Related papers: Analytical Formulas of Molecular Ion Abundances an…
Protoplanetary disks are the target of many chemical studies (both observational and theoretical) as they contain the building material for planets. Their large vertical and radial gradients in density and temperature make them challenging…
During the million years of evolution, gas dust and ice in protoplanetary disks can be chemically reprocessed. There are evidences that the gas-phase carbon and oxygen abundances are sub-solar in disks belonging to nearby star forming…
Planets form in protoplanetary disks and inherit their chemical compositions. It is thus crucial to map the distribution and investigate the formation of simple organics, such as formaldehyde and methanol, in protoplanetary disks. We…
The recent detection of gas-phase methanol (CH$_3$OH) lines in the disc of TW Hya by Walsh et al. provided the first observational constraints on the complex O-bearing organic content in protoplanetary discs. The emission has a ring-like…
Observations conducted using the Atacama Large Millimeter/submillimeter Array on the protoplanetary disk around TW Hya show the nitrogen fractionation of HCN molecules in HC$^{14}$N/HC$^{15}$N $\sim$120 at a radius of $\sim$20 AU. In this…
(Abridged) Near- to mid-IR observations of protoplanetary disks show that the inner regions (<10AU) are rich in small organic volatiles (e.g., C2H2 and HCN). Trends in the data suggest that disks around cooler stars (~3000K) are potentially…
The efficiency of radial transport of icy solid material from outer disk to the inner disk is currently unconstrained. Efficient radial transport of icy dust grains could significantly alter the composition of the gas in the inner disk. Our…
H$_2$CO ice on dust grains is an important precursor of complex organic molecules (COMs). H$_2$CO gas can be readily observed in protoplanetary disks and may be used to trace COM chemistry. However, its utility as a COM probe is currently…
(Abridged) The observed presence of pure CO2 ice in protostellar envelopes is attributed to thermally induced ice segregation, but a lack of quantitative experimental data has prevented its use as a temperature probe. Quantitative…
We develop a simple iterative scheme to include vertical turbulent mixing and diffusion in ProDiMo thermo-chemical models for protoplanetary discs. The models are carefully checked for convergence toward the time-independent solution of the…
There is a robust polyatomic chemistry in diffuse, partially-molecular interstellar gas that is readily accessible in absorption at radio/mm/sub-mm wavelengths. Accurate column densities are derived owing to the weak internal excitation, so…
(Abridged) Rotational H$_2$O spectra as observed with JWST/MIRI provide a good probe of the temperature and column density structure of the inner disk. H$_2$O emission can also be influenced by dynamical processes, such as dust grains…
The distributions and abundances of molecules in protoplanetary disks are powerful tracers of the physical and chemical disk structures. The abundance ratios of HCN and its isomer HNC are known to be sensitive to gas temperature. Their line…
Ices are the main carriers of volatiles in protoplanetary disks and are crucial to our understanding of the chemistry that ultimately sets the organic composition of planets. The ERS program Ice Age on the JWST follows the ice evolution…
The cosmic-ray ionization rate (CRIR, $\zeta_2$) is one of the key parameters controlling the formation and destruction of various molecules in molecular clouds. However, the current most commonly used CRIR tracers, such as H$_3^+$, OH$^+$,…
We perform a complete census of molecular ions with an abundance larger than 1e-10 in the protostellar shock L1157-B1 by means of an unbiased high-sensitivity survey obtained with the IRAM-30m and Herschel/HIFI. By means of an LVG radiative…
Understanding the gas abundance distribution is essential when tracing star formation using molecular line observations. Changing density and temperature conditions cause gas to freeze-out onto dust grains, and this needs to be taken into…
Observations of deuterium fractionation in the solar system, and in interstellar and circumstellar material, are commonly used to constrain the formation environment of volatiles. Toward protoplanetary disks, this approach has been limited…
The thermal structure of protoplanetary disks is a fundamental characteristic of the system that has wide reaching effects on disk evolution and planet formation. In this study, we constrain the 2D thermal structure of the protoplanetary…
Observations of low-mass protostellar systems show evidence of rich complex organic chemistry. Their low luminosity, however, makes determining abundance distributions of complex organic molecules (COMs) within the water snowline…