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We present a study of graphene/substrate interactions on UHV-grown graphene islands with minimal surface contamination using \emph{in situ} low-temperature scanning tunneling microscopy (STM). We compare the physical and electronic…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 S. M. Hollen , G. A. Gambrel , S. J. Tjung , N. M. Santagata , E. Johnston-Halperin , J. A. Gupta

We have developed a novel method for crystalline hydrogenation of graphene on the nanoscale. Molecular hydrogen was physisorbed at 5 K onto pristine graphene islands grown on Cu(111) in ultrahigh vacuum. Field emission local to the tip of a…

Mesoscale and Nanoscale Physics · Physics 2017-06-06 S. J. Tjung , S. M. Hollen , G. A. Gambrel , N. M. Santagata , E. Johnston-Halperin , J. A. Gupta

The graphene islands, formed as different sizes, are crucial for the final quality of the formed graphene during the CVD growth either as the nucleation seeds or as the build blocks for larger graphene domains. Extensive efforts had been…

Computational Physics · Physics 2018-08-27 Ziwei Xu , Changshuai Shi , Lu Qiu , Feng Ding

Single layer graphene islands with a typical diameter of several nanometers were grown on a Pt (111) substrate. Scanning tunneling microscopy (STM) analysis showed most of islands are hexagonally shaped and the zigzag-type edge predominates…

Mesoscale and Nanoscale Physics · Physics 2011-01-21 Mayu Yamamoto , Seiji Obata , Koichiro Saiki

We use low-energy electron microscopy to investigate how graphene grows on Cu(111). Graphene islands first nucleate at substrate defects such as step bunches and impurities. A considerable fraction of these islands can be rotationally…

Materials Science · Physics 2011-10-20 S. Nie , J. M. Wofford , N. C. Bartelt , O. D. Dubon , K. F. McCarty

We study the growth and microscopic structure of large-area graphene monolayers, grown on copper single crystals by chemical vapor deposition (CVD) in ultra-high vacuum (UHV). Using atomic-resolution scanning tunneling microscopy (STM), we…

Mesoscale and Nanoscale Physics · Physics 2010-08-23 L. Zhao , K. T. Rim , H. Zhou , R. He , T. F. Heinz , A. Pinczuk , G. W. Flynn , A. N. Pasupathy

Low-energy electron microscopy (LEEM) reveals a new mode of graphene growth on Ru(0001) in which Ru atoms are etched from a step edge and injected under a growing graphene sheet. Based on density functional calculations, we propose a model…

Materials Science · Physics 2010-12-14 E. Loginova , S. Maier , I. Stass , N. C. Bartelt , P. J. Feibelman , M. Salmeron , K. F. McCarty

We present an investigation of the atomic and electronic structure of graphene monolayer islands on the 6H-SiC(000-1)(3x3) (SiC(3x3)) surface reconstruction using scanning tunneling microscopy (STM) and spectroscopy (STS). The orientation…

Materials Science · Physics 2010-01-04 F. Hiebel , P. Mallet , L. Magaud , J. -Y. Veuillen

We report an atomically-resolved scanning tunneling microscopy (STM) investigation of the edges of graphene grains synthesized on Cu foils by chemical vapor deposition (CVD). Most of the edges are macroscopically parallel to the zigzag…

Mesoscale and Nanoscale Physics · Physics 2011-09-20 Jifa Tian , Helin Cao , Wei Wu , Qingkai Yu , Yong P. Chen

We have used scanning tunneling microscopy (STM) to investigate two types of hydrogen defect structures on monolayer graphene supported by hexagonal boron nitride (h-BN) in a gated field-effect transistor configuration. The first H-defect…

Graphite crystals used to prepare graphene-based heterostructures are generally assumed to be defect free. We report here scanning tunneling microscopy results that show graphite commonly used to prepare graphene devices can contain a…

The growth of graphene by catalytic decomposition of ethylene on Cu(111) in an ultra-high vacuum system was investigated with low energy electron diffraction, low energy electron microscopy, and atomic force microscopy. Attempts to form a…

Materials Science · Physics 2013-07-19 Zachary R. Robinson , Parul Tyagi , Tyler R. Mowll , James B. Hannon , Carl A. Ventrice

We study the local density of states at and around a substituting impurity and use these results to compute current versus bias characteristic curves of Scanning Tunneling Microscopy (STM) experiments done on the surface of graphene. This…

Mesoscale and Nanoscale Physics · Physics 2009-04-28 N. M. R. Peres , Shan-Wen Tsai , J. E. Santos , R. M. Ribeiro

This work reports the peculiar properties of a graphene film prepared by the chemical vapor deposition (CVD) of ethylene in high vacuum on a well oriented and carefully cleaned Pt(111) crystal surface maintained at high temperature. In-situ…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 E. Cazzanelli , T. Caruso , M. Castriota , A. R. Marino , A. Politano , G. Chiarello , M. Giarola , G. Mariotto

Electrons in graphene have fourfold spin and valley degeneracies owing to the unique bipartite honeycomb lattice and an extremely weak spin-orbit coupling, which can support a series of broken symmetry states. Atomic-scale defects in…

Mesoscale and Nanoscale Physics · Physics 2022-08-17 Yu Zhang , Liangguang Jia , Yaoyao Chen , Lin He , Yeliang Wang

Graphene grown by chemical vapour deposition is transferred on top of flat gold nanoislands and characterized by scanning tunnelling microscopy (STM) and atomic force microscopy (AFM). Graphene bubbles are formed with lateral dimensions…

Mesoscale and Nanoscale Physics · Physics 2016-09-15 András Pálinkás , György Molnár , Chanyong Hwang , László Péter Biró , Zoltán Osváth

We report nanocrystalline carbon impurities coexisting with graphene synthesized via chemical vapor deposition (CVD) on platinum. We observe micron-size island-like impurity layers, which can easily be mistaken for second graphene layers in…

Mesoscale and Nanoscale Physics · Physics 2014-08-04 Jinglei Ping , Michael S. Fuhrer

An atomic-scale study utilizing scanning tunneling microscopy (STM) in ultrahigh vacuum (UHV) is performed on large single crystalline graphene grains synthesized on Cu foil by a chemical vapor deposition (CVD) method. After thermal…

Mesoscale and Nanoscale Physics · Physics 2014-09-12 Jifa Tian , Helin Cao , Wei Wu , Qingkai Yu , Nathan P. Guisinger , Yong P. Chen

Silicene, a counterpart of graphene, has achieved rapid development due to its exotic electronic properties and excellent compatibility with the mature silicon-based semiconductor technology. Its low room-temperature mobility of about 100…

Materials Science · Physics 2015-12-31 Hongsheng Liu , Haifeng Feng , Yi Du , Jian Chen , Kehui Wu , Jijun Zhao

We present scanning tunneling microscopy (STM) images of single-layer graphene crystals examined under ultrahigh vacuum conditions. The samples, with lateral dimensions on the micron scale, were prepared on a silicon dioxide surface by…

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