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Atomic disorder, a widespread problem in compound crystalline materials, is a imperative affecting the performance of multi-chalcogenide Cu2ZnSn(S, Se)4 (CZTSSe) photovoltaic device known for its low cost and environmental friendliness.…

Cation site disorder provides a degree of freedom in the growth of ternary nitrides for tuning the technologically relevant properties of a material system. For example, the band gap of ZnGeN$_2$ changes when the ordering of the structure…

Materials Science · Physics 2022-01-20 Jacob J. Cordell , Garritt J. Tucker , Adele C. Tamboli , Stephan Lany

Magnetic semiconductors may soon improve the energy efficiency of computers, but materials exhibiting these dual properties remain underexplored. Here, we report the computational prediction and realization of a new magnetic and…

This paper addresses the effect of disorder on the carrier transport mechanism of atomic layer deposited ZnO thin films as has been investigated by temperature dependent electrical resistivity measurements in the temperature range of 4.2K…

Materials Science · Physics 2013-01-08 D. Saha , Amit. K. Das , R. S. Ajimsha , P. Misra , L. M. Kukreja

Cu$_2$ZnSnS$_4$ is an earth-abundant photovoltaic absorber material predicted to provide a sustainable solution for commercial solar applications. One of the main limitations restricting its commercialization is the issue of cation…

Materials Science · Physics 2021-01-13 S. P. Ramkumar , H. P. C. Miranda , X. Gonze , G. -M. Rignanese

A novel feature of electron transport is explored through a thin film of varying impurity density with the distance from its surface. The film, attached to two metallic electrodes, is described by simple tight-binding model and its coupling…

Mesoscale and Nanoscale Physics · Physics 2009-09-15 Santanu K. Maiti

We study experimentally and theoretically the effects of disorder, nonlinear screening, and magnetism in semiconductor heterostructures containing a $\delta$-layer of Mn, where the charge carriers are confined within a quantum well and…

Mesoscale and Nanoscale Physics · Physics 2013-05-29 Vikram Tripathi , Kusum Dhochak , B. A. Aronzon , V. V. Rylkov , A. B. Davydov , Bertrand Raquet , Michel Goiran , K. I. Kugel

ZnSnN2 has recently garnered increasing interest as a potential solar absorber material due to its direct bandgap that is predicted to be tunable from 1.0-2.1 eV based on cation disorder. One important challenge to the further development…

Materials Science · Physics 2016-11-17 Angela N. Fioretti , Eric S. Toberer , Andriy Zakutayev , Adele C. Tamboli

Since the prediction of spin-gapless semiconducting behaviour in the Heusler compound Mn$_2$CoAl, evidence of spin-gapless behaviour in thin films has typically been inferred from magnetotransport measurements. The spin gapless state is…

Materials Science · Physics 2019-09-06 Robert G. Buckley , Tane Butler , Catherine Pot , Nicholas M. Strickland , Simon Granville

We report persistent photoconductivity in $p$-type Sb$_2$Se$_3$ single crystals doped with Cd or Zn, where enhanced conductivity remains for hours after illumination ceases at temperatures below $\sim$25~K. Comparative transport and…

Materials Science · Physics 2025-10-17 F. Herklotz , E. V. Lavrov , T. D. C. Hobson , T. P. Shalvey , J. D. Major , K. Durose

Electrical and thermal transport properties of Cu-deficient kuramite Cu3-xSnS4 (CTS) was examined as a possible earth-abundant thermoelectric material. Crystallographic structure of CTS was characterized by partial disorder between Cu and…

Materials Science · Physics 2015-06-23 Yosuke Goto , Yuki Sakai , Yoichi Kamihara , Masanori Matoba

Realistic, first-principles-based interatomic potentials have been used in molecular dynamics simulations to study the effect of cation composition on the ionic conductivity in the Zr2Y2O7-Y3NbO7 system and to link the dynamical properties…

Chemical Physics · Physics 2009-09-09 Dario Marrocchelli , Paul A Madden , Stefan T Norberg , Stephen Hull

The charge carrier transport in metal phthallocyanine based disordered thin films has been investigated. Charge carrier mobility in these disordered thin films strongly depends on the electric field and temperature due to hopping…

Disordered Systems and Neural Networks · Physics 2015-06-25 Ajit Kumar Mahapatro , Subhasis Ghosh

Semi-transparent photovoltaic devices for building integrated applications have the potential to provide simultaneous power generation and natural light penetration. CuIn$_{1-x}$Ga$_x$Se$_2$ (CIGS) has been established as a mature…

Mossbauer analysis is carried out on CZTS samples, subjected to a low temperature processing at 3000C (S1) and high temperature processing at 5500C under sulfur environment (S2). Loss of Sn is observed in sample S2 due to high temperature…

Applied Physics · Physics 2018-08-07 Goutam Kumar Gupta , V R Reddy , Ambesh Dixit

Owing high conductivity in microcrystalline thin-films, CsSnI3 perovskite is a promising semiconductor for thermoelectrics and optoelectronics. Rapid oxidation of thin-film and intrinsic lattice strain hinders stabilization of the device…

The controlled introduction of covalent sp$^{3}$ defects into semiconducting single-walled carbon nanotubes (SWCNTs) gives rise to exciton localization and red-shifted near-infrared luminescence. The single-photon emission characteristics…

Materials Science · Physics 2022-06-22 Wenhao Zheng , Nicolas F. Zorn , Mischa Bonn , Jana Zaumseil , Hai I. Wang

The effect of disorder on the superconducting transition temperature $T_{c}$ of cuprate superconductors is examined. Disorder is introduced into the cation sites in the plane adjacent to the CuO$_{2}$ planes of two single-layer systems,…

Superconductivity · Physics 2009-11-11 K. Fujita , T. Noda , K. M. Kojima , H. Eisaki , S. Uchida

Strong disorder has a crucial effect on the electronic structure in quantum materials by increasing localization, interactions, and modifying the density of states. Bi$_x$TeI films grown at room temperature and \SI{230}{K} exhibit dramatic…

Materials Science · Physics 2023-06-06 Paul Corbae , Nicolai Taufertshöfer , Ellis Kennedy , Mary Scott , Frances Hellman

We propose a low-cost approach for the synthesis of multifunctional CuSnS3 (CTS) ternary compound thin film via spray pyrolysis technique. By varying Sn and S doping concentrations, a high energy absorber layers of CuSnS3 thin films were…

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