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Nickel/zinc (Ni/Zn) technology is a promising post-lithium battery type for stationary applications with respect to aspects such as safety, environmental compatibility and resource availability. Although this battery type has been known for…

The atomic structure and elastic properties of silicon carbide nanowires of different shapes and effective sizes were studied using density functional theory and classical molecular dynamics. The surface relaxation led to surface…

Recent years have seen a rapidly escalating demand for battery technologies capable of storing more energy, charging more quickly and having longer usable lifetimes, driven largely by increased electrification of transport and by grid-scale…

A density functional theory study of the structural and electronic properties and relative stability of narrow SP3 silicon nanotubes of different growth orientations is presented. All nanotubes studied and their corresponding wire…

Mesoscale and Nanoscale Physics · Physics 2012-12-05 Alon Hever , Jonathan Bernstein , Oded Hod

Silicon-containing lithium-ion batteries can exhibit capacity gain early in life, which makes forecasting future cell behavior difficult. We have observed these anomalous trends even in conditions where known mechanisms, such as overhang…

Chemical Physics · Physics 2026-02-17 Marco-Tulio F. Rodrigues , Charles McDaniel , Stephen E. Trask , Daniel P. Abraham

The article describes fabrication and properties of composite fibrous scaffolds obtained by electrospinning of the solution of poly({\epsilon}-caprolactone) and arginine in common solvent. The influence of arginine content on structure,…

This study presents a comprehensive investigation into the exceptional superconducting attributes of titanium nitride (TiN) achieved through plasma-enhanced atomic layer deposition (PEALD) on both planar and intricate three-dimensional (3D)…

Superconductivity · Physics 2023-12-18 John Femi-Oyetoro , Sasha Sypkens , Henry LeDuc , Matthew Dickie , Andrew Beyer , Peter Day , Frank Greer

We demonstrate that for polycrystalline LiNi0.33Mn0.33Co0.33O2 c-axis textured thin film cathodes of rechargeable lithium-ion batteries, the kinetics of Li storage and release including maximum specific capacity is determined by Li…

Materials Science · Physics 2025-09-11 Erwin Hüger , Harald Schmidt

Lithium titanium oxide Li$_4$Ti$_5$O$_{12}$ (LTO) is an intriguing anode material promising particularly long lived batteries, due to its remarkable phase stability during (dis)charging of the cell. However, its usage is limited by its low…

Materials Science · Physics 2020-01-03 Matthias Kick , Cristina Grosu , Markus Schuderer , Christoph Scheurer , Harald Oberhofer

Higher energy density and longer lifetime are the requirements for next-generation lithium-ion batteries. A promising anode material is silicon, which offers high specific capacity, but its significant volume change during lithiation and…

In Lithium ion batteries (LIBs), proper design of cathode materials influences its intercalation behavior, overall cost, structural stability, and its impact on environment. At present, the most common type of cathode materials, NCA , has…

Materials Science · Physics 2018-04-03 Kamalika Ghatak , Hemant Kumar , Siva Nadimpalli , Dibakar Datta

The development of multifunctional solid-state materials is key to advancing lithium-ion batteries with enhanced safety and simplified architectures. Here, we report a scalable, highly efficient (near $100\%$), solvent-free mechanochemical…

Highly conductive solid electrolytes are one key component for the development of safe and high-power all-solid-state batteries. Enormous progress has been achieved in the field of lithium solid electrolytes. Meanwhile, their ion…

Materials Science · Physics 2017-12-14 Marc Duchardt , Uwe Ruschewitz , Stefanie Dehnen , Bernhard Roling

The two-dimensional (2D) IV-V semiconductors have attracted much attention due to their fascinating electronic and optical properties. In this work, we predicted three phases of silicon nitrides, denoted $\alpha$-Si$_{2}$N$_{2}$,…

Materials Science · Physics 2024-04-02 Jiesen Li , Wanxing Lin , Junjun Shi , Feng Zhu , Haiwen Xie , Dao-Xin Yao

Amorphous polymer derived silicon oxycarbide (SiOC) is an attractive candidate for Lithium ion battery anodes, as an alternative to graphite, which is limited to a theoretical capacity of 372 mAh/g. However, SiOC tends to exhibit poor…

Layered-oxide $\mathrm{LiNi_xMn_yCo_{1-x-y}O_2}$ (NMC) positive electrodes with high Nickel content, deliver high voltages and energy densities. However, a high nickel content, e.g., $x$ = 0.8 (NMC 811), can lead to high surface reactivity,…

Materials Science · Physics 2023-07-11 Hengning Chen , Zeyu Deng , Yuheng Li , Pieremanuele Canepa

Density-functional-theory (DFT) calculations have been performed on the Li-Si and Li-Ge systems. Lithiated Si and Ge, including their metastable phases, play an important technological r\^ole as Li-ion battery (LIB) anodes. The calculations…

Materials Science · Physics 2015-06-18 Andrew J. Morris , C. P. Grey , C. J Pickard

As power generated from renewables becomes more readily available, the need for power-efficient energy storage devices, such as redox flow batteries, becomes critical for successful integration of renewables into the electrical grid. An…

Chemical Physics · Physics 2022-06-07 Tiras Y. Lin , Sarah E. Baker , Eric B. Duoss , Victor A. Beck

We propose theoretically a reconfigurable two-dimensional (2D) hexagonal sonic crystal with higher-order topology protected by the six-fold, $C_6$, rotation symmetry. The acoustic band gap and band topology can be controlled by rotating the…

Mesoscale and Nanoscale Physics · Physics 2020-12-16 Zhi-Kang Lin , Shi-Qiao Wu , Hai-Xiao Wang , Jian-Hua Jiang

A general framework to study the mechanical behaviour of a cylindrical silicon anode particle in a lithium ion battery as it undergoes lithiation is presented. The two-way coupling between stress and concentration of lithium in silicon,…

Soft Condensed Matter · Physics 2019-08-13 Jeevanjyoti Chakraborty , Colin P. Please , Alain Goriely , S. Jonathan Chapman
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