Related papers: Gelation Paradox
Using a unique home-made cell for four-contact impedance spectroscopy of conductive liquid samples, we establish the existence of two low frequency conductivity relaxations in aqueous solutions of gelatin, in both liquid and gel state. A…
We present a theory of active, permeating, polar gels, based on a two-fluid model. An active relative force between the gel components creates a steady-state current. We analyze its stability, while considering two polar coupling terms to…
One of water's unsolved puzzles is the question of what determines the lowest temperature to which it can be cooled before freezing to ice. The supercooled liquid has been probed experimentally to near the homogeneous nucleation temperature…
Recently, Wang et al. [1] reported on an unusual violation of Wiedemann-Franz law in three semimetals. We compare their observations to our observations in a variety of systems, where the apparent WF law violations in the same temperature…
We study the Boltzmann equation in a smooth bounded domain featuring a mixed boundary condition. Specifically, gas particles experience specular reflection in two parallel plates, while diffusive reflection occurs in the remaining portion…
The classical problem of thermal explosion is modified so that the chemically active gas is not at rest but is flowing in a long cylindrical pipe. Up to a certain section the heat-conducting walls of the pipe are held at low temperature so…
Thermoreversible sol-gel transitions in solutions of rod-like associating polymers are analyzed by computer simulations and by mean field models. The sol-gel transition is determined by the divergence of the cluster weight average. The…
This letter reports a temperature-dependent limit for the subthreshold swing in MOSFETs that deviates from the Boltzmann limit at deep-cryogenic temperatures. Below a critical temperature, the derived limit saturates to a value that is…
We revisit dark-matter production through freeze-in and freeze-out by solving the Boltzmann equations at the level of the phase-space distribution $f(p,t)$. Using the $2\to2$ annihilation and the $1\to2$ decay processes for illustration, we…
The growth history of the inner core is inherently linked to the thermal history of the Earth. The crystallization of the inner core may have been delayed by supercooling, and went through an initial phase of fast growth after the…
Glass formers exhibit, upon an oscillatory excitation, a response function whose imaginary and real parts are known as the loss and storage moduli respectively. The loss modulus typically peaks at a frequency known as the \alpha frequency…
We study a microscopically realistic model of a physical gel and use computer simulations to investigate its static and dynamic properties at thermal equilibrium. The phase diagram comprises a sol phase, a coexistence region ending at a…
Here we show that the Coulomb interaction between violations of the Bernal-Fowler rules leads to a temperature induced step-wise increase in their concentration by 6-7 orders of magnitude. This first-order phase transition is accompanied by…
Aims: We investigate temperature fluctuations in H II regions in terms of a two-phase model, which assumes that the nebular gas consists of a hot and a cold phase. Methods: We derive general formulae for T([O III), the [O III] forbidden…
The steep increase of the relaxation time of glass forming liquids upon cooling is traditionally ascribed to an impending entropy crisis: since the system has "nowhere to go", dynamics must come to a halt. This classic argument, due to Adam…
We are interested in the hydrodynamic limit of the Boltzmann equation for a gas of fermions in the incompressible Euler regime. We use the relative entropy method as improved by Saint-Raymond. Our result is analogous to what is obtained in…
The diffusion of glycerol molecules decreases with decreasing temperature as its viscosity increases in a manner simply described by the Stokes-Einstein(SE) relation. Approaching the glass transition, this relation breaks down as it does…
Molecular predissociation is the spontaneous, nonradiative bond breaking process that can occur upon excitation. In the context of laser cooling, predissociation is an unwanted consequence of molecular structure that limits the ability to…
The behaviour of electrons in solids is remarkably well described by Landau's Fermi-liquid theory, which says that even though electrons in a metal interact they can still be treated as well-defined fermions, called ``quasiparticles''. At…
In concentrated electrolytes with asymmetric or irregular ions, such as ionic liquids and solvent-in-salt electrolytes, ion association is more complicated than simple ion-pairing. Large branched aggregates can form at significant…