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Related papers: Phosphorene: Synthesis, Scale-up, and Quantitative…

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It attracts wide interest to seek universe saturable absorber covering wavelengths from near infrared to mid-infrared band. Multilayer black phosphorus, with variable direct bandgap (0.3-2 eV) depending on the layer number, becomes a good…

Black phosphorus is an infrared layered material. Its bandgap complements other widely studied two-dimensional materials: zero-gap graphene and visible/near-infrared gap transition metal dichalcogenides. Though highly desirable, a…

Mesoscale and Nanoscale Physics · Physics 2017-02-07 Guowei Zhang , Shenyang Huang , Andrey Chaves , Chaoyu Song , V. Ongun Özçelik , Tony Low , Hugen Yan

Systematic engineering of atomic-scale low-dimensional defects in two-dimensional nanomaterials is a promising way to modulate the electronic properties of these nanomaterials. Defects at interfaces such as grain boundaries and line defects…

Materials Science · Physics 2016-01-22 Woosun Jang , Kisung Kang , Aloysius Soon

Phosphorene, a monolayer of black phosphorus, is a two-dimensional material that lacks a multivalley structure in the Brillouin zone and has negligible spin-orbit coupling. This makes it a promising candidate for investigating the orbital…

Mesoscale and Nanoscale Physics · Physics 2023-10-20 Tarik P. Cysne , Marcio Costa , Marco Buongiorno Nardelli , R. B. Muniz , Tatiana G. Rappoport

The capacity and stability of constituent electrodes determine the performance of Li-ion batteries. In this study, density functional theory is employed to explore the potential application of recently synthesized two dimensional…

Mesoscale and Nanoscale Physics · Physics 2014-09-24 Shijun Zhao , Wei Kang

Semi-metallic graphene and semiconducting monolayer transition metal dichalcogenides (TMDCs) are the two-dimensional (2D) materials most intensively studied in recent years. Recently, black phosphorus emerged as a promising new 2D material…

Mesoscale and Nanoscale Physics · Physics 2014-11-07 Xiaomu Wang , Aaron M. Jones , Kyle L. Seyler , Vy Tran , Yichen Jia , Huan Zhao , Han Wang , Li Yang , Xiaodong Xu , Fengnian Xia

Using first-principles calculations, we study the electronic properties of few-layer phosphorene focusing on layer-dependent behavior of band gap, work function and band alignment and carrier effective mass. It is found that few-layer…

Materials Science · Physics 2014-10-13 Yongqing Cai , Gang Zhang , Yong-Wei Zhang

Two-dimensional and layered materials, such as graphene, have emerged in recent years for their potential use in several applications in technology, for example in electronics, bioelectronics, optoelectronics and related fields.…

Materials Science · Physics 2020-07-10 Francesco Mercuri

Micromechanically exfoliated mono- and multilayers of molybdenum disulfide (MoS2) are investigated by spectroscopic imaging ellipsometry. In combination with knife edge illumination, MoS2 flakes can be detected and classified on arbitrary…

Mesoscale and Nanoscale Physics · Physics 2016-11-17 S. Funke , B. Miller , E. Parzinger , P. Thiesen , A. W. Holleitner , U. Wurstbauer

Single layer (SL) phosphorus (phosphorene) has drawn considerable research attention recently as a two-dimensional (2D) material for application promises. It is a semiconductor showing superior transport and optical properties. Few-layer or…

Mesoscale and Nanoscale Physics · Physics 2017-11-22 Jin-Peng Xu , Jun-Qiu Zhang , Hao Tian , Hu Xu , Wingkin Ho , Maohai Xie

The surface structure of phosphorene crystals materials is determined using surface sensitive dynamical micro-spot low energy electron diffraction ({\mu}LEED) analysis using a high spatial resolution low energy electron microscopy (LEEM)…

We systematically evaluate the prospects of a novel 2D nanomaterial, phosphorene, as anode for Na-ion batteries. Using first-principles calculations, we determine the Na adsorption energy, specific capacity and Na diffusion barriers on…

Materials Science · Physics 2015-06-24 Vadym V. Kulish , Oleksandr I. Malyi , Clas Persson , Ping Wu

We demonstrate the large scale exfoliation of bulk black phosphorus into few-layers black phosphorus. We use wet-jet mill (WJM) as an industrially scalable exfoliation technique. In order to avoid the degradation by oxidation of the…

Phosphorene, an emerging elemental two-dimensional (2D) direct band gap semiconductor with fascinating structural and electronic properties distinctively different from other 2D materials such as graphene and MoS2, is promising for novel…

Materials Science · Physics 2015-04-21 Yongqing Cai , Qingqing Ke , Gang Zhang , Yuan Ping Feng , Vivek B Shenoy , Yong-Wei Zhang

Atomic structure of single-crystalline black phosphorus was studied by high resolution synchrotron-based photoelectron diffraction (XPD). The results show that the topmost phosphorene layer in the black phosphorus is slightly displaced…

Materials Science · Physics 2016-02-03 Luis Henrique de Lima , Lucas Barreto , Richard Landers , Abner de Siervo

Tuning band gaps in two-dimensional (2D) materials is of great interest in the fundamental and practical aspects of contemporary material sciences. Recently, black phosphorus (BP) consisting of stacked layers of phosphorene was…

Materials Science · Physics 2017-09-13 Sun-Woo Kim , Hyun Jung , Hyun-Jung Kim , Jin-Ho Choi , Su-Huai Wei , Jun-Hyung Cho

We propose here a two-dimensional material based on a single layer of violet or Hittorf's phosphorus. Using first-principles density functional theory, we find it to be energetically very stable, comparable to other previously proposed…

Materials Science · Physics 2016-06-13 Georg Schusteritsch , Martin Uhrin , Chris J. Pickard

Phosphorene, a puckered two-dimensional allotrope of phosphorus, has sparked considerable interest in recent years due to its potential especially for optoelectronic applications with its layer-number-dependant direct band gap and strongly…

In this work, we reported uniform layer-by-layer sublimation of black phosphorus under heating below 600 K. The uniformity and crystallinity of BP samples after thermal thinning were confirmed by Raman spectra and 2D Raman imaging. A…

Materials Science · Physics 2017-08-02 Weijun Luo , Rui Yang , Jialun Liu , Yunlong Zhao , Wenjuan Zhu , Guangrui , Xia

Phosphorene is a bidimensional material that has properties useful for semiconductor devices. In this work we studied the electronic and optical properties of this material using the $GW$ approximation and the Bethe-Salpeter equation (BSE)…

Mesoscale and Nanoscale Physics · Physics 2017-11-16 Fábio Ferreira , Ricardo Mendes Ribeiro