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The theoretical investigation of non-adiabatic processes is hampered by the complexity of the coupled electron-nuclear dynamics beyond the Born-Oppenheimer approximation. Classically, the simulation of such reactions is limited by the…

Quantum Physics · Physics 2021-01-06 Pauline J. Ollitrault , Guglielmo Mazzola , Ivano Tavernelli

We present an efficient \textit{ab initio} algorithm for quantum dynamics simulations of interacting systems that is based on the conditional decomposition of the many-body wavefunction [Phys. Rev. Lett. 113, 083003 (2014)]. Starting with…

Mesoscale and Nanoscale Physics · Physics 2019-02-27 Guillermo Albareda , Aaron Kelly , Angel Rubio

We propose an approach to the quantum-classical correspondence based on a deformation of the momentum and kinetic operators of quantum mechanics. Making use of the factorization method, we construct classical versions of the momentum and…

Quantum Physics · Physics 2007-05-23 Ricardo A. Mosna , Ian P. Hamilton , Luigi Delle Site

We address nonsequential double ionization induced by strong, linearly polarized laser fields of only a few cycles, considering a physical mechanism in which the second electron is dislodged by the inelastic collision of the first electron…

Atomic Physics · Physics 2009-11-10 C. Figueira de Morisson Faria , X. Liu , A. Sanpera , M. Lewenstein

We study dynamics of nonclassical correlations by exactly solving a model consisting of two atomic qubits with spontaneous emission. We find that the nonclassical correlations defined by different measures give different qualitative…

Quantum Physics · Physics 2012-02-01 Ming-Liang Hu , Heng Fan

Incorporating nuclear quantum effects into nonadiabatic dynamics remains a significant challenge. Herein we introduce new nonadiabatic dynamics approaches based on the recently developed constrained nuclear-electronic orbital (CNEO) theory.…

Chemical Physics · Physics 2025-04-15 Zhe Liu , Zehua Chen , Yang Yang

In this thesis concrete quantum systems are investigated in the framework of the environment induced decoherence. The focus is on the dynamics of highly nonclassical quantum states, the Wigner function of which are negative over some…

Quantum Physics · Physics 2007-05-23 Peter Foldi

A non-equilibrium theory describing the charge qubit dynamics measured by a quantum point contact is developed based on Schwinger-Keldysh's approach. Using the real-time diagram technique, we derive the master equation to all orders in…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Ming-Tsung Lee , Wei-Min Zhang

We discuss the evolution of purity in mixed quantum/classical approaches to electronic nonadiabatic dynamics in the context of the Ehrenfest model. As it is impossible to exactly determine initial conditions for a realistic system, we…

Chemical Physics · Physics 2012-09-07 J. L. Alonso , J. Clemente-Gallardo , J. C. Cuchí , P. Echenique , F. Falceto

A new approximate solution to the quantum-classical Liouville equation is derived starting from the formal solution of this equation in forward-backward form. The time evolution of a mixed quantum-classical system described by this equation…

Chemical Physics · Physics 2015-06-05 Chang-Yu Hsieh , Raymond Kapral

The dominant source of decoherence for an electron spin in a quantum dot is the hyperfine interaction with the surrounding bath of nuclear spins. The decoherence process may be slowed down by subjecting the electron spin to suitable…

Mesoscale and Nanoscale Physics · Physics 2017-08-23 Wenxian Zhang , V. V. Dobrovitski , Lea F. Santos , Lorenza Viola , B. N. Harmon

Motivated by various systems in which quantum effects occur in classical backgrounds, we consider the dynamics of a classical particle as described by a coherent state that is coupled to a quantum bath via bi-quadratic interactions. We…

High Energy Physics - Theory · Physics 2018-02-06 Tanmay Vachaspati

Quantum nuclear dynamics with wavepacket time-evolution is classically intractable and viewed as a promising avenue for quantum information processing. Here, we use an IonQ 11-qubit trapped-ion quantum computer, Harmony, to study the…

Quantum Physics · Physics 2024-12-05 Anurag Dwivedi , A. J. Rasmusson , Philip Richerme , Srinivasan S. Iyengar

One of the central problems in quantum theory is to characterize, detect, and quantify quantumness in terms of classical strategies. Dephasing processes, caused by non-dissipative information exchange between quantum systems and…

Quantum Physics · Physics 2019-08-23 Hong-Bin Chen , Ping-Yuan Lo , Clemens Gneiting , Joonwoo Bae , Yueh-Nan Chen , Franco Nori

We look at the time dependent fluctuations of the electrical charge in an open 1D quantum system represented by a quantum dot experiencing random lateral motion. In essentially non-adiabatic settings we study both diffusive and ballistic…

Chaotic Dynamics · Physics 2016-04-19 Stanislav Derevyanko , Daniel Waltner

A first principles quantum formalism to describe the non-adiabatic dynamics of electrons and nuclei based on a second quantization representation (SQR) of the electronic motion combined with the usual representation of the nuclear…

Chemical Physics · Physics 2020-11-06 Sudip Sasmal , Oriol Vendrell

The dynamics of a quantum system following a sudden, highly non-adiabatic change of its control parameter (quantum quench) is studied with quasiclassical techniques. Recent works have shown, using exact quantum mechanical approach, that…

A direct classical analog of the quantum dynamics of intrinsic decoherence in Hamiltonian systems, characterized by the time dependence of the linear entropy of the reduced density operator, is introduced. The similarities and differences…

Quantum Physics · Physics 2009-11-10 Jiangbin Gong , Paul Brumer

Recently some authors have pointed out that there exist nonclassical correlations which are more general, and possibly more fundamental, than entanglement. For these general quantum correlations and their classical counterparts, under the…

Quantum Physics · Physics 2009-10-08 J. Maziero , L. C. Celeri , R. M. Serra , V. Vedral

Coupled trajectory mixed quantum classical (CTMQC) dynamics is a rigorous approach to trajectory-based non-adiabatic dynamics, which has recently seen an improvement to energy conservation via the introduction of the CTMQC-E algorithm.…

Quantum Physics · Physics 2023-10-12 Aaron Dines , Matthew Ellis , Jochen Blumberger