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In this paper, we introduce a new scheme for the efficient numerical treatment of the electronic Schr\"odinger equation for molecules. It is based on the combination of a many-body expansion, which corresponds to the so-called bond order…

Numerical Analysis · Mathematics 2017-07-20 Sambasiva Rao Chinnamsetty , Michael Griebel , Jan Hamaekers

We investigate the multi-particle states of the (1+1)-dimensional Ising model using a spectroscopy scheme based on the tensor renormalization group method. We start by computing the finite-volume energy spectrum of the model from the…

High Energy Physics - Lattice · Physics 2026-02-17 Fathiyya Izzatun Az-zahra , Shinji Takeda , Takeshi Yamazaki

Spectroscopic techniques are essential tools for determining the structure of molecules. Different spectroscopic techniques, such as Nuclear magnetic resonance (NMR), Infrared spectroscopy, and Mass Spectrometry, provide insight into the…

Chemical Physics · Physics 2024-10-30 Marvin Alberts , Oliver Schilter , Federico Zipoli , Nina Hartrampf , Teodoro Laino

A spectral method is developed for the direct solution of linear ordinary differential equations with variable coefficients. The method leads to matrices which are almost banded, and a numerical solver is presented that takes O(m^2n)…

Numerical Analysis · Mathematics 2012-08-16 Sheehan Olver , Alex Townsend

The influence of continuous measurements of energy with a finite accuracy is studied in various quantum systems through a restriction of the Feynman path-integrals around the measurement result. The method, which is equivalent to consider…

Condensed Matter · Physics 2009-10-22 Ubaldo Tambini , Roberto Onofrio , Carlo Presilla

Energy levels of neutral atoms have been re-examined by applying an alternative perturbative scheme in solving the Schrodinger equation for the Yukawa potential model with a modified screening parameter. The predicted shell binding energies…

Quantum Physics · Physics 2009-11-11 Sameer M. Ikhdair , Ramazan Sever

The progress in high-precision spectroscopy requires one to verify the accuracy of theoretical models such as the master equation describing spontaneous emission of atoms. For this purpose, we apply the coarse-graining method to derive a…

Quantum Physics · Physics 2016-10-26 Andreas Alexander Buchheit , Giovanna Morigi

We present a refinement of the Spectral Method by incorporating an optimization method into it and generalize it to two space dimensions. We then apply this Refined Spectral Method as an extremely accurate technique for finding the bound…

Mathematical Physics · Physics 2007-05-23 P. Pedram , M. Mirzaei , S. S. Gousheh

The spectroscopic quality of covariant density functional theory has been accessed by analyzing the accuracy and theoretical uncertainties in the description of spectroscopic observables. Such analysis is first presented for the energies of…

Nuclear Theory · Physics 2015-08-25 A. V. Afanasjev

In this study, we employ exact quantization rule (EQR) to derive the analytical approximate l-wave solutions of the Schrodinger equation with the general molecular oscillator (GMO). The energy eigenvalues equation and the corresponding wave…

Chemical Physics · Physics 2020-11-03 D. Yabwa , E. S. Eyube , Y. Ibrahim , V. Targema

We substantiate the need for account of the proper electromagnetic field of the electron in the canonical problem of hydrogen in relativistic quantum mechanics. From mathematical viewpoint, the goal is equivalent to determination of the…

Quantum Physics · Physics 2021-01-12 Leon V. Biguaa , Vladimir V. Kassandrov

Circular dichroism spectroscopy is an essential technique for understanding molecular structure and magnetic materials, but spatial resolution is limited by the wavelength of light, and sensitivity sufficient for single-molecule…

Spectroscopy has an illustrious history delivering serendipitous discoveries and providing a stringent testbed for new physical predictions, including applications from trace materials detection, to understanding the atmospheres of stars…

Atomic Physics · Physics 2015-01-05 Gar-Wing Truong , James D. Anstie , Eric F. May , Thomas M. Stace , Andre N. Luiten

Duo is a general, user-friendly program for computing rotational, rovibrational and rovibronic spectra of diatomic molecules. Duo solves the Schr\"{o}dinger equation for the motion of the nuclei not only for the simple case of uncoupled,…

Computational Physics · Physics 2016-07-05 Sergei N. Yurchenko , Lorenzo Lodi , Jonathan Tennyson , Andrey V. Stolyarov

The analytic solutions of the spatially-dependent mass Schrodinger equation of diatomic molecules with the centrifugal term l(l+1)/r2 for the generalized q-deformed Morse potential are obtained approximately by means of a parametric…

Quantum Physics · Physics 2015-05-13 Sameer Ikhdair

Finding accurate solutions to the Schr\"odinger equation is the key unsolved challenge of computational chemistry. Given its importance for the development of new chemical compounds, decades of research have been dedicated to this problem,…

Machine Learning · Computer Science 2022-10-12 Leon Gerard , Michael Scherbela , Philipp Marquetand , Philipp Grohs

With the aim of describing bound and continuum states for diatomic molecules, we develop and implement a spectral method that makes use of Generalized Sturmian Functions (GSF) in prolate spheroidal coordinates. In order to master all…

Atomic and Molecular Clusters · Physics 2021-06-02 D. M. Mitnik , F. A. Lopez , L. U. Ancarani

Resonant solutions of the quantum Schr\"odinger equation occur at complex energies where the S-matrix becomes singular. Knowledge of such resonances is important in the study of the underlying physical system. Often the Schr\"odinger…

Mathematical Physics · Physics 2016-08-24 Przemysław Kłosiewicz , Wim Vanroose , Jan Broeckhove

Spectroscopic properties of molecules holds great importance for the description of the molecular response under the effect of an UV/Vis electromagnetic radiation. Computationally expensive ab initio (e.g. MultiConfigurational SCF, Coupled…

We investigate optimal control strategies for state to state transitions in a model of a quantum dot molecule containing two active strongly interacting electrons. The Schrodinger equation is solved nonperturbatively in conjunction with…

Quantum Physics · Physics 2016-08-14 R. Nepstad , L. Sælen , I. Degani , J. P. Hansen
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