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Crystal structure prediction methods and first-principles calculations have been used to explore low-energy structures of carbon monoxide (CO). Contrary to the standard wisdom, the most stable structure of CO at ambient pressure was found…

Materials Science · Physics 2017-04-06 Kang Xia , Jian Sun , Chris J. Pickard , Dennis D. Klug , Richard J. Needs

The recent discovery of methods to isolate graphene, a one-atom-thick layer of crystalline carbon, has raised the possibility of a new class of nano-electronics devices based on the extraordinary electrical transport and unusual physical…

Mesoscale and Nanoscale Physics · Physics 2008-10-02 Xu Du , Ivan Skachko , Anthony Barker , Eva Y. Andrei

The discovery of fullerenes has stimulated extensive exploration of the resulting behavior of adsorbed films. Our study addresses the planar substrates graphene-fluoride (GF) and graphane (GH) in comparison to graphene. We present initial…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 L. Reatto , M. Nava , D. E. Galli , C. Billman , J. O. Sofo , M. W. Cole

We determine, by means of density functional theory, the stability and the structure of graphene nanoribbon (GNR) edges in presence of molecules such as oxygen, water, ammonia, and carbon dioxide. As in the case of hydrogen-terminated…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Ari P. Seitsonen , A. Marco Saitta , Tobias Wassmann , Michele Lazzeri , Francesco Mauri

Hydrogenated graphene edges are assumed to be either armchair, zigzag or a combination of the two. We show that the zigzag is not the most stable fully hydrogenated structure along the <2-1-10> direction. Instead hydrogenated Klein and…

Density functional calculations of electronic structure, total energy, structural distortions, and magnetism for hydrogenated single-layer, bilayer, and multi-layer graphene are performed. It is found that hydrogen-induced magnetism can…

Materials Science · Physics 2008-01-24 D. W. Boukhvalov , M. I. Katsnelson , A. I. Lichtenstein

In this work, we focus on the fermionic structure of the low-energy excitations of graphene (a monolayer of carbon atoms) to propose a new supersymmetric field-theoretic model for this physical system. In the current literature, other…

Four sp3 carbon allotropes with six, eight, and 16 atoms per primitive cell have been derived using a combination of metadynamics simulations and topological scan. A chiral orthorhombic phase oC16 (C2221) was found to be harder than…

Materials Science · Physics 2012-06-26 Daniele Selli , Igor A. Baburin , Roman Martoňák , Stefano Leoni

Silica or SiO$_2$, the main constituent of earth's rocks has several 3D complex crystalline and amorphous phases, but it does not have a graphite like layered structure in 3D. Our theoretical analysis and numerical calculations from the…

Mesoscale and Nanoscale Physics · Physics 2014-06-24 V. Ongun Özçelik , S. Cahangirov , S. Ciraci

The formation of one-dimensional carbon chains from graphene nanoribbons is investigated using it ab initio molecular dynamics. We show under what conditions it is possible to obtain a linear atomic chain via pulling of the graphene…

Materials Science · Physics 2015-05-14 Edwin Hobi , Renato B. Pontes , A. Fazzio , Antonio J. R. da Silva

Ubiquitous graphene is a stricly 2D material representing an ideal adsorbing platform due to its large specific surface area as well as its mechanical strength and resistance to both thermal and chemical stresses. However, graphene as a…

Materials Science · Physics 2016-10-06 Massimiliano Bartolomei , Giacomo Giorgi

The lithium-carbon binary system possesses a broad range of chemical compounds, which exhibit fascinating chemical bonding characteristics that give rise diverse and technologically important properties. While lithium carbides with various…

Materials Science · Physics 2016-07-13 Yangzheng Lin , Timothy A. Strobel , R. E. Cohen

The power of polymorphism in carbon is vividly manifested by the numerous applications of carbon-based nano-materials. Ranging from environmental issues to biomedical applications, it has the potential to address many of today's dire…

Materials Science · Physics 2017-03-28 Obaidur Rahaman , Bohayra Mortazavi , Arezoo Dianat , Gianaurelio Cuniberti , Timon Rabczuk

We report on various nanocarbons formed from a unique structural pattern containing two pentagons, three hexagons and two heptagons, resulting from local rearrange- ments around a divacancy in pristine graphene or nanotubes. This defect can…

Materials Science · Physics 2015-06-03 Jean-Marc Leyssale , G érard L. Vignoles , Antoine Villesuzanne

We show that graphene, in its simplest form and settings, is a practical table-top realization of the analog of exotic quantum gravity scenarios, which are speculated to lead to certain generalized Heisenberg algebras. In particular, we…

General Relativity and Quantum Cosmology · Physics 2022-12-22 Alfredo Iorio , Boris Ivetić , Salvatore Mignemi , Pablo Pais

We address the energetic stability of the graphene/SiC(0001) interface and the associated binding mechanism by studying a series of low-strain commensurate interface structures within a density functional scheme. Among the structures with…

Mesoscale and Nanoscale Physics · Physics 2012-05-23 Gabriele Sclauzero , Alfredo Pasquarello

Research on graphene and other two-dimensional atomic crystals is intense and likely to remain one of the hottest topics in condensed matter physics and materials science for many years. Looking beyond this field, isolated atomic planes can…

Materials Science · Physics 2013-07-26 A. K. Geim , I. V. Grigorieva

The thermal stability of graphene/graphane nanoribbons (GGNRs) is investigated using density functional theory. It is found that the energy barriers for the diffusion of hydrogen atoms on the zigzag and armchair interfaces of GGNRs are 2.86…

Materials Science · Physics 2015-03-17 Z. M. Ao , A. D. Hernández-Nieves , F. M. Peeters , S. Li

N-graphdiyne monolayers, a set of carbon-nitride nanosheets, have been synthesized recently through the polymerization of triazine- and pyrazine-based monomers. Since the two-dimensional nano-structures are mainly composed of light-weight…

Computational Physics · Physics 2018-12-27 Meysam Makaremi , Bohayra Mortazavi , Timon Rabczuk , Geoffrey A. Ozin , Chandra Veer Singh

Designing new 2D systems with tunable properties is an important subject for science and technology. Starting from graphene, we developed an algorithm to systematically generate 2D carbon crystals belonging to the family of graphdiynes…

Materials Science · Physics 2021-03-25 Patrick Serafini , Alberto Milani , Davide M. Proserpio , Carlo S. Casari