Related papers: Microscopic theory for electrocaloric effects in p…
We utilize the self-consistent field theory to explore the mechanical and electrical properties of charged surfaces immersed in polyelectrolyte solutions that could be potentially useful for electrochemical applications. Our research…
A major challenge in modelling interfacial processes in electrochemical (EC) devices is performing simulations at constant potential. This requires an open-boundary description of the electrons, so that they can enter and leave the…
Mean-field theory is used to model polyelectrolyte adsorption and the possibility of overcompensation of charged surfaces. For charged surfaces that are also chemically attractive, the overcharging is large in high salt conditions,…
Using molecular simulation, we assess the impact of an electric field on the properties of water, modeled with the SPC/E potential, over a wide range of states and conditions. Electric fields of the order of $0.1V/$\AA and beyond are found…
The development of advanced electrochemical devices for energy conversion and storage requires fine tuning of electrode reactions, which can be accomplished by altering the electrode/solution interface structure. Particularly, in case of an…
An applied electric field can reversibly change the temperature of an electrocaloric material under adiabatic conditions, and the effect is strongest near phase transitions. This phenomenon has been largely ignored because only small…
We study the role of ionic correlations on the electroosmotic flow in planar double-slit channels, without salt. We propose an analytical theory, based on recent advances in the understanding of correlated systems. We compare the theory…
We report the discovery of serendipitous electrocaloric effects in commercial multilayer capacitors based on ferroelectric BaTiO3. Direct thermometry records ~0.5 K changes due to 300 kV cm-1, over a wide range of temperatures near and…
We propose a novel actuation mechanism for colloids, which is based on the Seebeck effect of the electrolyte solution: Laser heating of a nonionic particle accumulates in its vicinity a net charge Q, which is proportional to the excess…
An atomistic effective Hamiltonian is used to compute electrocaloric (EC) effects in rare-earth substituted BiFeO$_{3}$ multiferroics. A phenomenological model is then developed to interpret these computations, with this model indicating…
Calculations of heat transfer between two plates of gold in an extreme near field is performed taking into account the existence of the electric double layer on metal surfaces. For d < 3nm the double layer contribution exceeds the…
Despite the ubiquity of aqueous electrolytes, the effect of salt on water organization remains controversial. We introduce a nonlocal and nonlinear field theory for the nanoscale polarization of ions and water and derive the electrolyte…
Caloric responses (temperature changes) can be induced in solid-state materials by applying external stimuli such as stress, pressure, and electric and magnetic fields. The magnetic-field-stimulated response is called the magnetocaloric…
The electrocaloric effect (ECE), i.e., the reversible temperature change due to the adiabatic variation of the electric field, is of great interest due to its potential technological applications. Based on entropy arguments, we present a…
An efficient cooling effect is put forward, by means of external electric or magnetic fields along hysteresis loops. A simplified model of hysteresis is used for numerical illustration. The model is based upon a second-order expansion of…
The multicaloric effect is defined as the adiabatic temperature change in multiferroic materials induced by the application of an external electric or magnetic field, and it was first proposed in 2012. The multicaloric effects in…
We employ an effective-field theory with correlations in order to study a magnetocaloric effect on a triangular Ising antiferromagnet, which is selectively diluted by non-magnetic impurities on one of the three sublattices. Such a dilution…
Giant electrocaloric (EC) effect is observed in BaTiO3 multilayer thick film structure. The temperature change is as high as 4.0 oC under an applied electric field of 352 kV/cm. Most importantly, the EC effect is found to depend on the…
In the present article we intend to accomplish a rigorous analysis which allows to elaborate useful symbolic and numerical codes leading to an accurate evaluation of the thermal radiation. We will consider the case of the electromagnetic…
Understanding the electrical double layer (EDL), i.e, the distribution of electrolyte at an electrified interface, in concentrated electrolytes is important for various technologies, such as supercapacitors, batteries and electrocatalysis.…