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We present results of electronic band structure, Fermi surface and electron transport properties calculations in orthorhombic $n$- and $p$-type SnSe, applying Korringa-Kohn-Rostoker method and Boltzmann transport approach. The analysis…

Materials Science · Physics 2015-05-11 K. Kutorasinski , B. Wiendlocha , S. Kaprzyk , J. Tobola

Excellent thermoelectric performance in the out-of-layer n-doped SnSe has been observed experimentally (Chang et al., Science 360, 778-783 (2018)). However, a first-principles investigation of the dominant scattering mechanisms governing…

Materials Science · Physics 2021-09-29 Anderson S. Chaves , Daniel T. Larson , Efthimios Kaxiras , Alex Antonelli

We conduct comprehensive investigations of both thermal and electrical transport properties of SnSe and SnS using first-principles calculations combined with the Boltzmann transport theory. Due to the distinct layered lattice structure,…

Materials Science · Physics 2015-10-14 Ruiqiang Guo , Xinjiang Wang , Youdi Kuang , Baoling Huang

The reliable calculation of electronic structures and understanding of electrical properties depends on an accurate model of the crystal structure. Here, we have reinvestigated the crystal structure of the high-zT thermoelectric material…

Materials Science · Physics 2018-08-14 I. Loa , S. R. Popuri , A. D. Fortes , J. W. G. Bos

We study the electronic transport coefficients and the thermoelectric figure of merit ZT in $n$-doped Mg$_3$Sb$_2$ based on density-functional electronic structure and Bloch-Boltzmann transport theory with an energy- and…

Materials Science · Physics 2019-01-07 Roberta Farris , Maria Barbara Maccioni , Alessio Filippetti , Vincenzo Fiorentini

The unique structure of Zintl phase makes it an ideal system to realize the concept of phonon-glass and electron-crystal in the thermoelectric community. In this work, by combining first-principles calculations and Boltzmann transport…

Materials Science · Physics 2017-08-01 S. Huang , H. J. Liu , D. D. Fan , P. H. Jiang , J. H. Liang , G. H. Cao , J. Shi

SnSe is a topical thermoelectric material with a low thermal conductivity which is linked to its unique crystal structure. We use low-temperature heat capacity measurements to demonstrate the presence of two characteristic vibrational…

Materials Science · Physics 2017-06-22 S. R. Popuri , M. Pollet , R. Decourt , M. L. Viciu , J. W. G. Bos

Using first-principles method and Boltzmann theory, we provide an accurate prediction of the electronic band structure and thermoelectric transport properties of alpha-MgAgSb. Our calculations demonstrate that only when an appropriate…

Materials Science · Physics 2016-06-22 C. Y. Sheng , H. J. Liu , D. D. Fan , L. Cheng , J. Zhang J. Wei , J. H. Liang , P. H. Jiang , J. Shi

The record-breaking thermoelectric performance of tin selenide (SnSe) has motivated the investigation of analogue compounds with the same structure. A promising candidate that emerged recently is germanium selenide (GeSe). Here, using…

Materials Science · Physics 2022-02-15 Anderson S. Chaves , Daniel T. Larson , Efthimios Kaxiras , Alex Antonelli

The electronic, phonon and thermoelectric transport properties of (PbTe)2 layer are systematically investigated by using first-principles pseudopotential method and Boltzmann transport equation. Our calculations demonstrate that there is a…

Materials Science · Physics 2020-03-04 Caiyu Sheng , Dengdong Fan , Huijun Liu

The band structure of the novel low-temperature thermoelectric material, \CBT, is calculated and analyzed using the semi-classic transport equations. It is shown that to obtain a quantitative agreement with measured transport properties a…

Materials Science · Physics 2007-05-23 Lars Lykke , Bo B. Iversen , Georg K. H. Madsen

The binary compound SnSe exhibits record high thermoelectric performance, largely because of its very low thermal conductivity. The origin of the strong phonon anharmonicity leading to the low thermal conductivity of SnSe is investigated…

Materials Science · Physics 2019-11-12 Jiawang Hong , Olivier Delaire

Improving the thermoelectric efficiency is one of the greatest challenges in materials science. The recent discovery of excellent thermoelectric performance in simple orthorhombic SnSe crystal offers new promise in this prospect [Zhao et…

Materials Science · Physics 2015-05-12 Guangqian Ding , Guoying Gao , Kailun Yao

The electronic and transport properties of the half-Heusler compound LaPtSb are investigated by performing first-principles calculations combined with semi-classical Boltzmann theory and deformation potential theory. Compared with many…

Materials Science · Physics 2016-06-13 Q. Y. Xue , H. J. Liu , D. D. Fan , L. Cheng , B. Y. Zhao , J. Shi

We used density functional and many-body perturbation theory to calculate the quasiparticle band structures and electronic transport parameters of p-type SnSe both for the low-temperature Pnma and high-temperature Cmcm phases. The Pnma…

Materials Science · Physics 2015-06-19 Guangsha Shi , Emmanouil Kioupakis

In order to improve the thermoelectric performance of TiCoSb we have substituted 50% of Ti equally with Zr and Hf at Ti site and Sb with Sn and Se equally at Sb site. The electronic structure of Ti0.5Zr0.25Hf0.25CoSn0.5Se0.5 is investigated…

Materials Science · Physics 2018-05-09 Mukesh K. Choudhary , P Ravindran

The electronic and transport properties of CuInTe2 chalcopyrite are investigated using density functional calculations combined with Boltzmann theory. The band gap predicted from hybrid functional is 0.92 eV, which agrees well with…

Materials Science · Physics 2016-01-06 J. Wei , H. J. Liu , L. Cheng , J. Zhang , J. H. Liang , P. H. Jiang , D. D. Fan , J. Shi

In this work, we try to understand the experimental thermoelectric (TE) properties of a ZrNiSn sample with DFT and semiclassical transport calculations using SCAN functional. SCAN and mBJ provide the same band gap $E_{g}$ of $\sim$0.54 eV.…

Strongly Correlated Electrons · Physics 2020-06-24 Shivprasad S. Shastri , Sudhir K. Pandey

In this first-principles study, we investigated the thermoelectric properties of the full-Heusler compound CsK$_2$Sb at different compressive strains. This material exhibits a valence band structure with significant effective mass…

Materials Science · Physics 2025-05-14 Øven A. Grimenes , G. Jeffrey Snyder , Ole M. Løvvik , Kristian Berland

Electron-crystal and phonon-glass are regarded as two essential factors for ideal thermoelectric materials, which require both an enhanced electronic transport and a depressed phononic transport. These two characteristics usually can not…

Materials Science · Physics 2016-06-29 Guangqian Ding , Guoying Gao , KailunYao
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