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Related papers: Theory of long-range ultracold atom-molecule photo…

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Ultracold collisions of neutral atoms and molecules have been of great interest since experimental advances enabled the cooling and trapping of such species. This study is a theoretical investigation of a low-energy collision between an…

Atomic Physics · Physics 2025-11-25 Ahmed A. Elkamshishy , Chris H. Greene

Photoassociation of ultracold atoms is a resonant light-assisted collision process, in which two colliding atoms absorb a photon and form an excited molecule. Since the first observation about three decades ago, the photoassociation of…

Atomic Physics · Physics 2024-03-19 Jin Cao , Bo-Yuan Wang , Huan Yang , Zhi-Jie Fan , Zhen Su , Jun Rui , Bo Zhao , Jian-Wei Pan

The general formalism of the multipolar expansion of electrostatic interactions is applied to the calculation the potential energy between an excited atom (without fine structure) and a ground state diatomic molecule at large separations.…

Quantum Physics · Physics 2017-04-11 M. Lepers , O. Dulieu , V. Kokoouline

We investigate the formation of ultracold NaCs molecules by photoassociation of Na and Cs atoms.

Chemical Physics · Physics 2010-08-09 Xuan Li

We explore the feasibility of optically forming long-range tetratomic and larger polyatomic molecules in their ground electronic state from ultracold pairs of polar molecules aligned by external fields. Depending on the relative orientation…

Atomic Physics · Physics 2021-06-16 Marko Gacesa , Jason N. Byrd , Jonathan Smucker , John A. Montgomery, , Robin Côté

A theoretical model is proposed for the formation of ultracold ground-state triatomic molecules in weakly bound energy levels. The process is driven by the electric component of a microwave field, which induces the association of an…

Atomic Physics · Physics 2026-01-16 Baraa Shammout , Leon Karpa , Silke Ospelkaus , Eberhard Tiemann , Olivier Dulieu

Photoassociation of ultracold atoms is shown to lead to alignment of the product molecules along the excitation laser polarization axis. We theoretically investigate pulsed photoassociation of $^{87}Rb$ atoms into a specific weakly-bound…

Quantum Physics · Physics 2017-11-15 S. Kallush , J. L. Carini , P. L. Gould , R. Kosloff

The electrostatic interaction between an excited atom and a diatomic ground state molecule in an arbitrary rovibrational level at large mutual separations is investigated with a general second-order perturbation theory, in the perspective…

Quantum Physics · Physics 2017-04-11 M. Lepers , R. Vexiau , N. Bouloufa , O. Dulieu , V. Kokoouline

The paper investigates cold molecules formation in the photoassociation of two cold atoms by a strong laser pulse applied at short interatomic distances, which lead to a molecular dynamics taking place in the light-induced (adiabatic)…

Quantum Physics · Physics 2009-07-23 M. Vatasescu

Ultracold atoms coupled to optical cavities offer a powerful platform for studying strongly correlated many-body physics. Here, we propose an experimental scheme for creating biatomic molecules via cavity-enhanced photoassociation from an…

Quantum Gases · Physics 2026-04-17 Yun Chen , Yuqi Wang , Jingjun You , Yingqi Liu , Su Yi , Yuangang Deng

The formation of ultracold metastable RbCs molecules is observed in a double species magneto-optical trap through photoassociation below the ^85Rb(5S_1/2)+^133Cs(6P_3/2) dissociation limit followed by spontaneous emission. The molecules are…

Atomic Physics · Physics 2015-06-03 N. Bouloufa-Maafa , M. Aymar , O. Dulieu , C. Gabbanini

Photoassociation of ultracold atoms induced by chirped picosecond pulses is analyzed in a non-perturbative treatment by following the wavepackets dynamics on the ground and excited surfaces. The initial state is described by a Boltzmann…

Atomic and Molecular Clusters · Physics 2009-06-10 Eliane Luc-Koenig , Mihaela Vatasescu , Francoise Masnou-Seeuws

Chemical reactions can be surprisingly efficient at ultracold temperatures ( < 1mK) due to the wave nature of atoms and molecules. The study of reactions in the ultracold regime is a new research frontier enabled by cooling and trapping…

Atomic Physics · Physics 2017-01-16 Lee R. Liu , Jessie T. Zhang , Yichao Yu , Nicholas R. Hutzler , Yu Liu , Till Rosenband , Kang-Kuen Ni

The generation of cold molecules is a core topic in the field of cold atoms and molecules, which has advanced relevant research like ultracold chemistry, quantum computation, and quantum metrology. With high atomic phase space density,…

Atomic Physics · Physics 2024-02-27 Li Li , Yi-Jia Liu , Xiao-Long Zhou , Ze-Min Shen , Si-Jian He , Zhao-Di Liu , Jian Wang

This review describes recent experimental and theoretical advances in forming molecules in ultracold gases of trapped alkali metal atoms, both by magnetic tuning through Feshbach resonances and by photoassociation. Molecular Bose-Einstein…

Chemical Physics · Physics 2007-05-23 Jeremy M. Hutson , Pavel Soldan

A model for photoassociation of ultracold atoms and molecules is presented, and applied to the case of $^{39}$K and $^{23}$Na$^{39}$K bosonic particles. The model relies on the assumption that photoaossociation is dominated by long-range…

Chemical Physics · Physics 2023-03-22 Baraa Shammout , Leon Karpa , Silke Ospelkaus , Eberhard Tiemann , Olivier Dulieu

Ultracold metastable RbCs molecules are observed in a double species MOT through photoassociation near the Rb(5S$_{1/2}$)+Cs(6P$_{3/2}$) dissociation limit followed by radiative stabilization. The molecules are formed in their lowest…

Atomic Physics · Physics 2017-09-13 C. Gabbanini , O. Dulieu

We report the production of ultracold heteronuclear Cs$^*$Yb molecules through one-photon photoassociation applied to an ultracold atomic mixture of Cs and Yb confined in an optical dipole trap. We use trap-loss spectroscopy to detect…

Ultracold molecules offer a broad variety of applications, ranging from metrology to quantum computing. However, forming "real" ultracold molecules, {\it i.e.} in deeply bound levels, is a very difficult proposition. Here, we show how…

Atomic Physics · Physics 2009-11-13 Philippe Pellegrini , Marko Gacesa , Robin Côté

We theoretically explore photoassociation by Adiabatic Passage of two colliding cold ^{85}Rb atoms in an atomic trap to form an ultracold Rb_2 molecule. We consider the incoherent thermal nature of the scattering process in a trap and show…

Quantum Physics · Physics 2009-11-13 Evgeny A. Shapiro , Moshe Shapiro , Avi Pe'er , Jun Ye
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