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We demonstrate that rectification ratios (RR) of >250 (>1000) at biases of 0.5 V (1.2 V) are achievable at the two-molecule limit for donor-acceptor bilayers of pentacene on fullerene on Cu using scanning tunneling spectroscopy and…

Mesoscale and Nanoscale Physics · Physics 2016-03-22 Joseph A. Smerdon , Noel C. Giebink , Nathan P. Guisinger , Pierre Darancet , Jeffrey R. Guest

Bipolar nanochannels comprising two domains of positively and negatively charged walls along the pore axis are known to rectify current when exposed to an electric potential bias. We find that addition of charged nanoparticles can increase…

We study theoretically the transport properties of a molecular two level system with large electron-vibron coupling in the Coulomb blockade regime. We show that when the electron-vibron coupling induces polaron states, the current-voltage…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Gregers A. Kaat , Karsten Flensberg

We report on inelastic electron tunneling spectroscopy measurements carried out on single molecules incorporated into a mechanically controllable break-junction of Au and Pt electrodes at low temperature. Here we establish a correlation…

Mesoscale and Nanoscale Physics · Physics 2010-11-16 Youngsang Kim , Hyunwook Song , Florian Strigl , Hans-Fridtjof Pernau , Takhee Lee , Elke Scheer

The energetic positions of molecular electronic states at molecule/electrode interfaces are crucial factors for determining the transport and optoelectronic properties of molecular junctions. Strong light--matter coupling offers a potential…

Mesoscale and Nanoscale Physics · Physics 2023-05-10 Kuniyuki Miwa , Souichi Sakamoto , Akihito Ishizaki

In this work, we review and expand recent theoretical proposals for the realization of electronic thermal diodes based on tunnel-junctions of normal metal and superconducting thin films. Starting from the basic rectifying properties of a…

Superconductivity · Physics 2015-03-18 Antonio Fornieri , María José Martínez-Pérez , Francesco Giazotto

We investigate the electronic transport through a molecule in the Kondo regime. The tunneling between the electrode and the molecule is asymmetrically modulated by the oscillations of the molecule, i.e., if the molecule gets closer to one…

Mesoscale and Nanoscale Physics · Physics 2008-12-09 J. Mravlje , A. Ramsak

The transport properties of serially coupled quantum dots (SCQDs) embedded in a matrix connected to metallic electrodes are theoretically studied in the linear and nonlinear regimes. The current rectification and negative differential…

Mesoscale and Nanoscale Physics · Physics 2015-06-12 Yen-Chun Tseng , David M. -T. Kuo

The influence of multiple vibrational modes on current fluctuations in electron transport through single-molecule junctions is investigated. Our analysis is based on a generic model of a molecular junction, which comprises a single…

Mesoscale and Nanoscale Physics · Physics 2014-09-26 C. Schinabeck , R. Härtle , H. B. Weber , M. Thoss

Thermal diode is a growing technology and important for active thermal flow control. Since the theoretical designing of thermal diode in 2004, various kinds of solid-state thermal diodes have been theoretically and experimentally…

Superconductivity · Physics 2025-10-02 Poonam Rani , Masayuki Mashiko , Keisuke Hirata , Ken-ichi Uchida , Yoshikazu Mizuguchi

We observe current rectification in a molecular diode consisting of a semiconducting single-wall carbon nanotube and an impurity. One half of the nanotube has no impurity, and it has a current-voltage (I-V) charcteristic of a typical…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 R. D. Antonov , A. T. Johnson

We study the optical rectification in a metallic tunnel junction. We consider a planar junction in a Kretschmann configuration and measure the photon-assisted tunneling under infrared illumination at $\lambda= 1.5\, \mu \mathrm{m}$. To…

Mesoscale and Nanoscale Physics · Physics 2022-07-29 P. Février , J. Basset , J. Estève , M. Aprili , J. Gabelli

One of the missing elements for realising an integrated optical circuit is a rectifying device playing the role of an optical diode. A proposal based on a pair of two-level atoms strongly coupled to a one-dimenisonal waveguide showed a…

Quantum Physics · Physics 2016-02-23 Jibo Dai , Alexandre Roulet , Huy Nguyen Le , Valerio Scarani

We derive an explicit expression for the quantum conductivity of a molecular wire containing a redox center, which is embedded in an electrochemical environment. The redox center interacts with the solvent, and the average over the solvent…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 A. V. B. Cruz , A. K. Mishra , W. Schmickler

We present theoretical and experimental studies of Schottky diodes that use aligned arrays of single walled carbon nanotubes. A simple physical model, taking into account the basic physics of current rectification, can adequately describe…

Mesoscale and Nanoscale Physics · Physics 2021-07-02 Xinning Ho , Lina Ye , Slava V. Rotkin , Xu Xie , Frank Du , Simon Dunham , Jana Zaumseil , John A. Rogers

Electronic devices composed of single molecules constitute the ultimate limit in the continued downscaling of electronic components. A key challenge for single-molecule electronics is to control the temperature of these junctions.…

Mesoscale and Nanoscale Physics · Physics 2016-04-08 Jacob Lykkebo , Giuseppe Romano , Alessio Gagliardi , Alessandro Pecchia , Gemma C. Solomon

Solid state electronics relies on the intentional introduction of impurity atoms or dopants into a semiconductor crystal and/or the formation of junctions between different materials (heterojunctions) to create rectifiers, potential…

Mesoscale and Nanoscale Physics · Physics 2017-04-05 Farzan Gity , Lida Ansari , Martin Lanius , Peter Schüffelgen , Gregor Mussler , Detlev Grützmacher , James C. Greer

In the field of molecular electronics, particularly in quantum transport studies, the orientation of molecules plays a crucial role. This orientation, with respect to the electrodes, can be defined through the cavity of ring-shaped…

Materials Science · Physics 2023-02-17 A. Martinez-Garcia , T. de Ara , L. Pastor-Amat , C. Untiedt , E. B. Lombardi , W. Dednam , C. Sabater

Electronic-vibrational coupling in single-molecule junctions may result in current-induced bond rupture and is thus an important mechanism for the stability of molecular junctions. We use the hierarchical quantum master equation (HQME)…

Mesoscale and Nanoscale Physics · Physics 2018-08-01 Andre Erpenbeck , Christian Schinabeck , Uri Peskin , Michael Thoss

We present an original method to estimate the conductivity of a single molecule anchored to nanometric-sized metallic electrodes, using a Mechanically Controlled Break Junction (MCBJ) operated at room temperature in liquid. We record the…

Mesoscale and Nanoscale Physics · Physics 2018-03-16 M. Gil , T. Malinowski , M. Iazykov , H. Klein