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The inter-band optical absorption in graphene characterized by its fine-structure constant has a universal value of 2.3\% independent of the material parameters. However, for several graphene-based photonic applications, enhanced optical…

Materials Science · Physics 2016-03-23 Shaloo Rakheja , Parijat Sengupta

A density-functional approach on the hexagonal graphene lattice is developed using an exact numerical solution to the Hubbard model as the reference system. Both nearest-neighbour and up to third nearest-neighbour hoppings are considered…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 M. Ijäs , A. Harju

Graphynes are 2D porous structures deriving from graphene featuring triangular and regularly distributed subnanometer pores, which may be exploited to host small gaseous species. First principles adsorption energies of molecular hydrogen…

Chemical Physics · Physics 2015-10-06 Massimiliano Bartolomei , Estela Carmona-Novillo , Giacomo Giorgi

We have investigated the quantum capacitance ($C_Q$) in functionalized graphene, modified with ad-atoms from different groups in the periodic table. Changes in the electronic band structure of graphene upon functionalization and…

Materials Science · Physics 2019-06-17 Sruthi T , Kartick Tarafder

The increasing relevance of energy storage technologies demands high-capacity cathode materials for Li-ion batteries. Recently, Li-rich defect anti-fluorite Li$_5$FeO$_4$ has emerged as a high-capacity cathode material exhibiting…

Materials Science · Physics 2022-06-24 Anu Maria Augustine , Vishnu Sudarsanan , P. Ravindran

We present a model study to estimate the sensitivity of the optical absorption of multilayered graphene structure to the subnanometer interlayer separation. Starting from a transfer-matrix formalism we derive semi-analytical expressions for…

Optics · Physics 2022-11-28 Devashish Pandey , Sanshui Xiao , Martijn Wubs

Local curvature, or bending, of a graphene sheet is known to increase the chemical reactivity presenting an opportunity for templated chemical functionalization. Using first principles calculations based on density functional theory (DFT)…

Materials Science · Physics 2015-08-12 Jesper Toft Rasmussen , Tue Gunst , Peter Bøggild , Antti-Pekka Jauho , Mads Brandbyge

The kinetic performance of graphite particles is difficult to deconvolute from half-cell experiments, where the influences of the working electrode porosity and the counter electrode contribute nonlinearly to the electrochemical re-sponse.…

Materials Science · Physics 2015-03-13 Michael Heß , Petr Novák

The hexagonal structure of graphene gives rise to the property of gas impermeability, motivating its investigation for a new application: protection of semiconductor photocathodes in electron accelerators. These materials are extremely…

Graphene, owing to its zero bandgap electronic structure, is promising as an absorption material for ultra-wideband photodetection applications. However, graphene-absorption based detectors inherently suffer from poor responsivity due to…

Applied Physics · Physics 2019-08-20 Krishna Murali , Nithin Abraham , Sarthak Das , Sangeeth Kallatt , Kausik Majumdar

Graphite fluoride (CFx) cathodes coupled with lithium anodes yield one of the highest theoretical energy densities (>860 Wh/g) among primary batteries. In practice, the observed discharge voltage (~2.5 V) is significantly lower than…

Materials Science · Physics 2021-07-06 Kevin Leung , Noah B. Schorr , Matthew Mayer , Timothy N. Lambert , Y. Shirley Meng , K. L. Harrison

Graphene is believed to be an excellent candidate material for next-generation electronic devices. However, one needs to take into account the nontrivial effect of metal contacts in order to precisely control the charge injection and…

Mesoscale and Nanoscale Physics · Physics 2013-10-08 Salvador Barraza-Lopez , Markus Kindermann , M. Y. Chou

We investigate the absorption properties of graphene-based anisotropic metamaterial structures where the metamaterial layer possesses an electromagnetic response corresponding to a near-zero permittivity. We find that through analytical and…

Optics · Physics 2016-08-25 Jacob Linder , Klaus Halterman

A recent study of temperature programmed desorption (TPD) measurements of small n-alkanes (CNH2N+2) from C(0001) deposited on Pt(111) shows a linear relationship of the desorption energy with increasing n-alkane chain length. We here…

Super capacitors are promising energy storage devices due to their capability of delivering high peak current and storing high amount of energy in a short time with very low internal power loss. We fabricated the graphene or graphite oxide…

Mesoscale and Nanoscale Physics · Physics 2014-09-24 Gladson Joseph , A. Alfred Kirubaraj , U. Satheesh , D. Devaprakasam

Doped graphene sheets are pseudochiral two-dimensional Fermi liquids with abnormal electron-electron interaction physics. We address graphene's Fermi liquid properties quantitatively using a microscopic random-phase-approximation theory and…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Marco Polini , Reza Asgari , Yafis Barlas , T. Pereg-Barnea , A. H. MacDonald

Experimental realization of efficient graphene-based absorbers is a challenging task due to the low carrier mobility in processed graphene. In this paper, we circumvent this problem by placing uniform graphene sheets on metallic…

Applied Physics · Physics 2020-03-24 Xuchen Wang , Sergei A. Tretyakov

We report on a capacitance study of dual gated bilayer graphene. The measured capacitance allows us to probe the electronic compressibility as a function of carrier density, temperature, and applied perpendicular electrical displacement D.…

Mesoscale and Nanoscale Physics · Physics 2013-09-17 A. F. Young , C. R. Dean , I. Meric , S. Sorgenfrei , H. Ren , K. Watanabe , T. Taniguchi , J. Hone , K. L. Shepard , P. Kim

Graphene is an attractive material for microelectronics applications, given such favourable electrical characteristics as high mobility, high operating frequency, and good stability. If graphene is to be implemented in electronic devices on…

Materials Science · Physics 2019-06-14 B. C. Worley , S. Kim , T. J. Ha , S. Park , R. Haws , P. Rossky , D. Akinwande , A. Dodabalapur

The presence of finite bandgap and high mobility in semiconductor few-layer black phosphorus offers an attractive prospect for using this material in future two-dimensional electronic devices. Here we demonstrate for the first time fully…