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We investigate the structural, electronic and magnetic properties of the newly synthesized mineral barlowite Cu4(OH)6FBr which contains Cu2+ ions in a perfect kagome arrangement. In contrast to the spin-liquid candidate herbertsmithite…

The search for quantum spin liquid (QSL) materials has attracted significant attention in the field of condensed matter physics in recent years, but until now only a handful of them are considered as candidates hosting QSL ground state.…

Strongly Correlated Electrons · Physics 2018-12-17 Zili Feng , Wei Yi , Kejia Zhu , Jie Ma , Jianlin Luo , Shiliang Li , Zi Yang Meng , Youguo Shi

Geometric frustration of magnetic ions can lead to a quantum spin liquid ground state where long range magnetic order is avoided despite strong exchange interactions. The physical realization of quantum spin liquids comprises a major…

Strongly Correlated Electrons · Physics 2023-06-07 Alex Hallett , Catalina Avarvarei , John W. Harter

Synthetic barlowite, Cu4(OH)6BrF, has emerged as a new quantum spin liquid (QSL) host, containing kagome layers of S=1/2 Cu2+ ions separated by interlayer Cu2+ ions. Similar to synthetic herbertsmithite, ZnCu3(OH)6Cl2, it has been reported…

Strongly Correlated Electrons · Physics 2018-05-02 C. M. Pasco , B. A. Trump , Thao T. Tran , Z. A. Kelly , C. Hoffmann , I. Heinmaa , R. Stern , T. M. McQueen

The spin-$\frac{1}{2}$ kagome antiferromagnet is considered an ideal host for a quantum spin liquid ground state. We find that when the bonds of the kagome lattice are modulated with a periodic pattern, new quantum ground states emerge.…

Herbertsmithite and Zn-doped barlowite are two compounds for experimental realization of twodimensional gapped kagome spin liquid. Theoretically, it has been proposed that charge doping a quantum spin liquid gives rise to exotic metallic…

Strongly Correlated Electrons · Physics 2018-10-17 Wei Jiang , Huaqing Huang , Jiawei Mei , Feng Liu

We present thermodynamic studies of a new spin-1/2 antiferromagnet containing undistorted kagome lattices---barlowite Cu$_{4}$(OH)$_{6}$FBr. Magnetic susceptibility gives $\theta_{CW}$ = $-$136 K, while long-range order does not happen…

Strongly Correlated Electrons · Physics 2014-12-05 Tian-Heng Han , John Singleton , John A. Schlueter

Herbertsmithite, ZnCu$_3$(OH)$_6$Cl$_2$, is a two dimensional kagom\'{e} lattice realization of a spin liquid, with evidence for fractionalized excitations and a gapped ground state. Such a quantum spin liquid has been proposed to underlie…

Strongly Correlated Electrons · Physics 2016-10-18 Z. A. Kelly , M. J. Gallagher , T. M. McQueen

Barlowite Cu$_4$(OH)$_6$FBr shows three-dimensional (3D) long-range antiferromagnetism, which is fully suppressed in Cu$_3$Zn(OH)$_6$FBr with a kagome quantum spin liquid ground state. Here we report systematic studies on the evolution of…

Realizing a quantum spin liquid (QSL) ground state in a real material is a leading issue in condensed matter physics research. In this pursuit, it is crucial to fully characterize the structure and influence of defects, as these can…

Materials with a perfect kagome lattice structure of magnetic ions are intensively sought for, because they may exhibit exotic ground states like the a quantum spin liquid phase. Barlowite is a natural mineral that features perfect kagome…

Strongly Correlated Electrons · Physics 2016-09-22 Daniel Guterding , Roser Valenti , Harald O. Jeschke

We report muSR experiments on Mg{x}Cu{4-x}(OH)6Cl2 with x \sim 1, a new material isostructural to Herbertsmithite exhibiting regular kagome planes of spin 1/2 (Cu^{2+}), and therefore a candidate for a spin liquid ground state. We evidence…

Strongly Correlated Electrons · Physics 2014-10-06 E. Kermarrec , P. Mendels , F. Bert , R. H. Colman , A. S. Wills , P. Strobel , P. Bonville , A. Hillier , A. Amato

A quantum spin liquid (QSL) is an exotic quantum state of matter characterized by fluctuating spins which may exhibit long-range entanglement. Among the possible host candidates for a QSL ground state, the $S$=1/2 kagome lattice…

The mineral barlowite, Cu$_4$(OH)$_6$FBr, has been the focus of recent attention due to the possibility of substituting the interlayer Cu$^{2+}$ site with non-magnetic ions to develop new quantum spin liquid materials. We re-examine…

Strongly Correlated Electrons · Physics 2018-08-21 Rebecca W. Smaha , Wei He , John P. Sheckelton , Jiajia Wen , Young S. Lee

The kagome Heisenberg antiferromagnet formed by frustrated spins arranged in a lattice of corner-sharing triangles is a prime candidate for hosting a quantum spin liquid (QSL) ground state consisting of entangled spin singlets. But the…

Strongly Correlated Electrons · Physics 2022-03-09 Jiaming Wang , Weishi Yuan , Philip M. Singer , Rebecca W. Smaha , Wei He , Jiajia Wen , Young S. Lee , Takashi Imai

The discovery of ideal spin-1/2 kagome antiferromagnets Herbertsmithite and Zn-doped Barlowite represents a breakthrough in the quest for quantum spin liquids (QSLs), and nuclear magnetic resonance (NMR) spectroscopy plays a prominent role…

Strongly Correlated Electrons · Physics 2019-12-06 Shunhong Zhang , Yi Zhou , Feng Liu , Zheng Liu

A quantum spin liquid (QSL) is a state of matter in which magnetic spins interact strongly, but quantum fluctuations inhibit long-range magnetic order even at zero temperature. A QSL has been predicted to have a host of exotic properties,…

Barlowite, Cu$_{4}$(OH)$_{6}$FBr, has attracted much attention as the parent compound of a new series of quantum spin liquid candidates, Zn$_{x}$Cu$_{4-x}$(OH)$_{6}$FBr. While it is known to undergo a magnetic phase transition to a…

Strongly Correlated Electrons · Physics 2018-12-05 K. Tustain , G. J. Nilsen , C. Ritter , I. da Silva , L. Clark

Herbertsmithite, ZnCu3(OH)6Cl2, is the prototype candidate for a spin liquid behavior on a geometrically perfect kagome lattice. Its discovery and the absence of any evidence for spin-freezing down to the lowest probed temperature to-date…

Strongly Correlated Electrons · Physics 2015-05-28 P. Mendels , F. Bert

Remarkably, doping isovalent $d^{10}$ and $d^0$ cations onto the $B$'' site in $A_2B$'$B$''O$_6$ double perovskites has the power to direct the magnetic interactions between magnetic $B$' cations. This is due to changes in orbital…

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