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In this work, we studied cobalt nitride (Co-N) thin films deposited using a dc magnetron sputtering method at a substrate temperature (\Ts) of 523\,K. We find that independent of the reactive gas flow (\pn) used during sputtering, the…

Materials Science · Physics 2017-02-15 Nidhi Pandey , Mukul Gupta , Rachana Gupta , Sujay Chakravarty , Neeraj Shukla , Anton Devishvili

In this work we investigate the process of iron nitride (Fe-N) phase formation using 2 at.% Al or 2 at.% Ti as additives. The samples were prepared with a magnetron sputtering technique using different amount of nitrogen during the…

Materials Science · Physics 2012-09-25 Rachana Gupta , Akhil Tayal , Mukul Gupta , Ajay Gupta , M. Horisberger , J. Stahn

We studied the growth behavior, structural, electronic, and magnetic properties of cobalt nitride (Co-N) thin films deposited using direct current (dc) and high power impulse magnetron sputtering (HiPIMS) processes. The N$_2$ partial gas…

Materials Science · Physics 2020-05-26 Seema , Akhil Tayal , S. M. Amir , Sabine Pütter , S. Mattauch , Mukul Gupta

Transition-metal nitrides in {\eta}-carbide type structures exhibit unusual bonding motifs and proximity to magnetic instabilities. Yet they remain unexplored in thin-film form due to the difficulty of stabilizing nitrogen-poor ternaries…

In this work, we studied the pathways for formation of stoichiometric \tcn~thin films. Polycrystalline and epitaxial \tcn~films were prepared using reactive direct current magnetron (dcMS) sputtering technique. A systematic variation in the…

Materials Science · Physics 2019-07-03 Nidhi Pandey , Mukul Gupta , Rachana Gupta , Zaineb Hussain , V. R. Reddy , D. M. Phase , Jochen Stahn

As a single-phase alloy, CrFeCoNi is a face centered cubic (fcc) material related to the archetypical high-entropy Cantor alloy CrFeCoNiMn. For thin films, CrFeCoNi of approximately equimolar composition tends to assume an fcc structure…

Single phase nickel-cobalt-titanate thin films with a formula A1+2xTi1-xO3, where A is Ni2+,Co2+ and -0.25<x<1, were grown by pulsed laser deposition on sapphire substrates. There is a large window in which both Ni/Co ratio and x can be…

Materials Science · Physics 2016-10-17 Yukari Fujioka , Johannes Frantti , Christopher Rouleau , Alexander Puretzky , Harry M. Meyer

In this work, we studied the local structure and the magnetization of Co4N thin films deposited by a reactive dc magnetron sputtering process. The interstitial incorporation of N atoms in a fcc Co lattice is expected to expand the structure…

Materials Science · Physics 2018-03-14 Nidhi Pandey , Mukul Gupta , Rachana Gupta , Parasmani Rajput , Jochen Stahn

We studied the structural and magnetic properties of \textit{in-situ} grown iron mononitride (FeN) thin films. Initial stages of film growth were trapped utilizing synchrotron based soft x-ray absorption near edge spectroscopy (XANES) at…

Materials Science · Physics 2019-02-12 Mukul Gupta , Nidhi Pandey , Niti , V. R. Reddy , D. M. Phase , Kai Schlage , Hans-Christian Wille , Ajay Gupta

Magnetism of 3d transition metals at high density has always received wide interest due to existence of magnetism at the core of the Earth. For ferromagnetic cobalt, although there is a theoretical prediction that its magnetic moment would…

Materials Science · Physics 2016-02-19 Nasrin Banu , Surendra Singh , B. Satpati , A. Roy , S. Basu , P. Chakraborty , Hema C. P. Movva , V. Lauter , B. N. Dev

Thin-films of bct Co$_{1-x}$Mn$_x$ grown by molecular beam epitaxy on MgO(001) were measured to have an enhanced atomic magnetic moment of $2.52 \pm 0.07$ $\mu_\text{B}/\text{atom}$ beyond the pinnacle of the Slater-Pauling curve for…

Materials Science · Physics 2025-04-04 S. F. Peterson , Y. U. Idzerda

This work demonstrates synthesis and study of fcc-Co derived from an isostructural Co4N. Diffusion measurements carried out in this work, reveal that N self-diffusion is the swiftest in Co4N compared to other transition metal nitrides or…

Materials Science · Physics 2024-06-19 Seema , Dileep Kumar , U. P. Deshpande , Mukul Gupta

Recent high-throughput computational searches have predicted many novel ternary nitride compounds providing new opportunities for materials discovery in under explored phase spaces. Nevertheless, there are hardly any predictions and/or…

Antiperovskite nitrides with the general formula M$_3$N have attracted significant attention due to their tunable electronic and magnetic properties. Among them are many cobalt-based compounds predicted to exhibit high thermodynamic…

Nickel nitride (Ni-N) thin film samples were deposited using reactive magnetron sputtering process utilizing different partial flow of N2 (RN2). They were characterized using x-ray reflectivity (XRR), x-ray diffraction (XRD) and x-ray…

Materials Science · Physics 2020-04-23 Nidhi Pandey , Mukul Gupta , Jochen Stahn

The Nd0.6Sr0.4MnO3 manganite system exhibits a phase transition from paramagnetic insulating (PMI) to ferromagnetic metallic (FMM) state around its Curie temperature TC = 270 K (bulk). The morphology-driven changes in the kinetically…

Materials Science · Physics 2023-12-25 R S Mrinaleni , E P Amaladass , A T Sathyanarayana , Jegadeesan P , S Amirthapandian , Awadhesh Mani

In order to unambiguously identify the source of magnetism reported in recent studies of the Co-Te system, two sets of high-quality, epitaxial CoTe$_x$ films (thickness $\simeq$ 300 nm) were prepared by pulse laser deposition (PLD). X-ray…

Materials Science · Physics 2024-07-23 Zhiwei Zhang , William A. Hines , J. I. Budnick , David M. Perry , B. O. Wells

Magnetic nanoparticles of cobalt ferrite have been synthesized by wet chemical method using stable ferric and cobalt salts with oleic acid as the surfactant. X-ray Diffraction (XRD) and Transmission Electron Microscope (TEM) confirmed the…

Materials Science · Physics 2007-05-23 K. Maaz , Arif Mumtaz , S. K. Hasanain , Abdullah Ceylan

In the present work, we systematically studied the effect of Al doping on the phase formation of iron nitride (Fe-N) thin films. Fe-N thin films with different concentration of Al (Al=0, 2, 3, 6, and 12 at.%) were deposited using dc…

Materials Science · Physics 2015-05-21 Akhil Tayal , Mukul Gupta , Nidhi Pandey , Ajay Gupta , M. Horisberger , Jochen Stahn

Initial powder mixtures of Cu, Fe and Co are exposed to severe plastic deformation by high-pressure torsion to prepare solid solutions. A broad range of compositions is investigated, whereas this study aims at the synthesis of soft magnetic…

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