09-12 Hannu-Pekka Komsa , Arkady V. Krasheninnikov

Calculating the quasiparticle (QP) band structure of two-dimensional (2D) materials within the GW self-energy approximation has proven to be a rather demanding computational task. The main reason is the strong $\mathbf{q}$-dependence of the…

Materials Science · Physics 2016-10-12 Filip A. Rasmussen , Per S. Schmidt , Kirsten T. Winther , Kristian S. Thygesen

Interfaces formed between monolayer transition metal dichalcogenides (TMDs) and (metallo)phthalocyanine molecules are promising in energy applications and provide a platform for studying mixed-dimensional molecule-semiconductor…

Materials Science · Physics 2021-12-13 Olugbenga Adeniran , Zhen-Fei Liu

Understanding and controlling the photoexcited quasiparticle (QP) dynamics in monolayer transition metal dichalcogenides lays the foundation for exploring the strongly interacting, non-equilibrium 2D quasiparticle and polaritonic states in…

Materials Science · Physics 2024-10-04 Akiyoshi Park , Rohit Kantipudi , Jonas Göser , Yinan Chen , Duxing Hao , Nai-Chang Yeh

We present a $GW$ space-time algorithm for periodic systems in a Gaussian basis including spin-orbit coupling. We employ lattice summation to compute the irreducible density response and the self-energy, while we employ $k$-point sampling…

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