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In recent years, several aromatic molecules (benzene-based rings) have been detected in the cold molecular cloud TMC-1, with its CN-derivative, benzonitrile (c-C$_6$H$_5$CN), also identified in other nearby cold sources. However, observed…

The intermediate coupling regime in polaronic systems, situated between the adiabatic and the anti-adiabatic limit, is characterized by resonant pairing between quasi-free electrons which is induced by an exchange interaction with localized…

Superconductivity · Physics 2009-11-10 Julius Ranninger , Alfonso Romano

Many molecules exhibit multiple conformers that often easily interconvert under thermal conditions. Therefore, single conformations are difficult to isolate which renders the study of their distinct chemical reactivities challenging. We…

Chemical Physics · Physics 2014-03-31 Daniel Rösch , Stefan Willitsch , Yuan-Pin Chang , Jochen Küpper

We present a systematic study of ground state and spectroscopic properties of many-electron nanoscopic quantum rings. Addition energies at zero magnetic field (B) and electro-chemical potentials as a function of $B$ are given for a ring…

Condensed Matter · Physics 2009-11-07 A. Emperador , M. Pi , M. Barranco , E. Lipparini

We report on an experimental and theoretical investigation of the importance of anharmonicity in the 3 micron CH stretching region of Polycyclic Aromatic Hydrocarbon (PAH) molecules. We present mass-resolved, high-resolution spectra of the…

The spectrum of a hexagonal ring is analysed using concepts of group theory and a tight-binding model with first, second and third neighbours. The two doublets in the spectrum are explained with the $C_3$ symmetry group together with…

Chemical Physics · Physics 2020-06-24 Y. Hernández-Espinosa , R. A. Méndez-Sánchez , E. Sadurní

We investigate electron-phonon coupling in the molecular crystals CH$_4$, NH$_3$, H$_2$O, and HF, using first-principles quantum mechanical calculations. We find vibrational corrections to the electronic band gaps at zero temperature of…

Materials Science · Physics 2015-10-28 Bartomeu Monserrat , Edgar A. Engel , Richard J. Needs

In conventional superconductors, the electron-phonon coupling plays a dominant role in pairing the electrons and generating superconductivity. In high temperature cuprate superconductors, the existence of the electron coupling with phonons…

Nucleon and $\Delta$ resonances in the fourth resonance region are studied in a multichannel partial-wave analysis which includes nearly all available data on pion- and photo-induced reactions off protons. In the high-mass range, above…

High Energy Physics - Phenomenology · Physics 2015-05-30 A. V. Anisovich , E. Klempt , V. A. Nikonov , A. V. Sarantsev , U. Thoma

We perform a systematic quantum Monte Carlo study of the pairing correlation in the $S_4$ symmetric microscopic model for iron-based superconductors. It is found that the pairing with an extensive s-wave symmetry robustly dominates over…

Strongly Correlated Electrons · Physics 2013-03-07 Tianxing Ma , Hai-Qing Lin , Jiangping Hu

A recent study of soft X-ray absorption in native and hydrogenated coronene cations, C$_{24}$H$_{12+m}^+$ $m=0-7$, led to the conclusion that additional hydrogen atoms protect (interstellar) Polycyclic Aromatic Hydrocarbon (PAH) molecules…

Positron binding in parabenzoquinone is studied using \textit{ab initio} many-body theory. The effects of electron-positron correlations including polarization, virtual positronium formation and positron-hole repulsion, as well as those of…

Chemical Physics · Physics 2025-02-17 S. K. Gregg , J. Hofierka , B. Cunningham , D. G. Green

We investigate the cyclic polyenes (annulenes) C_{M}H_{M}, described by the Pariser--Parr--Pople (PPP) model, by means of the approximate coupled-pair theories (ACP, ACPQ). For the systems with the spectroscopic value of the PPP resonance…

Chemical Physics · Physics 2009-11-07 R. Podeszwa

Following the work in graphene, we report a first-principles study of electron-phonon coupling (EPC) in low-buckled (LB) monolayer silicene and germanene. Despite of the similar honeycomb atomic arrangement and linear band dispersion, the…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Jia-An Yan , Ryan Stein , David M. Schaefer , Xiao-Qian Wang , M. Y. Chou

The explicit solution is obtained for Raman four-wave mixing $\omega_4=\omega_1-\omega_2+\omega_3$ of two strong fields $E_1, E_3$ and two weak fields $E_2, E_4$ in a four-level system with the large Doppler broadening. The resonance of the…

Atomic Physics · Physics 2008-02-03 S. A. Babin , E. V. Podivilov , D. A. Shapiro

In ultra-relativistic heavy-ion collisions heavy quarks (charm and beauty) are produced in hard scattering processes and thus carry relevant information on the properties of the created hot and dense medium. Heavy-flavour hadrons can be…

High Energy Physics - Experiment · Physics 2019-08-13 Deepa Thomas

We investigate the two-orbital periodic Anderson model, where the local orbital fluctuations of f-electrons couple with a two-fold degenerate Jahn-Teller phonon, by using the dynamical mean-field theory. It is found that the heavy fermion…

Strongly Correlated Electrons · Physics 2013-03-05 Keisuke Mitsumoto , Yoshiaki Ono

We report nonresonant inelastic x-ray scattering from the semi-core 5d levels of several actinide compounds. Dipole-forbidden, high-multipole features form a rich bound-state spectrum dependent on valence electron configuration and…

Relativistic close coupling calculations are reported for unified electronic recombination of (e + C IV) including non-resonant and resonant recombination processes, radiative and dielectronic recombination (RR and DR). Detailed comparison…

Astrophysics · Physics 2008-11-26 Anil K. Pradhan , Guo Xin Chen , Sultana N. Nahar , Hong Lin Zhang

We report the existence of broad and weakly asymmetric features in the high-energy (G) Raman modes of freely suspended metallic carbon nanotubes of defined chiral index. A significant variation in peak width (from 12 cm-1 to 110 cm-1) is…