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Using the extended discrete interaction model we investigate the tuneabilty of surface plasmon resonance in alloys and core-shell nanoparticles made from silver and gold. We show that the surface plasmon resonance of these alloys and…

The static response properties and the structural stability of silver clusters in the size range $1\le n \le 23$ have been studied using a linear combination of atomic Gaussian-type orbitals within the density functional theory in the…

Atomic and Molecular Clusters · Physics 2009-11-13 M. Pereiro , D. Baldomir

We simulate the localized surface plasmon resonances of an Au nanoparticle within tunneling proximity of a Au substrate and demonstrate that the modes may be identified with those responsible for light emission from a scanning tunneling…

Mesoscale and Nanoscale Physics · Physics 2012-07-18 J. Mitra , Lei Feng , Michael G. Boyle , P. Dawson

Cathodoluminescence spectroscopy has been performed on silver nanoparticles in a scanning electron microscopy setup. Peaks appearing in the visible range for particles fabricated on silicon substrate are shown to arrive from excitation of…

Optics · Physics 2009-06-08 Pratik Chaturvedi , Keng Hsu , Anil Kumar , James C. Mabon , Nicholas Fang

We have investigated the effects of tuning the localized surface plasmon resonances (LSPRs) of silver nanoparticles on the fluorescence intensity, lifetime, and Raman signal from nearby fluorophores. The presence of a metallic structure can…

Other Condensed Matter · Physics 2009-11-13 N. I. Cade , T. Ritman-Meer , D. Richards

We derive a time-dependent density functional theory appropriate for calculating the near-edge X-ray absorption spectrum in molecules and condensed matter. The basic assumption is to increase the space of many-body wave functions from one…

Strongly Correlated Electrons · Physics 2015-06-16 G. F. Bertsch , A. Lee

We present theoretical and experimental studies of the optical response of L-shaped silver nanoparticles. The scattering spectrum exhibits several plasmon resonances that depend sensitively on the polarization of the incident…

Optics · Physics 2007-11-14 Maxim Sukharev , Jiha Sung , Kenneth G. Spears , Tamar Seideman

Clear influence of particle size, surfactants and dispersion medium on surface plasmon resonance (SPR) features of Ag nanoparticles (NPs), synthesized in thermal decomposition method, in the broad range of ultraviolet (UV) radiation,…

Applied Physics · Physics 2020-01-29 Vikash Sharma , Divya Verma , Gunadhor Singh Okram

In local effective potential theories of electronic structure, the electron correlations due to the Pauli exclusion principle, Coulomb repulsion, and correlation-kinetic effects, are all incorporated in the local electron-interaction…

Materials Science · Physics 2007-05-23 Zhixin Qian , Viraht Sahni

A many-body Green's function approach to the microscopic theory of plasmon-enhanced spectroscopy is presented within the context of localized surface-plasmon resonance spectroscopy and applied to investigate the coupling between…

Chemical Physics · Physics 2015-05-14 David J. Masiello , George C. Schatz

We present a new strategy, based on a Fresnel coefficient pole analysis, for designing an asymmetric multilayer structure that supports long range surface plasmons (LRSP). We find that the electric field intensity in the metal layer of a…

Optics · Physics 2013-07-17 Aida Delfan , J. E. Sipe

We summarize our recent results that model the formation of uniform spherical silver colloids prepared by mixing iso-ascorbic acid and silver-amine complex solutions in the absence of dispersants. We found that the experimental results can…

Soft Condensed Matter · Physics 2010-09-22 Ionel Halaciuga , Daniel T. Robb , Vladimir Privman , Dan V. Goia

This study presents a self-consistent, quantum-informed model for the decay dynamics of localized surface plasmons (LSPs) in spherical metal nanoparticles (NPs), described as plasmonic quasi-particles (PQPs). By bridging classical…

Optics · Physics 2026-05-15 Krystyna Kolwas

We have performed self-consistent calculations of the dynamical response of the (111) surface of the noble metals Cu, Ag, and Au. Our results indicate that the partially occupied surface-state band in these materials yields the existence of…

Materials Science · Physics 2009-11-11 V. M. Silkin , J. M. Pitarke , E. V. Chulkov , P. M. Echenique

The ability to confine light down to atomic scales is critical for the development of applications in optoelectronics and optical sensing as well as for the exploration of nanoscale quantum phenomena. Plasmons in metallic nanostructures can…

Linear clusters made by tightly connecting two or more metallic nanoparticles have new types of surface plasmon resonances as compared to isolated nanoparticles. These new resonances are related to the size of the junction and to the number…

Mesoscale and Nanoscale Physics · Physics 2011-05-18 Titus Sandu , Daniel Vrinceanu , Eugen Gheorghiu

In this research we present a theory of the surface plasmon resonance (SPR) effect based on the dual length-scale driven damped collective quantum oscillations of the spill-out electrons in plasmonic material surface. The metallic electron…

Mesoscale and Nanoscale Physics · Physics 2023-02-28 M. Akbari-Moghanjoughi

Spherical gold nanoclusters are grown by 1.8 MeV Au++ ion implantation into an amorphous silica matrix and subsequent air annealing at 873 K. Ultraviolet and visible light absorption confirms the presence of a dipolar surface plasmon peak…

Other Condensed Matter · Physics 2007-05-23 Daniel B. Murray , S. Dhara , T. R. Ravindran , K. G. M. Nair , S. Kalavathi , Lucien Saviot , Eugene Duval

Multipolar plasmon oscillation frequencies and corresponding damping rates for nanospheres formed of the simplest free-electron metals are studied. The possibility of controlling plasmon features by choosing the size and dielectric…

Optics · Physics 2008-04-15 A. Derkachova , K. Kolwas

Investigating nanoplasmonics using time-dependent approaches permits shedding light on the dynamic optical properties of plasmonic structures, which are intrinsically connected with their potential applications in photochemistry and…

Mesoscale and Nanoscale Physics · Physics 2024-06-18 Piero Lafiosca , Luca Nicoli , Silvio Pipolo , Stefano Corni , Tommaso Giovannini , Chiara Cappelli