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Using the Wentzel-Kramers-Brillouin method, we derive a modified form of the Thomas-Fermi approximation to electron density. This new result enables us to calculate the details of the self-consistent ion cores, as well as the ionization…

Materials Science · Physics 2009-02-23 Gregory C. Dente , Michael L. Tilton

Quantum corrections to Thomas-Fermi (TF) theory are investigated for noninteracting one-dimensional fermions with known uniform semiclassical approximations to the density and kinetic energy. Their structure is analyzed, and contributions…

Quantum Gases · Physics 2017-03-15 Raphael F. Ribeiro , Kieron Burke

An eikonal expansion is developed in order to provide systematic corrections to the eikonal approximation through order 1/k^2, where k is the wave number. The expansion is applied to wave functions for the Klein-Gordon equation and for the…

Nuclear Theory · Physics 2011-07-19 J. A. Tjon , S. J. Wallace

The route to reliable quantum nanoelectronic devices hinges on precise control of the electrostatic environment. For this reason, accurate methods for electrostatic simulations are essential in the design process. The most widespread…

Mesoscale and Nanoscale Physics · Physics 2023-02-28 Waldemar Svejstrup , Andrea Maiani , Kevin Van Hoogdalem , Karsten Flensberg

It has been previously proven that the Kohn-Sham kinetic energy functional scales homogeneusly under generalized coordinate scaling, in a way that is obeyed by the von Weiz\"acker functional, but seems to be in contradiction with the…

Quantum Physics · Physics 2014-10-16 Lázaro Calderín

Thermal density functional theory calculations often use the Mermin-Kohn-Sham scheme, but employ ground-state approximations to the exchange-correlation (XC) free energy. In the simplest solvable nontrivial model, an asymmetric Hubbard…

Strongly Correlated Electrons · Physics 2016-06-29 Justin C Smith , Aurora Pribram-Jones , Kieron Burke

Approximations to the many-fermion free energy density functional that include the Thomas-Fermi (TF) form for the non-interacting part lead to singular densities for singular external potentials (e.g. attractive Coulomb). This limitation of…

Statistical Mechanics · Physics 2016-09-21 James W. Dufty , S. B. Trickey

We calculate numerically the quasiparticle effective mass (m*) renormalization as a function of temperature and electron density in two- and three-dimensional electron systems with long-range Coulomb interaction. In two dimensions, the…

Strongly Correlated Electrons · Physics 2007-05-23 Ying Zhang , S. Das Sarma

We propose a new method for the evaluation of the particle density and kinetic pressure profiles in inhomogeneous one-dimensional systems of non-interacting fermions, and apply it to harmonically confined systems of up to N=1000 fermions.…

Statistical Mechanics · Physics 2009-10-31 Patrizia Vignolo , Anna Minguzzi , M. P. Tosi

One of the most powerful strategies to address properties of real many-body systems is to incorporate data obtained for models, for example, to use data of the homogeneous electron gas in order to build the Local Density Approximation for…

Materials Science · Physics 2026-05-05 Muhammed Hüseyin Güneş , Ayoub Aouina , Vitaly Gorelov , Matteo Gatti , Lucia Reining

The energy spectra of atomic ions are re-examined from the point of view of Thomas-Fermi scaling relations. For the first ionization potential, which sets the energy scale for the true discrete spectrum, Thomas-Fermi theory predicts the…

Atomic Physics · Physics 2015-05-13 Robert Carcasses , Augusto Gonzalez

Modeling the Pauli energy, the contribution to the kinetic energy caused by Pauli statistics, without using orbitals is the open problem of orbital-free density functional theory. An important aspect of this problem is correctly reproducing…

Chemical Physics · Physics 2024-06-19 Jeremy J. Redd , Antonio C. Cancio

The nuclear energy density functional method at finite temperature is a useful tool for studies of nuclear structure at high excitation, and also for researches of nuclear matter involved in explosive stellar phenomena and neutron stars.…

Nuclear Theory · Physics 2023-03-02 Takashi Nakatsukasa

We investigate the behavior of the kinetic and the exchange energy densities near the nuclear cusp of atomic systems. Considering hydrogenic orbitals, we derive analytical expressions near the nucleus, for single shells, as well as in the…

Other Condensed Matter · Physics 2016-04-01 L. A. Constantin , E. Fabiano , F. Della Sala

We present an analytical approximation for nonlinear dynamics of trapped Bose-co ndensed gases. The new approximation is a substantial improvement over the Thomas-Fermi approximation and is shown to be applicable for systems with a rather…

Statistical Mechanics · Physics 2007-05-23 Alexander L. Zubarev , Yeong E. Kim

Developing a reliable kinetic energy density functional within orbital-free density functional theory remains a long-standing challenge, particularly for atomic and molecular systems. A major difficulty lies in the absence of a systematic…

Chemical Physics · Physics 2025-10-22 Priya Priya , Anuvab Panda , Saswata Basu , Mainak Sadhukhan

We proposed a formally exact, probabilistic method to assess the validity of the Thomas-Fermi potential for three-dimensional condensed matter systems where electron dynamics is constrained to the Fermi surface. Our method, which relies on…

Materials Science · Physics 2024-06-25 Gionni Marchetti

We consider the singular electron-electron interaction corrections to the transport coefficients in disordered metals to test the validity of the Wiedemann-Franz law. We develop a local, quantum kinetic equation approach in which the charge…

Disordered Systems and Neural Networks · Physics 2008-09-25 G. Catelani , I. L. Aleiner

Corrections to elastic moduli, including the effective shear modulus, of a solid neutron star crust due to electron screening are calculated. At any given mass density, the crust is modelled as a body-centred cubic Coulomb crystal of fully…

Solar and Stellar Astrophysics · Physics 2016-03-23 D. A. Baiko

The non-interacting kinetic energy functional, $T_{KS}(\rho)$, plays a fundamental role in Density Functional Theory (DFT), but its explicit form remains unknown for arbitrary $N$-representable densities. Although it can, in principle, be…

Chemical Physics · Physics 2025-11-19 Dharamveer Kumar , Amuthan A. Ramabathiran