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We construct a non-perturbative approach based on quantum averaging combined with resonant transformations to detect the resonances of a given Hamiltonian and to treat them. This approach, that generalizes the rotating-wave approximation,…

Quantum Physics · Physics 2007-05-23 M. Amniat-Talab , S. Guerin , H. R. Jauslin

The computation of vibrational spectra of diatomic molecules through the exact diagonalization of algebraically determined matrixes based on powers of Morse coordinates is made substantially more efficient by choosing a properly adapted…

Chemical Physics · Physics 2016-09-28 Andrea Bordoni , Nicola Manini

Developing the isolation and control of ultracold atomic systems to the level of single quanta has led to significant advances in quantum sensing, yet demonstrating a quantum advantage in real world applications by harnessing entanglement…

Molecular quantum sensors represent a promising frontier for the detection of nuclear magnetic resonance signals and alternating current magnetic fields at the nanoscale, potentially reaching single-proton sensitivity. Although the triplet…

Chemical Physics · Physics 2026-05-18 Maria Grazia Concilio , Yiwen Wang , Siyuan Wang , Xueqian Kong

We spectroscopically investigate the hyperfine, rotational and Zeeman structure of the vibrational levels $\text{v}'=0$, $7$, $13$ within the electronically excited $c^3\Sigma_g^+$ state of $^{87}\text{Rb}_2$ for magnetic fields of up to…

A robust variational approach is used to investigate the sensitivity of the rotation-vibration spectrum of phosphine (PH$_3$) to a possible cosmological variation of the proton-to-electron mass ratio, $\mu$. Whilst the majority of computed…

Cosmology and Nongalactic Astrophysics · Physics 2018-08-17 Alec Owens , Sergei N. Yurchenko , Vladimir Špirko

Quantum resources can enhance the sensitivity of a device beyond the classical shot noise limit and, as a result, revolutionize the field of metrology through the development of quantum-enhanced sensors. In particular, plasmonic sensors,…

A molecular rotor mechanism is proposed to explain weak magnetic field effects in biology. Despite being nanoscale (1 nm), this rotor exhibits quantum superposition and interference. Analytical modeling shows its quantum dynamics are highly…

Biological Physics · Physics 2025-12-18 V. N. Binhi

We determine the theoretical limits to squeezing-enhanced measurement sensitivity of mechanical motion in a cavity optomechanical system. The motion of a mechanical resonator is transduced onto quadrature fluctuations of a cavity optical…

Quantum Physics · Physics 2016-11-30 Hugo Kerdoncuff , Ulrich B. Hoff , Glen I. Harris , Warwick P. Bowen , Ulrik L. Andersen

Spins are prototypical systems with the potential to probe magnetic fields down to the atomic scale limit. Exploiting their quantum nature through appropriate sensing protocols allows to enlarge their applicability to fields not always…

Quantum Physics · Physics 2024-04-26 Claudio Bonizzoni , Alberto Ghirri , Fabio Santanni , Marco Affronte

This chapter takes a microscopic view of quantum tunneling of magnetization (QTM) in single-molecule magnets (SMMs), focusing on the interplay between exchange and anisotropy. Careful consideration is given to the relationship between…

Mesoscale and Nanoscale Physics · Physics 2013-03-04 Junjie Liu , Enrique del Barco , Stephen Hill

The orthogonality of cat and displaced cat states, underlying Heisenberg limited measurement in quantum metrology, is studied in the limit of large number of states. The asymptotic expression for the corresponding state overlap function,…

Quantum Physics · Physics 2015-11-11 Raman Sharma , Suranjana Ghosh , Utpal Roy , Prasanta K. Panigrahi

Quantum effects, such as entanglement, Einstein-Podolsky-Rosen steering, and Bell correlations, can enhance metrological sensitivity beyond the standard quantum limit. These correlations are typically generated through interactions between…

Quantum Physics · Physics 2025-07-16 Danish Ali Hamza , Jan Chwedeńczuk

Quantum enhanced sensing is a powerful technique in which nonclassical states are used to improve the sensitivity of a measurement. For enhanced mechanical displacement sensing, squeezed states of light have been shown to reduce the photon…

Quantum Physics · Physics 2016-07-05 Jeremy B. Clark , Florent Lecocq , Raymond W. Simmonds , José Aumentado , John D. Teufel

Quantum sensors are powerful devices that exploit quantum effects to detect minute quantities with extremely high precision. Two obstacles to harnessing the full capacity of quantum probes are the resource-intensive preparation of the probe…

Quantum Physics · Physics 2025-08-28 Dingwei Zhao , Abolfazl Bayat , Victor Montenegro

Quantum metrology utilizes entanglement for improving the sensitivity of measurements. Up to now the focus has been on the measurement of just one out of two non-commuting observables. Here we demonstrate a laser interferometer that…

Recently proposed quantum-chaotic sensors achieve quantum enhancements in measurement precision by applying nonlinear control pulses to the dynamics of the quantum sensor while using classical initial states that are easy to prepare. Here,…

Quantum Physics · Physics 2020-03-11 Jonas Schuff , Lukas J. Fiderer , Daniel Braun

We construct quantum error-correcting codes that embed a finite-dimensional code space in the infinite-dimensional Hilbert state space of rotational states of a rigid body. These codes, which protect against both drift in the body's…

Quantum Physics · Physics 2020-09-09 Victor V. Albert , Jacob P. Covey , John Preskill

By exploiting the correlation properties of ultracold atoms in a multi-mode interferometer, we show how quantum enhanced measurement precision can be achieved with strong robustness to particle loss. While the potential for enhanced…

Quantum Physics · Physics 2012-04-03 J. J. Cooper , D. W. Hallwood , J. A. Dunningham , J. Brand

Pushing the boundaries of measurement precision is central for sensing and metrology, pursued by nonclassical resources such as squeezing, and non-Hermitian degeneracies with distinct spectral response. Their convergence, however, remains…