Related papers: Gelation Paradox
Understanding the behavior of molecular systems under pressure is a fundamental problem in condensed matter physics. In the case of nitrogen, the determination of the phase diagram and in particular of the melting line, are largely open…
We propose that the origin of the Vogel-Fulcher-Tammann law is the increase of the range of elastic interaction between local relaxation events in a liquid. In this picture, we discuss the origin of cooperativity of relaxation, the absence…
Recent experiments on atom loss in ultra-cold Fermi gases all show a maximum at a magnetic field below Feshbach resonance, where the s-wave scattering length is large (close to inter-particle distance) and positive. These experiments have…
We consider the supercooled Stefan problem, which captures the freezing of a supercooled liquid, in one space dimension. A probabilistic reformulation of the problem allows to define global solutions, even in the presence of blow-ups of the…
It has been suggested by Timmermans [Phys. Rev. Lett. {\bf 87}, 240403 (2001)] that loss of fermions in a degenerate system causes strong heating. We address the fundamental limit imposed by this loss on the temperature that may be obtained…
It is well-known that evaporation can lead to cooling. However, little is known that evaporation can actually create a refrigeration effect, i.e., the vapor phase temperature can drop below the temperature of the cooling wall. This…
Melting is often understood in purely equilibrium terms, where crystalline order disappears once the free energy of the solid equals that of the liquid. Yet at the microscopic level, the initiating events for melting can often be traced to…
We study a two-component model for gelation consisting of $f$-functional monomers (the gel) and inert particles (the solvent). After equilibration as a simple liquid, the gel particles are gradually crosslinked to each other until the…
A microscopically motivated theory of glassy dynamics based on an underlying random first order transition is developed to explain the magnitude of free energy barriers for glassy relaxation. A variety of empirical correlations embodied in…
Nearly-logarithmic decay of correlations, which was observed for several supercooled liquids in optical-Kerr-effect experiments [G. Hinze et al. Phys. Rev. Lett. 84, 2437(2000), H. Cang et al. Phys. Rev. Lett. 90, 197401 (2003)], is…
We represent a theory of polymer gelation as an analogue of liquid-glass transition in which elastic fields of stress and strain shear components appear spontaneously as a consequence of the cross-linking of macromolecules. This…
We re-visit the issue of plasmon damping due to electron-electron interaction. The plasmon linewidth can related to the imaginary part of the charge susceptibility or, equivalently, to the real part of the optical conductivity,…
We consider the spatially homogeneous Boltzmann equation for inelastic hard spheres, in the framework of so-called constant normal restitution coefficients. We prove the existence of self-similar solutions, and we give pointwise estimates…
We prove strong convergence to singular limits for a linearized fully inhomogeneous Stefan problem subject to surface tension and kinetic undercooling effects. Different combinations of $\sigma \to \sigma_0$ and $\delta \to\delta_0$, where…
We consider heat semigroups of the form $\exp(t(\Delta - \lambda\mathbf{1}_{\Omega_0}))$ on bounded domains. These singularly perturbed equations arise in certain models of diffusion limited chemical reactions. Using variants of Moser…
In diluted lattices, cooperation is often enhanced at specific densities, particularly near the percolation threshold for stochastic updating rules. However, the Replicator rule, despite being probabilistic, does not follow this trend. We…
In irreversible aggregation processes droplets or polymers of microscopic size successively coalesce until a large cluster of macroscopic scale forms. This gelation transition is widely believed to be self-averaging, meaning that the order…
Abundance of chemical elements in the stars provides important clues regarding galaxy formation. The most powerful diagnostics is the relative abundance of {\alpha}-elements (O, Mg, Si, S, Ca, and Ti) with respect to iron (Fe),…
We show numeric evidence that, at low enough temperatures, the potential energy density of a glass-forming liquid fluctuates over length scales much larger than the interaction range. We focus on the behavior of translationally invariant…
Many predictions of Doppler cooling theory of two-level atoms have never been verified in a three-dimensional geometry, including the celebrated minimum achievable temperature $\hbar \Gamma/2 k_B$, where $\Gamma$ is the transition…