Related papers: Filling transitions in acute and open wedges
We use a microscopic density functional theory based on Wertheim's first order thermodynamic perturbation theory to study wetting behavior of athermal mixtures of colloids and excluded-volume polymers. In opposition to the wetting behavior…
We study the order of capillary condensation and evaporation transitions of a simple fluid adsorbed in a deep capillary groove using a fundamental measure density functional theory (DFT). The walls of the capillary interact with the fluid…
The global phase diagram of wetting in the two-dimensional (2d) Ising model is obtained through exact calculation of the surface excess free energy. Besides a surface field for inducing wetting, a surface-coupling enhancement is included.…
Wetting and drying of a rigid substrate by a Lennard-Jones fluid in molecular dynamics simulations is reported. The size of the substrate particles, being smaller than the fluid particles in former simulations, is now taken to be equal to,…
The properties of the coexisting bulk gas and liquid phases of a polydisperse fluid depend not only on the prevailing temperature, but also on the overall parent density. As a result, a polydisperse fluid near a wall will exhibit…
One of the most distinctive hallmarks of many-body systems far from equilibrium is the spontaneous emergence of order under conditions where disorder would be plausibly expected. Here, we report on the self-transition between ordered and…
In this article we calculate the surface phase diagram of a two-dimensional hard-rod fluid confined between two hard lines. In a first stage we study the semi-infinite system consisting of an isotropic fluid in contact with a single hard…
We study the interplay between wetting and miscibility of a symmetric polymer mixture via MC simulations and SCF calculations. The film surfaces interact with the monomers via short ranged potentials and the wetting transition is of first…
We study the transition between steady flows of non-cohesive granular materials in quasi-2D bounded heaps by suddenly changing the feed rate. In both experiments and simulations, the primary feature of the transition is a wedge of flowing…
We report results of wetting on non-planar and heterogeneous surfaces calculated from an effective interfacial Hamiltonian model. The lack of translational invariance along the substrate induces a series of structural changes on the…
Replica and functional renormalization group methods show that, with short range substrate forces or in strong fluctuation regimes, wetting of a self-affine rough wall in 2D turns first-order as soon as the wall roughness exponent exceeds…
Although realizing wetting transitions of droplets spontaneously on solid rough surfaces is quite challenging, it is becoming a key research topic in many practical applications which require highly efficient removal of liquid. We report…
We study phase behaviour of a model fluid confined between two unlike parallel walls in the presence of long range (dispersion) forces. Predictions obtained from macroscopic (geometric) and mesoscopic arguments are compared with numerical…
A model for nonequilibrium wetting in 1+1 dimensions is introduced. It comprises adsorption and desorption processes with a dynamics which generically does not obey detailed balance. Depending on the rates of the dynamical processes the…
A theory is constructed for dense ionic solutions near charged planar walls that is valid for strong inter-ionic correlations. This theory predicts a fluctuation-induced, first-order transition and spontaneous charge density ordering at the…
A comprehensive theory of interfacial fluctuation effects occurring at 2D wedge (corner) filling transitions in pure (thermal disorder) and impure (random bond-disorder) systems is presented. Scaling theory and the explicit results of…
We present the first detailed numerical study in three dimensions of a first-order phase transition that remains first-order in the presence of quenched disorder (specifically, the ferromagnetic/paramagnetic transition of the site-diluted…
Two numerical strategies based on the Wang-Landau and Lee entropic sampling schemes are implemented to investigate the first-order transition features of the 3D bimodal ($\pm h$) random-field Ising model at the strong disorder regime. We…
The wetting transition of the Blume-Capel model is studied by a finite-size scaling analysis of $L \times M$ lattices where competing boundary fields $\pm H_1$ act on the first row or last row of the $L$ rows in the strip, respectively. We…
Polymorphism is ubiquitous in crystalline solids. Amorphous solids, such as glassy water and silicon, may undergo amorphous-to-amorphous transitions (AATs). The nature of AATs remains ambiguous, due to diverse system-dependent behaviors and…