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We calculate the double resonant (DR) Raman spectrum of graphene, and determine the lines associated to both phonon-defect processes, and two-phonons ones. Phonon and electronic dispersions reproduce calculations based on density functional…

Mesoscale and Nanoscale Physics · Physics 2011-07-26 Pedro Venezuela , Michele Lazzeri , Francesco Mauri

The experimental Raman spectra of graphene exhibit a few intense two-phonon bands, which are enhanced through double-resonant scattering processes. Though there are many theoretical papers on this topic, none of them predicts the spectra…

Mesoscale and Nanoscale Physics · Physics 2014-12-17 Valentin N. Popov , Philippe Lambin

An experimental study of Raman scattering in N-layer graphene as a function of the top layer doping is reported. At high doping level, achieved by a CHF_3 plasma treatment, we observe a splitting of the $G$ band in the spectra of bilayer…

Mesoscale and Nanoscale Physics · Physics 2010-03-23 M. Bruna , S. Borini

We present low-temperature Raman measurements on gate tunable graphene encapsulated in hexagonal boron nitride, which allows to study in detail the Raman G and 2D mode frequencies and line widths as function of the charge carrier density.…

Mesoscale and Nanoscale Physics · Physics 2023-02-15 Jens Sonntag , Kenji Watanabe , Takashi Taniguchi , Bernd Beschoten , Christoph Stampfer

We have revisited the still unresolved puzzle of the dispersion of the Raman disordered-induced D band as a function of laser excitation photon energy E$_L$ in graphite-like materials. We propose that the D-mode is a combination of an optic…

Disordered Systems and Neural Networks · Physics 2009-11-07 A. K. Sood , Rajeev Gupta , S. A. Asher

Magneto Raman scattering study of the E$_{2g}$ optical phonons in multi-layer epitaxial graphene grown on a carbon face of SiC are presented. At 4.2K in magnetic field up to 33 T, we observe a series of well pronounced avoided crossings…

Materials Science · Physics 2015-05-13 C. Faugeras , M. Amado , P. Kossacki , M. Orlita , M. Sprinkle , C. Berger , W. A. de Heer , M. Potemski

We use polarized magneto-Raman scattering to study purely electronic excitations and the electron-phonon coupling in bulk graphite. At a temperature of 4.2 K and in magnetic fields up to 28 T we observe $K$-point electronic excitations…

Mesoscale and Nanoscale Physics · Physics 2015-05-30 P. Kossacki , C. Faugeras , M. Kühne , M. Orlita , A. A. L. Nicolet , J. M. Schneider , D. M. Basko , Y. I. Latyshev , M. Potemski

We report multiphonon Raman scattering in graphene samples. Higher order combination modes involving 3 phonons and 4 phonons are observed in single-layer (SLG), bi-layer (BLG), and few layer (FLG) graphene samples prepared by mechanical…

Mesoscale and Nanoscale Physics · Physics 2015-05-30 Rahul Rao , Derek Tishler , Jyoti Katoch , Masa Ishigami

The properties of pristine, free-standing graphene monolayers prepared by mechanical exfoliation of graphite are investigated. The graphene monolayers, suspended over open trenches, are examined by means of spatially resolved Raman…

Materials Science · Physics 2009-01-08 Stephane Berciaud , Sunmin Ryu , Louis E. Brus , Tony F. Heinz

Results of room temperature Raman scattering studies of ultrathin graphitic films supported on Si (111)/SiO2 substrates are reported. The results are significantly different from those known for graphite. Spectra were collected using 514 nm…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Awnish Gupta , Gugang Chen , P. Joshi , S. Tadigadapa , P. C. Eklund

We present a computational study of the two-phonon Raman spectra of silicene and graphene within a density-functional non-orthogonal tight-binding model. Due to the presence of linear bands close to the Fermi energy in the electronic…

Mesoscale and Nanoscale Physics · Physics 2016-04-29 Valentin N. Popov , Philippe Lambin

We perform Raman scattering experiments on natural graphite in magnetic fields up to 45 T, observing a series of peaks due to interband electronic excitations over a much broader magnetic field range than previously reported. We also…

Mesoscale and Nanoscale Physics · Physics 2012-03-14 Y. Kim , Y. Ma , A. Imambekov , N. G. Kalugin , A. Lombardo , A. C. Ferrari , J. Kono , D. Smirnov

Under homogeneous uniaxial strains, the Raman 2D band of graphene involving two-phonon double-resonance scattering processes splits into two peaks and they altogether redshift strongly depending on the direction and magnitude of the strain.…

Mesoscale and Nanoscale Physics · Physics 2015-03-19 Duhee Yoon , Young-Woo Son , Hyeonsik Cheong

We have studied, both experimentally and theoretically, the change of the so-called 2D band of the Raman scattering spectrum of graphene (the two-phonon peak near 2700 cm-1) in an external magnetic field applied perpendicular to the…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 C. Faugeras , P. Kossacki , D. M. Basko , M. Amado , M. Sprinkle , C. Berger , W. A. de Heer , M. Potemski

The band structure of bilayer graphene is tunable by introducing a relative twist angle between the two layers, unlocking exotic phases, such as superconductor and Mott insulator, and providing a fertile ground for new physics. At…

Mesoscale and Nanoscale Physics · Physics 2021-07-28 Matthew C. DeCapua , Yueh-Chun Wu , Takashi Taniguchi , Kenji Watanabe , Jun Yan

Radio-frequency compressed ultrafast electron diffraction has been used to probe the coherent and incoherent coupling of impulsive electronic excitation at 1.55 eV (800 nm) to optical and acoustic phonon modes directly from the perspective…

Materials Science · Physics 2015-06-23 Robert P. Chatelain , Vance R. Morrison , Bart L. M. Klarenaar , Bradley J. Siwick

The scattering of lattice excitations (phonons) with the photoexcited charge carriers is of a major concern in optoelectronic devices. Here, the resonant Raman scattering will be utilized to study an exciton-phonon interaction in GaN…

The micro-Raman scattering response of a graphene-like location on the surface of bulk natural graphite is investigated both at $T=\unit{4.2}{K}$ and at room temperature in magnetic fields up to 29 T. Two different polarization…

Mesoscale and Nanoscale Physics · Physics 2014-10-03 M. Kuhne , C. Faugeras , P. Kossacki , A. A. L. Nicolet , M. Orlita , Yu. I. Latyshev , M. Potemski

We perform polarization-resolved Raman spectroscopy on graphene in magnetic fields up to 45T. This reveals a filling-factor-dependent, multi-component anticrossing structure of the Raman G peak, resulting from magnetophonon resonances…

Mesoscale and Nanoscale Physics · Physics 2013-06-20 Y. Kim , J. M. Poumirol , A. Lombardo , N. G. Kalugin , T. Georgiou , Y. J. Kim , K. S. Novoselov , A. C. Ferrari , J. Kono , O. Kashuba , V. I. Fal'ko , D. Smirnov

We report the observation of an intense anomalous peak at 1608 cm$^{-1}$ in the Raman spectrum of graphene associated to the presence of chromium nanoparticles in contact with graphene. Bombardment with an electron beam demonstrates that…