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<001> oriented 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 single crystals were poled under different electric fields, i.e. Epoling=4 kV/cm and Epoling=13 kV/cm. In addition to the temperature-dependent dielectric constant measurement, X-ray diffraction…

Materials Science · Physics 2009-11-07 Ke-Pi Chen , Xiao-Wen Zhang , Hao-Su Luo

Giant electrocaloric (EC) effect is observed in BaTiO3 multilayer thick film structure. The temperature change is as high as 4.0 oC under an applied electric field of 352 kV/cm. Most importantly, the EC effect is found to depend on the…

Materials Science · Physics 2015-05-18 Yang Bai , Guang-Ping Zheng , San-Qiang Shi

The ferroelectric polarization of perovskite oxides is much larger than implied by displacement of static ionic charges. We use an explicitly correlated scheme to investigate the phenomenon; charge transport is evaluated as a geometric…

Condensed Matter · Physics 2012-07-07 R. Resta , S. Sorella

Recent observations of unusual ferroelectricity in thin films of HfO_2 and related materials have attracted broad interest to the materials and led to the emergence of a number of competing models for observed behaviors. Here we develop the…

Materials Science · Physics 2018-11-27 Maya D. Glinchuk , Anna N. Morozovska , Yunseok Kim , Sergei V. Kalinin

In this paper, a consistent theory is developed for size-dependent piezoelectricity in dielectric solids. This theory shows that electric polarization can be generated as the result of coupling to the mean curvature tensor, unlike previous…

General Physics · Physics 2013-05-15 Ali R. Hadjesfandiari

Geometrically frustrated structures combined with competing exchange interactions that have different magnitudes are known ingredients for achieving exotic properties. Herein, we studied detailed structural, magnetic, thermal (specific…

Materials Science · Physics 2023-12-18 P. Mohanty , N. Sharma , D. Singh , Y. Breard , D. Pelloquin , S. Marik , R. P. Singh

The intrinsic flexible character of polymeric materials also causes remarkable strain deformations along directions perpendicular to the applied stress. Here the biaxial response in the shear piezoelectricity of polyvinylidenefluoride…

The magnetocaloric effect in single crystalline Nd_{0.7}Sr_{0.3}MnO_{3} is investigated by measuring the field-induced adiabatic change in temperature which reveals a single negative peak around 130 K well below the Curie temperature…

The proton ordering model of the phase transition and physical properties of antiferroelectric crystals of squaric acid is modified by taking into account the influence of diagonal lattice strains and of the local geometry of hydrogen…

Materials Science · Physics 2021-01-20 A. P. Moina

GdFe3(BO3)4 exhibits a structural phase transition at 156 K, antiferromagnetic order of the Fe3+ moments at 36 K followed by a spin reorientation phase transition at 9 K. The reorientation phase transition is studied through dielectric,…

Strongly Correlated Electrons · Physics 2009-11-11 F. Yen , B. Lorenz , Y. Y. Sun , C. W. Chu , L. N. Bezmaternykh , A. N. Vasiliev

Using Landau-Ginzburg-Devonshire theory and effective medium approximation, we analytically calculate typical dependences of the pyroelectric and electrocaloric coefficients on external electric field, temperature and radius for spherical…

We report the mechanisms of atomic ordering in Fe$_{1-x}$Pt$_{x}$ alloys using density functional theory (DFT) and machine-learning interatomic potential Monte Carlo (MLIP-MC) simulations. We clarified that the formation enthalpy of the…

Charge-order-driven ferroelectrics are an emerging class of functional materials, distinct from conventional ferroelectrics, where electron-dominated switching can occur at high frequency. Despite their promise, only a few systems…

Materials Science · Physics 2020-02-19 Se Young Park , Karin M. Rabe , Jeffrey B. Neaton

We study the effects of the nonlinear piezoelectricity and the In distribution on the exciton energy, the electron-hole electric dipole moment, and the fine-structure splitting in stress-tunable InGaAs/GaAs quantum dots integrated onto a…

Mesoscale and Nanoscale Physics · Physics 2018-10-11 Petr Klenovský , Petr Steindl , Johannes Aberl , Eugenio Zallo , Rinaldo Trotta , Armando Rastelli , Thomas Fromherz

Apart from being so far the only known binary multiferroic compound, CuO has a much higher transition temperature into the multiferroic state, 230 K, than any other known material in which the electric polarization is induced by spontaneous…

We describe magneto-, baro- and elastocaloric effects (MCEs, BCEs and eCEs) in materials which possess both discontinuous (first-order) and continuous (second-order) magnetic phase transitions. Our ab initio theory of the interacting…

Materials Science · Physics 2020-06-03 Eduardo Mendive-Tapia , Julie B. Staunton

In the present work we analyze the influence of the charge-ordering on the magnetocaloric effect of Pr$_{1-x}$Ca$_x$MnO$_3$ manganites. The results for the samples with $x<$0.30 present the usual ferromagnetic behavior, peaking at the Curie…

Materials Science · Physics 2007-05-23 M. S. Reis , V. S. Amaral , J. P. Araujo , P. B. Tavares , A. M. Gomes , I. S. Oliveira

Ferroelectricity usually fades away when materials are thinned down below a critical value. Employing the first-principles density functional theory and modern theory of polarization, we show that the unique ionic-potential anharmonicity…

Materials Science · Physics 2016-08-31 Ruixiang Fei , Wei Kang , Li Yang

We present a phenomenological model for magnetoelectricity in multiferroic materials. The distinctive feature of the model is a two-component complex order parameter that encodes the electric polarization, along with a direct coupling…

Materials Science · Physics 2024-04-11 Pei Wang , You-Quan Li

We report ferroelectric ordering in Ni substituted CaBaCo4O7. Magnetization showed ferrimagnetic transition at 60 K and an additional transition is found ~ 82 K, further, enhanced antiferromagnetic interactions and decrease in saturation…

Materials Science · Physics 2017-10-18 C. Dhanasekhar , A. K Das , Ripandeep Singh , A. Das , G. Giovannetti , D. Khomskii , A. Venimadhav