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A simple ansatz for the study of velocity autocorrelation functions in fluids at different timescales is proposed. The ansatz is based on an effective summation of the infinite continued fraction at a reasonable assumption about convergence…

Statistical Mechanics · Physics 2018-04-02 V. V. Ignatyuk , I. M. Mryglod , T. Bryk

Calculations of highly excited and delocalized molecular vibrational states are computationally challenging tasks, which strongly depends on the choice of coordinates for describing vibrational motions. We introduce a new method that…

We introduce a class of unconditionally energy stable, high order accurate schemes for gradient flows in a very general setting. The new schemes are a high order analogue of the minimizing movements approach for generating a time discrete…

Numerical Analysis · Mathematics 2020-02-11 Alexander Zaitzeff , Selim Esedoglu , Krishna Garikipati

Molecular dynamics is a powerful tool for studying the thermodynamics and kinetics of complex molecular events. However, these simulations can rarely sample the required time scales in practice. Transition path sampling overcomes this…

Chemical Physics · Physics 2023-07-31 Gianmarco Lazzeri , Hendrik Jung , Peter G. Bolhuis , Roberto Covino

Modern optimal control theory involves adjoining the already known equations of motion of a dynamic system to the objective function using dynamic costates; this is done in order to constrain the optimal control solutions to satisfy the…

Optimization and Control · Mathematics 2026-05-25 Ossama Abdelkhalik , Aimar Negrete

By using a formulation of motion equations for a viscous (compressible) fluid flow in terms of the vorticity and the rate of expansion as the main fluid dynamical variables, an approximation model is established for compressible flows with…

Analysis of PDEs · Mathematics 2023-08-17 Zhongmin Qian , Zihao Shen

Forecasting conditional stochastic nonlinear dynamical systems is a fundamental challenge repeatedly encountered across the biological and physical sciences. While flow-based models can impressively predict the temporal evolution of…

Machine Learning · Computer Science 2025-04-02 Adam P. Generale , Andreas E. Robertson , Surya R. Kalidindi

A variational method is studied based on the minimum of energy variance. The method is tested on exactly soluble problems in quantum mechanics, and is shown to be a useful tool whenever the properties of states are more relevant than the…

High Energy Physics - Phenomenology · Physics 2009-01-07 Luca Marotta , Fabio Siringo

We discuss kinetic-based particle optimization methods and variable-sample strategies for problems where the cost function represents the expected value of a random mapping. Kinetic-based optimization methods rely on a consensus mechanism…

Optimization and Control · Mathematics 2025-07-08 Sabrina Bonandin , Michael Herty

Atomistic modelling of phase transitions, chemical reactions, or other rare events that involve overcoming high free energy barriers usually entails prohibitively long simulation times. Introducing a bias potential as a function of an…

Computational Physics · Physics 2019-11-06 Federico Giberti , Bingqing Cheng , Gareth Aneurin Tribello , Michele Ceriotti

We study the statistical properties of the variation of the kinetic energy of a spherical Brownian particle that freely moves in an incompressible fluid at constant temperature. Based on the underdamped version of the generalized Langevin…

Statistical Mechanics · Physics 2024-12-10 Juan Ruben Gomez-Solano

As the share of renewables in the grid increases, the operation of power systems becomes more challenging. The present paper proposes a method to formulate and solve chance-constrained optimal power flow while explicitly considering the…

Systems and Control · Computer Science 2019-04-04 T. Mühlpfordt , L. Roald , V. Hagenmeyer , T. Faulwasser , S. Misra

We present numerical solutions to the extended Doering-Constantin variational principle for upper bounds on the energy dissipation rate in plane Couette flow, bridging the entire range from low to asymptotically high Reynolds numbers. Our…

Soft Condensed Matter · Physics 2009-10-31 Rolf Nicodemus , Siegfried Grossmann , Martin Holthaus

Unitary transformations can allow one to study open quantum systems in situations for which standard, weak-coupling type approximations are not valid. We develop here an extension of the variational (polaron) transformation approach to open…

We analyse the efficiency of several simulation methods which we have recently proposed for calculating rate constants for rare events in stochastic dynamical systems, in or out of equilibrium. We derive analytical expressions for the…

Other Condensed Matter · Physics 2009-11-11 Rosalind J. Allen , Daan Frenkel , Pieter Rein ten Wolde

Simulating transition dynamics between metastable states is a fundamental challenge in dynamical systems and stochastic processes with wide real-world applications in understanding protein folding, chemical reactions and neural activities.…

Machine Learning · Computer Science 2024-10-22 Haibo Wang , Yuxuan Qiu , Yanze Wang , Rob Brekelmans , Yuanqi Du

The Vortex-induced vibration (VIV) prediction of long flexible cylindrical structures relies on the accuracy of the hydrodynamic database constructed via rigid cylinder forced vibration experiments. However, to create a comprehensive…

We introduce a method of exploring potential energy contours in complex dynamical systems based on potentiostatic kinematics wherein the systems are evolved with minimal changes to their potential energy. We construct a simple iterative…

Computational Physics · Physics 2022-04-13 Michael J. Waters , James M. Rondinelli

We derive the hydrodynamic equations of perfect fluids without boost invariance [1] from kinetic theory. Our approach is to follow the standard derivation of the Vlasov hierarchy based on an a-priori unknown collision functional satisfying…

High Energy Physics - Theory · Physics 2025-10-01 Kevin T. Grosvenor , Niels A. Obers , Subodh P. Patil

We present an alternative to reweighting techniques for modifying distributions to account for a desired change in an underlying conditional distribution, as is often needed to correct for mis-modelling in a simulated sample. We employ…

High Energy Physics - Phenomenology · Physics 2023-05-01 Malte Algren , Tobias Golling , Manuel Guth , Chris Pollard , John Andrew Raine