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It is a challenge to synthesize graphene nanoribbons (GNRs) with narrow widths and smooth edges in large scale. Our first principles study on the hydrogenation of GNRs shows that the hydrogenation starts from the edges of GNRs and proceeds…

Materials Science · Physics 2009-09-30 Hongjun Xiang , Erjun Kan , Su-Huai Wei , Myung-Hwan Whangbo , Jinlong Yang

We report on various nanocarbons formed from a unique structural pattern containing two pentagons, three hexagons and two heptagons, resulting from local rearrange- ments around a divacancy in pristine graphene or nanotubes. This defect can…

Materials Science · Physics 2015-06-03 Jean-Marc Leyssale , G érard L. Vignoles , Antoine Villesuzanne

In order to study a magnetic principle of carbon based materials, multiple spin state of zigzag edge modified graphene molecules are analyzed by the first principle density functional theory to select suitable modification element. Radical…

Mesoscale and Nanoscale Physics · Physics 2011-06-15 Norio Ota , Narjes Gorjizadeh , Yoshiyuki Kawazoe

Graphene, a thinnest material in the world, can form moire structures on different substrates, including graphite, h-BN, or metal surfaces. In such systems the structure of graphene, i. e. its corrugation, as well as its electronic and…

Mesoscale and Nanoscale Physics · Physics 2016-07-12 Elena Voloshina , Yuriy Dedkov

Atomically precise graphene nanoribbons are a promising emerging class of designer quantum materials with electronic properties that are tunable by chemical design. However, many challenges remain in the device integration of these…

Graphene nanopatterning on highly oriented pyrolytic graphite (HOPG) has previously been shown using both atomic force microscopy (AFM) and scanning tunneling microscopy (STM) based techniques, including folding of intrinsic step edges and…

Mesoscale and Nanoscale Physics · Physics 2018-12-27 Kim Akius , Jan van Ruitenbeek

We propose a new allotrope of graphane, named as tricycle graphane,with a 4up/2down UUUDUD hydrogenation in each hexagonal carbon ring,which is different from previously proposed allotropes with UUDUUD(boat-1) and UUUUDD (boat-2) types of…

Materials Science · Physics 2015-06-04 Chaoyu He , L. Z. Sun , C. X. Zhang , N. Jiao , K. W. Zhang , Jianxin Zhong

We propose a new class of semiconducting graphene-based nanostructures: hydrogenated graphene nanoripples (HGNRs), based on continuum-mechanics analysis and first principles calculations. They are formed via a two-step combinatorial…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Z. F. Wang , Yu Zhang , Feng Liu

In this study, we investigate the electronic and magnetic properties of graphane nanoribbons. We find that zigzag and armchair graphane nanoribbons with H-passivated edges are nonmagnetic semiconductors. While bare armchair ribbons are also…

Materials Science · Physics 2010-05-20 Hasan Sahin , Can Ataca , Salim Ciraci

Tailor-made magnetic nanostructures offer a variety of functionalities useful for technological applications. In this work, we explore the possibilities of realizing Fe nanostructures at the interfaces of 2D graphene and h-BN by ab initio…

Materials Science · Physics 2013-10-22 Soumyajyoti Haldar , Pooja Srivastava , Olle Eriksson , Prasenjit Sen , Biplab Sanyal

A series of carbon allotropes with novel optoelectronic and rich topological properties is predicted by systematic first-principles calculations. These fascinating carbon allotropes can be derived by inserting acetylenic linkages…

Materials Science · Physics 2021-08-12 Yan Gao , Chengyong Zhong , Shengyuan A. Yang , Kai Liu , Zhong-Yi Lu

Nano-holes, etched under an electron beam at room temperature in singlelayer graphene sheets as a result of their interaction with metalimpurities, are shown to heal spontaneously by filling up with either non-hexagon, graphene-like, or…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 Recep Zan , Quentin M. Ramasse , Ursel Bangert , Konstantin S. Novoselov

Graphene nano-ribbons junctions based electronic devices are proposed in this Letter. Non-equilibrium Green function calculations show that nano-ribbon junctions tailored from single layer graphene with different edge shape and width can…

Mesoscale and Nanoscale Physics · Physics 2007-06-13 Zhiping Xu

The mechanical response of graphene nano-ribbon under tensile loading has been investigated using atomistic simulation. Lattice symmetry dependence of elastic properties are found, which fits prediction from Cauchy-Born rule well.…

Materials Science · Physics 2009-03-12 Zhiping Xu

Graphene nanowiggles (GNW) are graphene-based nanostructures obtained by making alternated regular cuts in pristine graphene nanoribbons. GNW were recently synthesized and it was demonstrated that they exhibit tunable electronic and…

Materials Science · Physics 2017-02-06 Rafael A. Bizao , Tiago Botari , Eric Perim , Nicola M. Pugno , Douglas S. Galvao

We report scanning tunneling microscopy and spectroscopy investigation of graphene nanoribbons grown on an array of bunched steps of a 6H-SiC(0001) substrate. Our scanning tunneling microscopy images of a graphene nanoribbons on a step…

Mesoscale and Nanoscale Physics · Physics 2015-06-12 M. Ridene , T. Wassmann , E. Pallecchi , G. Rodary , J. C. Girard , A. Ouerghi1

Graphene is attracting vast interest due to its superior electronic and mechanical properties. However, structure and electronic properties of its edge are often neglected, although they are important for nanoscale devices because the edge…

Mesoscale and Nanoscale Physics · Physics 2022-08-25 Takamoto Yokosawa , Masahiro Kamada , Taisuke Ochi , Yuki Koga , Rin Takehara , Masahiro Hara , Tomohiro Matsui

Aligned graphene nanoribbon (GNR) arrays were made by unzipping of aligned single-walled and few-walled carbon nanotube (CNT) arrays. Nanotube unzipping was achieved by a polymer-protected Ar plasma etching method, and the resulting…

Materials Science · Physics 2010-05-03 Liying Jiao , Li Zhang , Lei Ding , Jie Liu , Hongjie Dai

We demonstrate that free graphene sheet edges can curl back on themselves,reconstructing as nanotubes. This results in lower formation energies than any other non-functionalised edge structure reported to date in the literature. We…

The small mass and atomic-scale thickness of graphene membranes make them highly suitable for nanoelectromechanical devices such as e.g. mass sensors, high frequency resonators or memory elements. Although only atomically thick, many of the…