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Molecular Dynamics simulations of a coarse-grained bead-spring model of flexible macromolecules tethered with one end to the surface of a cylindrical pore are presented. Chain length $N$ and grafting density $\sigma$ are varied over a wide…

Soft Condensed Matter · Physics 2007-05-23 Dimitar I. Dimitrov , Andrey Milchev , Kurt Binder , Dieter W. Heermann

Using the observation that slip in simple fluids at low and moderate shear rates is a thermally activated process driven by the shear stress in the fluid close to the solid boundary, we develop a molecular-kinetic model for simple fluid…

Fluid Dynamics · Physics 2019-07-03 Gerald J. Wang , Nicolas G. Hadjiconstantinou

The adhesion between a polymer melt and substrate is studied in the presence of chemically attached chains on the substrate surface. Extensive molecular dynamics simulations have been carried out to study the effect of temperature, tethered…

Materials Science · Physics 2016-08-31 Scott W. Sides , Gary S. Grest , Mark J. Stevens

Conformations of a single-component bottle-brush polymer with a fully flexible backbone under poor solvent conditions are studied by molecular-dynamics simulations, using a coarse-grained bead-spring model with side chains of up to N=40…

Soft Condensed Matter · Physics 2013-06-25 Nikolaos G. Fytas , Panagiotis E. Theodorakis

All-atom molecular dynamics simulations of an elastohydrodynamic lubrication oil film are performed to study the effect of pressure. Fluid molecules of n-hexane are confined between two solid plates under a constant normal force of 0.1--8.0…

Soft Condensed Matter · Physics 2018-05-29 Hitoshi Washizu , Toshihide Ohmori , Atsushi Suzuki

The dynamic behavior of a partially wetting polymer droplet driven over a nanostructured interface is studied using molecular dynamics simulations. We consider the bead-spring model to represent a polymeric liquid that partially wets a…

Soft Condensed Matter · Physics 2020-06-17 Anish Thomas , Nikolai V. Priezjev

We propose a dynamical theory of low-temperature shear deformation in amorphous solids. Our analysis is based on molecular-dynamics simulations of a two-dimensional, two-component noncrystalline system. These numerical simulations reveal…

Statistical Mechanics · Physics 2009-10-30 M. L. Falk , J. S. Langer

Polymer nanofibers with high thermal conductivities and outstanding thermal stabilities are highly desirable in heat transfer-critical applications such as thermal management, heat exchangers and energy storage. In this work, we unlock the…

Chemical Physics · Physics 2014-09-12 Teng Zhang , Xufei Wu , Tengfei Luo

We study the nonequilibrium kinetics during the coil-globule transition of a flexible polymer chain with active beads after a quench from good to poor solvent condition using molecular dynamics simulation. Activity for each bead is…

Soft Condensed Matter · Physics 2022-04-13 Subhajit Paul , Suman Majumder , Wolfhard Janke

The properties of polymer liquids on hard and soft substrates are investigated by molecular dynamics simulation of a coarse-grained bead-spring model and dynamic single-chain-in-mean-field (SCMF) simulations of a soft, coarse-grained…

Soft Condensed Matter · Physics 2015-05-18 F. Léonforte , J. Servantie , C. Pastorino , M. Müller

The physical behavior of glass-forming liquids presents complex features of both dynamic and thermodynamic nature. Some studies indicate the presence of thermodynamic anomalies and of crossovers in the dynamic properties, but their origin…

Statistical Mechanics · Physics 2018-06-08 Daniele Coslovich , Misaki Ozawa , Walter Kob

Droplet motion over a surface with wettability gradient has been simulated using molecular dynamics (MD) simulation to highlight the underlying physics. GROMACS and Visual Molecular Dynamics (VMD) were used for simulation and intermittent…

Fluid Dynamics · Physics 2015-04-13 Monojit Chakraborty , Anamika Chowdhury , Richa Bhusan , Sunando DasGupta

We review recent results from computer simulation studies of polymer glasses, from chain dynamics around the glass transition temperature Tg to the mechanical behaviour below Tg. These results clearly show that modern computer simulations…

Materials Science · Physics 2010-09-29 Jean-Louis Barrat , Joerg Baschnagel , Alexei Lyulin

Recent molecular dynamics simulation methods have enabled thermal conductivity of bulk materials to be estimated. In these simulations, periodic boundary conditions are used to extend the system dimensions to the thermodynamic limit. Such a…

Materials Science · Physics 2012-06-26 X. W. Zhou , R. E. Jones , S. Aubry

Generation of equilibrium configurations is the major obstacle for numerical investigation of the slow dynamics in supercooled liquid states. The parallel tempering (PT) technique, originally proposed for the numerical equilibration of…

Soft Condensed Matter · Physics 2009-11-07 Cristiano De Michele , Francesco Sciortino

The free surface of glassy polymers exhibits enhanced segmental dynamics compared to the bulk, forming a liquid-like layer that lowers the glass transition temperature (Tg) in nanometersized polymer samples. Recent studies have shown that…

Soft Condensed Matter · Physics 2025-05-12 Xinyu Zhang , Christian Pedersen , Haoqi Zhu , Siming Wang , Yuchen Fu , Liang Dai , Andreas Carlson , Thomas Salez , Yu Chai

Nonequilibrium molecular dynamics simulations are used to study the shear thinning behavior of immiscible symmetric polymer blends. The phase separated polymers are subjected to a simple shear flow imposed by moving a wall parallel to the…

Soft Condensed Matter · Physics 2009-11-07 Sandra Barsky , Mark O. Robbins

Molecular dynamics simulations are used to study fluidization of a vertically vibrated, three-dimensional shallow granular layer. As the container acceleration is increased above g, the granular temperature and root mean square particle…

Soft Condensed Matter · Physics 2007-08-01 Jennifer Kreft , Matthias Schroeter , Jack B. Swift , Harry L. Swinney

Despite the desirability of polymers for use in many products due to their flexibility, light weight, and durability, their status as thermal insulators has precluded their use in applications where thermal conductors are required. However,…

Computational Physics · Physics 2023-10-26 Ethan Abraham , Mohammadhasan Dinpajooh , Clàudia Climent , Abraham Nitzan

Molecular dynamics simulations are used to study structure formation in simple model polymer chains that are subject to excluded volume and torsional interactions. The changing conformations exhibited by chains of different lengths under…

Soft Condensed Matter · Physics 2009-11-07 D. C. Rapaport