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We analyse the self-diffusiophoresis of a spherical particle animated by a nonuniform chemical reaction at its boundary. We consider two models of solute absorption, one with a specified distribution of interfacial solute flux, and one…

Fluid Dynamics · Physics 2015-03-03 Ehud Yariv , Sebastien Michelin

We study a simple model for a particle that is active due to self-phoresis and that has been proposed to model symmetric camphor grains. The particle generates a concentration field through the continuous emission of a chemical substance,…

Statistical Mechanics · Physics 2026-02-18 Leah Anderson , David S. Dean

We investigate the self-diffusiophoretic motion of a catalytically active spherical particle confined within a wedge-shaped domain. Using the Fourier-Kontorovich-Lebedev transform, we solve the Laplace equation for the concentration field…

Soft Condensed Matter · Physics 2026-05-06 Abdallah Daddi-Moussa-Ider , Ramin Golestanian

Active droplets can swim spontaneously in viscous flows as a result of the non-linear convective transport of a chemical solute produced at their surface by the Marangoni and/or phoretic flows generated by this solute's inhomogeneous…

Fluid Dynamics · Physics 2022-12-01 Nikhil Desai , Sebastien Michelin

Diffusiophoresis is the spontaneous motion of particles under gradients of solutes. In electrolyte-driven diffusiophoresis, the zeta potential of the particles is an important surface property that characterizes diffusiophoretic mobility.…

Soft Condensed Matter · Physics 2022-09-30 Suin Shim , Janine K. Nunes , Guang Chen , Howard A. Stone

Breaking spatial symmetry is an essential requirement for phoretic active particles to swim at low Reynolds number. This fundamental prerequisite for swimming at the micro-scale is fulfilled either by chemical patterning of the surface of…

Soft Condensed Matter · Physics 2022-04-20 Abdallah Daddi-Moussa-Ider , Andrej Vilfan , Ramin Golestanian

In addition to self-propulsion by phoretic mechanisms that arises from an asymmetric distribution of reactive species around a catalytic motor, spherical particles with a uniform distribution of catalytic activity may also propel themselves…

Statistical Mechanics · Physics 2014-01-08 Pierre de Buyl , Alexander S. Mikhailov , Raymond Kapral

Microparticles migrate in response to gradients in solute concentration through diffusiophoresis and diffusioosmosis. Merging streams of fluid with distinct solute concentrations is a common strategy for producing a steady concentration…

Fluid Dynamics · Physics 2023-06-01 Robben E. Migacz , Guillaume Durey , Jesse T. Ault

Propulsion of colloidal particles due to momentum transfer from localized surface reactions is investigated by solving the exact unsteady Stokes equation. We model the effect of surface reactions as either a {\it force dipole} acting on the…

Soft Condensed Matter · Physics 2025-10-08 Javier Diaz , Ignacio Pagonabarraga , Carles Calero

Diffusiophoresis (DP) refers to the migration of particles driven by a solute concentration gradient in a liquid. Observations in the case of molecular neutral solutes are rather scarce, due to the low drift velocities in dilute solutions,…

The separation of colloidal particles based solely on their surface properties is a highly challenging task. This study demonstrates that diffusiophoresis and diffusioosmosis enable the continuous separation of carboxylate polystyrene…

We investigate the diffusiophoresis of a non-polarizable droplet laden with soluble ionic surfactant, for which the surface charge arises from adsorption of surfactant at the fluid-fluid interface. Unlike previous studies that assume either…

Fluid Dynamics · Physics 2026-02-09 Subrata Majhi , Somnath Bhattacharyya

Under a thermodynamic gradient, for example, the concentration or temperature gradients, the colloidal particles immersed in the solvent can exhibit a directional migration along or against the gradient -- phoresis, a cross transport…

Soft Condensed Matter · Physics 2026-03-31 Yuxing Jiao , Qing Yang , Mingcheng Yang

Electro- and diffusio- phoresis of particles correspond respectively to the transport of particles under electric field and solute concentration gradients. Such interfacial transport phenomena take their origin in a diffuse layer close to…

Soft Condensed Matter · Physics 2020-04-22 Sophie Marbach , Hiroaki Yoshida , Lydéric Bocquet

Hydrodynamic interactions with confining boundaries often lead to drastic changes in the diffusive behaviour of microparticles in suspensions. For axially symmetric particles, earlier numerical studies have suggested a simple form of the…

Soft Condensed Matter · Physics 2016-07-22 Maciej Lisicki , Bogdan Cichocki , Eligiusz Wajnryb

Chemically active colloids move by creating gradients in the composition of the surrounding solution and by exploiting the differences in their interactions with the various molecular species in solution. If such particles move near…

Soft Condensed Matter · Physics 2017-02-24 M. N. Popescu , W. E. Uspal , S. Dietrich

A colloidal particle placed in an inhomogeneous solution of smaller non-adsorbing polymers will move towards regions of lower polymer concentration, in order to reduce the free energy of the interface between the surface of the particle and…

Soft Condensed Matter · Physics 2017-12-13 Richard P. Sear , Patrick B. Warren

Charged colloidal particles propel themselves through asymmetric fluxes of chemically generated ions on their surface. We show that asymmetry in the surface charge distribution introduces a new mode of self-phoretic motion for chemically…

Soft Condensed Matter · Physics 2023-05-03 Ahis Shrestha , Monica Olvera de la Cruz

Chemically active, or autophoretic, particles that isotropically emit or absorb solute molecules undergo spontaneous self-propulsion when their activity is increased beyond a critical P\'{e}clet number ($Pe$). Here, we conduct numerical…

Fluid Dynamics · Physics 2022-09-20 R. Kailasham , Aditya S. Khair

We discuss the motion of colloidal particles relative to a two component fluid consisting of solvent and solute. Particle motion can result from (i) net body forces on the particle due to external fields such as gravity; (ii) slip…

Soft Condensed Matter · Physics 2015-05-13 Frank Julicher , Jacques Prost