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We investigate whether making the friction spatially dependent on the reaction coordinate introduces quantum effects into the thermal reaction rates for dissipative reactions. Quantum rates are calculated using the numerically exact…

The goal of this article is to investigate the dynamics of semi-relativistic or non-relativistic charged particles in interaction with a scalar meson field. Our main contribution is the derivation of the classical dynamics of a…

Mathematical Physics · Physics 2024-05-22 Shahnaz Farhat

We construct C*-dynamical systems for the dynamics of classical infinite particle systems describing harmonic oscillators interacting with arbitrarily many neighbors on lattices, as well on more general structures. Our approach allows…

Operator Algebras · Mathematics 2025-12-19 T. D. H. van Nuland , C. J. F. van de Ven

Classical simulation of quantum systems plays an important role in the study of many-body phenomena and in the benchmarking and verification of quantum technologies. Exact simulation is often limited to small systems because the dimension…

Quantum Physics · Physics 2024-06-04 Dominik S. Wild , Sabina Drăgoi , Corbin McElhanney , Jonathan Wurtz , Sheng-Tao Wang

A classical description of the dynamics of a dissipative charged-particle fluid in a quadrupole-like device is developed. It is shown that the set of the classical fluid equations contains the same information as a complex function…

Quantum Physics · Physics 2009-11-07 S. De Nicola , R. Fedele , V. I. Man'ko

We show that the centroid molecular dynamics (CMD) method provides a realistic way to calculate the thermal diffusivity $a=\lambda/\rho c_{\rm V}$ of a quantum mechanical liquid such as para-hydrogen. Once $a$ has been calculated, the…

Chemical Physics · Physics 2021-05-10 Benjamin J. Sutherland , William H. D. Moore , David. E. Manolopoulos

It is shown that, under the Wentzel-Kramers-Brillouin approximation conditions, using the Foldy-Wouthuysen representation allows the problem of finding a classical limit of relativistic quantum mechanical equations to be reduced to the…

Mathematical Physics · Physics 2013-02-11 A. J. Silenko

Ab-initio molecular dynamics (AIMD) is a powerful tool to simulate physical movements of molecules for investigating properties of materials. While AIMD is successful in some applications, circumventing its high computational costs is…

Quantum Physics · Physics 2024-06-28 Honomi Kashihara , Yudai Suzuki , Kenji Yasuoka

The theory underlying the Car-Parrinello extended-lagrangian approach to {\em ab initio} molecular dynamics (CPMD) is reviewed and reexamined using 'heavy' ice as a test system. It is emphasized that the adiabatic decoupling in CPMD is not…

Statistical Mechanics · Physics 2009-11-11 Paul Tangney

This study introduces a novel computational approach based on ratchet-and-pawl molecular dynamics (rMD) for accurately estimating ligand dissociation kinetics in protein-ligand complexes. By integrating Kramers' theory with Bell's equation,…

Chemical Physics · Physics 2025-08-19 Bruno Stegani , Riccardo Capelli

Local measurements of the Hubble parameter are increasingly in tension with the value inferred from a $\Lambda$CDM fit to the cosmic microwave background (CMB) data. In this paper, we construct scenarios in which evolving scalar fields…

Cosmology and Nongalactic Astrophysics · Physics 2023-10-13 Prateek Agrawal , Francis-Yan Cyr-Racine , David Pinner , Lisa Randall

Molecular or condensed matter systems are often well approximated by hybrid quantum-classical models: the electrons retain their quantum character, whereas the ions are considered to be classical particles. We discuss various alternative…

Chemical Physics · Physics 2021-05-07 J. L. Alonso , C. Bouthelier , A. Castro , J. Clemente-Gallardo , J. A. Jover-Galtier

While Born-Oppenheimer molecular dynamics (BOMD) has been widely studied by resorting to powerful methods in mathematical analysis, this paper presents a geometric formulation in terms of Hamilton's variational principle and…

Mathematical Physics · Physics 2023-07-20 Paul Bergold , Cesare Tronci

In this paper, we develop a multiscale hierarchy framework for objective molecular dynamics (OMD), a reduced order molecular dynamics with a certain symmetry, that connects it to the statistical kinetic equation, and the macroscopic…

Analysis of PDEs · Mathematics 2024-09-24 Richard D. James , Kunlun Qi , Li Wang

With the path integral approach, the thermal average in a multi-electronic-state quantum systems can be approximated by the ring polymer representation on an extended configuration space, where the additional degrees of freedom are…

Numerical Analysis · Mathematics 2020-11-24 Xiaoyu Lei , Zhennan Zhou

To provide a practitioner's introduction to the study of the nuclear pasta, this article presents a brief review of the evolution of the methods used to study nucleon dynamics. This is followed with a more complete description of the…

Nuclear Theory · Physics 2011-11-08 Claudio O. Dorso , Pedro A. Giménez Molinelli , Jorge A. López

We study the classical mechanics and dynamics of particles that retains some memory of quantum statistics. Our work builds on earlier work on the statistical mechanics and thermodynamics of such particles. Starting from the effective…

Quantum Physics · Physics 2025-11-21 Varsha Subramanyan , T. H. Hansson , Smitha Vishveshwara

Peridynamics (PD) is a non-local continuum formulation. The original version of PD was restricted to bond-based interactions. Bond-based PD is geometrically exact and its kinematics are similar to classical continuum mechanics (CCM).…

Computational Engineering, Finance, and Science · Computer Science 2020-04-30 A. Javili , S. Firooz , A. T. McBride , P. Steinmann

We study the fluctuation-induced dissipative dynamics of the quantized center of mass motion of a polarizable dielectric particle trapped near a surface. The particle's center of mass is treated as an open quantum system coupled to the…

Quantum Physics · Physics 2020-03-18 Kanupriya Sinha , Yigit Subasi

Recent progress in the development of quantum technologies has enabled the direct investigation of dynamics of increasingly complex quantum many-body systems. This motivates the study of the complexity of classical algorithms for this…

Quantum Physics · Physics 2023-07-12 Dominik S. Wild , Álvaro M. Alhambra
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