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A multiscale QM/classical approach is presented, that is able to model the optical properties of complex nanostructures composed of a molecular system adsorbed on metal nanoparticles. The latter are described by a combined…

Chemical Physics · Physics 2024-10-29 Pablo Grobas Illobre , Piero Lafiosca , Luca Bonatti , Tommaso Giovannini , Chiara Cappelli

In quantum/classical (QM/CM) partitioning methods for multi-scale modeling, one is often forced to introduce uncontrolled phenomenological effects of the environment (CM) in the quantum (QM) domain as ab initio quantum calculations are…

Chemical Physics · Physics 2007-05-23 Aditi Mallik , Carlos E. Taylor , Keith Runge , James W. Dufty

Plasmonic gap structures are among the few configurations capable of generating extreme light confinement, finding applications in surface-enhanced spectroscopy, ultrasensitive detection, photocatalysis and more. Their plasmonic response…

Mesoscale and Nanoscale Physics · Physics 2025-02-21 Pu Zhang , Christos Tserkezis , N. Asger Mortensen

The boundary element method (BEM) enables solving three-dimensional electromagnetic problems using a two-dimensional surface mesh, making it appealing for applications ranging from electrical interconnect analysis to the design of…

Numerical Analysis · Mathematics 2021-12-14 Shashwat Sharma , Piero Triverio

We propose and analyze a new approach based on quantum error correction (QEC) to improve quantum metrology in the presence of noise. We identify the conditions under which QEC allows one to improve the signal-to-noise ratio in…

Quantum Physics · Physics 2014-04-29 Eric M. Kessler , Igor Lovchinsky , Alexander O. Sushkov , Mikhail D. Lukin

We formulate a new atomistic/continuum (a/c) coupling scheme that employs the boundary element method (BEM) to obtain an improved far-field boundary condition. We establish sharp error bounds in a 2D model problem for a point defect…

Numerical Analysis · Mathematics 2017-09-27 A. S. Dedner , C. Ortner , H. Wu

The quasi-nonlocal quasicontinuum method (QNL) is a consistent hybrid coupling method for atomistic and continuum models. Embedded atom models are empirical many-body potentials that are widely used for FCC metals such as copper and…

Numerical Analysis · Mathematics 2010-09-15 Xingjie Helen Li , Mitchell Luskin

The finite element method (FEM) is a cornerstone numerical technique for solving partial differential equations (PDEs). Here, we present $\textbf{Qu-FEM}$, a fault-tolerant era quantum algorithm for the finite element method. In contrast to…

Quantum Physics · Physics 2025-10-22 Ahmad M. Alkadri , Tyler D. Kharazi , K. Birgitta Whaley , Kranthi K. Mandadapu

We present a methodology based on quantum mechanics for assigning quantum conductivity when an ac field is applied across a variable gap between two plasmonic nanoparticles with an insulator sandwiched between them. The quantum tunneling…

The optical response of a coupled nanowire dimer is studied using a fully quantum mechanical approach. The translational invariance of the system allows to apply the time--dependent density functional theory for the plasmonic dimer with the…

Optics · Physics 2013-02-15 T. V. Teperik , P. Nordlander , J. Aizpurua , A. G. Borisov

Time-domain Boundary Element Methods (BEM) have been successfully used in acoustics, optics and elastodynamics to solve transient problems numerically. However, the storage requirements are immense, since the fully populated system matrices…

Numerical Analysis · Mathematics 2020-06-11 Daniel Seibel

Quasicentroid molecular dynamics (QCMD) is a path-integral method for approximating nuclear quantum effects in dynamics simulations, which has given promising results for gas- and condensed-phase water. Here, by simulating the infrared…

Chemical Physics · Physics 2021-11-29 Christopher Haggard , Vijay Ganesh Sadhasivam , George Trenins , Stuart C. Althorpe

Our theoretical examination of second and third harmonic generation from metal-based nanostructures predicts that nonlocal and quantum tunneling phenomena can significantly exceed expectations based solely on local, classical…

Quantum defect embedding theory (QDET) is a many-body embedding method designed to describe condensed systems with correlated electrons localized within a given region of space, for example spin defects in semiconductors and insulators.…

Materials Science · Physics 2025-08-28 Siyuan Chen , Victor Wen-zhe Yu , Yu Jin , Marco Govoni , Giulia Galli

We present a new empirical pseudopotential (EPM) calculation approach to simulate the million atom nanostructured semiconductor devices under potential bias using the periodic boundary conditions. To treat the non-equilibrium condition,…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Xiang-Wei Jiang , Shu-Shen Li , Jian-Bai Xia , Lin-Wang Wang

Accurate and efficient prediction of electronic wavefunctions is central to ab initio molecular dynamics (AIMD) and electronic structure theory. However, conventional ab initio methods require self-consistent optimization of electronic…

Chemical Physics · Physics 2025-11-12 Yanxian Tao , Lingyun Wan , Xiongzhi Zeng , Yingdi Jin , Jie Liu , Zhenyu Li , Jinlong Yang

Investigating nanoplasmonics using time-dependent approaches permits shedding light on the dynamic optical properties of plasmonic structures, which are intrinsically connected with their potential applications in photochemistry and…

Mesoscale and Nanoscale Physics · Physics 2024-06-18 Piero Lafiosca , Luca Nicoli , Silvio Pipolo , Stefano Corni , Tommaso Giovannini , Chiara Cappelli

In tiny metallic nanostructures, quantum confinement and nonlocal response change the collective plasmonic behavior with important consequences for e.g. field-enhancement and extinction cross sections. We report on our most recent…

Optics · Physics 2012-09-07 N. A. Mortensen , G. Toscano , S. Raza , N. Stenger , W. Yan , A. -P. Jauho , S. Xiao , M. Wubs

Quantum error mitigation (QEM) is a class of promising techniques capable of reducing the computational error of variational quantum algorithms tailored for current noisy intermediate-scale quantum computers. The recently proposed…

Quantum Physics · Physics 2022-05-17 Yifeng Xiong , Soon Xin Ng , Lajos Hanzo

Within the MNPBEM toolbox, developed for the simulation of plasmonic nanoparticles using a boundary element method approach, we show how to include substrate and layer structure effects. We develop the methodology for solving Maxwell's…

Mesoscale and Nanoscale Physics · Physics 2016-05-04 Jürgen Waxenegger , Andreas Trügler , Ulrich Hohenester
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