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Using first-principles density functional calculations, we study the electronic and magnetic properties of ferromagnetic insulating double-perovskite compound La2NiMnO6, which has been reported to exhibit interesting magnetic field…

Materials Science · Physics 2008-05-09 Hena Das , Umesh V. Waghmare , T. Saha-Dasgupta , D. D. Sarma

We used single-crystal x-ray and neutron diffraction to investigate the crystal and magnetic structures of trigonal lattice iridate Ca2Sr2IrO6. The crystal structure is determined to be $R\bar3$ with two distinct Ir sites. The system…

Strongly Correlated Electrons · Physics 2018-06-14 Jieming Sheng , Feng Ye , Christina Hoffmann , Valentino R. Cooper , Satoshi Okamoto , Jasminka Terzic , Hao Zheng , Hengdi Zhao , G. Cao

High quality epitaxial thin films of LaBiMn4/3Co2/3O6 perovskite were fabricated on (001)-oriented SrTiO3 and LaAlO3 substrates by the pulsed laser deposition technique. Magnetization measurements reveal a strong magnetic anisotropy and a…

Materials Science · Physics 2008-02-18 R. Ranjith , Asish K. Kundu , M. Filippi , B. Kundys , W. Prellier , B. Raveau , J. Laverdiere , M. P. Singh , S. Jandl

Advances in complex oxide heteroepitaxy have highlighted the enormous potential of utilizing strain engineering via lattice mismatch to control ferroelectricity in thin-film heterostructures. This approach, however, lacks the ability to…

Ferromagnetism and its evolution in the orthorhombic perovskite system Sr1-xCaxRuO3 have been widely believed to correlate with the structural distortion. The recent development of high-pressure synthesis of the Ba substituted Sr1-yBayRuO3…

Strongly Correlated Electrons · Physics 2015-06-17 J. -G. Cheng , J. -S. Zhou , J. B. Goodenough

The structural, magnetic and dielectric properties have been investigated in 3$d$-5$d$ based double perovskite Sr$_2$FeIrO$_6$ thin films deposited by pulse laser deposition technique. To understand the effect of strain, epitaxial films are…

Strongly Correlated Electrons · Physics 2020-12-02 K. C. Kharkwal , Roshan Kumar Patel , K. Asokan , A. K. Pramanik

Doped HfO2 and HfO2-ZrO2 compounds are gaining significant interest thanks to their ferroelectric properties in ultrathin films. Here, we show that ZrO2 could be a playground for doping and strain engineering to increase the thickness in…

Materials Science · Physics 2022-09-01 Ali El Boutaybi , Thomas Maroutian , Ludovic Largeau , Sylvia Matzen , Philippe Lecoeur

We observe two consecutive transitions in La1-xCaxMnO3, x=0.19: ferromagnetic ordering at Tc = 177 K and Jahn-Teller orbital ordering at T_JT = 150 K. The presence of a ferromagnetic insulating state below T_JT shows that the metallic phase…

Strongly Correlated Electrons · Physics 2007-05-23 Bas B. van Aken , Auke Meetsma , Thomas T. M. Palstra

Epitaxial bilayered thin films consisting of La0.6Sr0.4MnO3 (LSMO) and 0.7 Pb(Mg1/3Nb2/3)O3 0.3 PbTiO3 (PMN-PT) layers of relatively different thicknesses were fabricated on LaNiO3 coated LaAlO3 (100) single crystal substrates by pulsed…

Materials Science · Physics 2011-06-29 Ayan Roy Chaudhuri , S. B. Krupanidhi , P. Mandal , A. Sundaresan

We report the comprehensive experimental results identifying the magnetic spin ordering and the magnetization dynamics of a double perovskite Pr2CoFeO6 by employing the (dc and ac) magnetization, powder neutron diffraction (NPD) and X-ray…

The unconventional Si-compatible ferroelectricity in hafnia-based systems, which becomes robust only at nanoscopic sizes, has attracted a lot of interest. While a metastable polar orthorhombic (o-) phase (Pca21) is widely regarded as the…

Materials Science · Physics 2021-01-05 Pavan Nukala , Yingfen Wei , Vincent de Haas , Qikai Guo , Jordi Antoja-Lleonart , Beatriz Noheda

Much attention has been given recently to flexible and wearable integrated-electronic devices, with a strong emphasis on real-time sensing, computing and communication technologies. Thin ferroelectric films exhibit switchable polarization…

Applied Physics · Physics 2019-04-01 Rachel Onn Winestook , Cecile Saguy , Chun-Hao Ma , Ying-Hao Chu , Yachin Ivry

Recent observations of unusual ferroelectricity in thin films of HfO_2 and related materials have attracted broad interest to the materials and led to the emergence of a number of competing models for observed behaviors. Here we develop the…

Materials Science · Physics 2018-11-27 Maya D. Glinchuk , Anna N. Morozovska , Yunseok Kim , Sergei V. Kalinin

Pyroelectric current and magnetoelectric coupling measurements on polycrystalline samples of the quadruple perovskite (LaMn$_{3}$)Mn$_{4}$O$_{12}$ give evidence of ferroelectricity driven by the antiferromagnetic ordering of the $B$-site…

We put forward double perovskites of the R$_2$NiMnO$_6$ family (with $R$ a rare-earth atom) as a new class of multiferroics on the basis of {\it ab initio} density functional calculations. We show that changing $R$ from La to Y drives the…

Strongly Correlated Electrons · Physics 2015-05-14 Sanjeev Kumar , Gianluca Giovannetti , Jeroen van den Brink , Silvia Picozzi

We report a detailed magnetic, dielectric and Raman studies on partially disordered and biphasic double perovskite La2NiMnO6. DC and AC magnetic susceptibility measurements show two magnetic anomalies at TC1 ~ 270 K and TC2 ~ 240 K, which…

Materials Science · Physics 2015-06-18 Pradeep Kumar , S. Ghara , B. Rajeswaran , D. V. S. Muthu , A. Sundaresan , A. K. Sood

The structural, electronic, magnetic and ferroelectric properties of Pb free double perovskite multiferroic Bi2FeTiO6 are investigated using density functional theory within the general gradient approximation (GGA) method. Our structural…

Materials Science · Physics 2018-05-23 Lokanath Patra , P. Ravindran

Density functional calculations are performed to study the effect of epitaxial strain on PbZrO3. We find a remarkably small energy difference between the epitaxially strained polar R3c and nonpolar Pbam structures over the full range of…

Materials Science · Physics 2014-05-15 Sebastian E. Reyes-Lillo , Karin M. Rabe

In this work multiferroic thin films of Bi containing perovskite oxides are discussed, where the driving force for ferroelectricity are the Bi3+ lone-pair electrons. First, a brief introduction of Bi containing multiferroic perovskite…

Strongly Correlated Electrons · Physics 2014-02-11 Rainer Schmidt , Eric Langenberg , Jofre Ventura , Manuel Varela

Double perovskites Sr2FeOsO6 and Ca2FeOsO6 show puzzling magnetic properties, the former a low-temperature antiferromagnet while the later a high-temperature insulating ferrimagnet. Here, in order to understand the underlying mechanism, we…

Materials Science · Physics 2015-08-24 Yusheng Hou , Hongjun Xiang , Xingao Gong