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A novel quantum dynamical method to simulate vibronic reaction dynamics in molecules at metal surfaces is proposed. The method is based on the hierarchical quantum master equation approach and uses a discrete variable representation of the…

Chemical Physics · Physics 2019-12-05 A. Erpenbeck , M. Thoss

Microscopic master equations have gained traction for the dissipative treatment of molecular spin and solid-state systems for quantum technologies. Single particle approximations are often invoked to treat these systems, which can lead to…

Quantum Physics · Physics 2026-02-12 Mikayla Z. Fahrenbruch , Anthony W. Schlimgen , Kade Head-Marsden

Mean-field molecular dynamics based on path integrals is used to approximate canonical quantum observables for particle systems consisting of nuclei and electrons. A computational bottleneck is the sampling from the Gibbs density of the…

Numerical Analysis · Mathematics 2023-11-30 Xin Huang , Petr Plechac , Mattias Sandberg , Anders Szepessy

We derive the general form of a master equation describing the interaction of an arbitrary multipartite quantum system, consisting of a set of subsystems, with an environment, consisting of a large number of sub-envirobments. Each subsystem…

Quantum Physics · Physics 2015-05-28 Vittorio Giovannetti , G. Massimo Palma

Quantum master equations are common tools to describe the dynamics of many-body systems open to an environment. Due to the interaction with the latter, even for the case of non-interacting electrons, the computational cost to solve these…

Other Condensed Matter · Physics 2009-09-29 Yu. V. Pershin , Y. Dubi , M. Di Ventra

We analyze the Markovian dynamics of a quantum system involving the interaction of two quantized fields at finite temperature decay. Utilizing superoperator techniques and applying two non-unitary transformations, we reformulate the…

In this paper we present a method to derive an exact master equation for a bosonic system coupled to a set of other bosonic systems, which plays the role of the reservoir, under the strong coupling regime, i.e., without resorting to either…

Quantum Physics · Physics 2015-06-19 T. B. Batalhão , G. D. de Moraes Neto , M. A. de Ponte , M. H. Y. Moussa

We derive a new perturbative quantum master equation for the reduced density matrix of a system interacting with an environment (with a dense spectrum of energy levels). The total system energy (system plus environment) is constant and…

Statistical Mechanics · Physics 2007-05-23 Massimiliano Esposito , Pierre Gaspard

A quantum analog of friction (understood as a completely positive, Markovian, translation-invariant and phenomenological model of dissipation) is known to be in odds with the detailed balance in the thermodynamic limit. We show that this is…

Quantum Physics · Physics 2018-11-07 Dmitry V. Zhdanov , Denys I. Bondar , Tamar Seideman

We put forth a new class of quantum master equations that correctly reproduce the asymptotic state of an open quantum system beyond the infinitesimally weak system-bath coupling limit. Our method is based on incorporating the knowledge of…

Quantum Physics · Physics 2022-11-10 Tobias Becker , Alexander Schnell , Juzar Thingna

We present explicit expressions for the central piece of a variational method developed by Shi et al. which extends variational wave functions that are efficiently computable on classical computers beyond mean-field to generalized Gaussian…

Quantum Physics · Physics 2021-09-23 Michael P. Kaicher , Simon B. Jäger , Frank K. Wilhelm

It has been argued that the bosonic large-$N$ master field of the IIB matrix model can give rise to an emergent classical spacetime. In a recent paper, we have obtained solutions of a simplified bosonic master-field equation from a related…

High Energy Physics - Theory · Physics 2021-11-01 F. R. Klinkhamer

We present a simple analytical method to solve master equations for finite temperatures and any initial conditions, which consists in the expansion of the density operator into normal modes. These modes and the expansion coefficients are…

Quantum Physics · Physics 2007-05-23 R. Rangel , L. Carvalho

The state matrix $\rho$ for an open quantum system with Markovian evolution obeys a master equation. The master equation evolution can be unraveled into stochastic nonlinear trajectories for a pure state $P$, such that on average $P$…

Quantum Physics · Physics 2009-11-06 H. M. Wiseman , L. Diosi

We derive the Hu-Paz-Zhang master equation for a Brownian particle linearly coupled to a bath of harmonic oscillators on the plane with spatial noncommutativity. The results obtained are exact to all orders in the noncommutative parameter.…

High Energy Physics - Theory · Physics 2009-07-13 Nuno Costa Dias , Joao Nuno Prata

A quantum algorithm to simulate the real time dynamics of two-flavor massive Gross-Neveu model is presented in Schrodinger picture. We implement the simulation on a classic computer by applying the matrix product state representation. The…

High Energy Physics - Theory · Physics 2020-11-17 De-Sheng Li , Hao Wang , Chu Guo , Ming Zhong , Ping-Xing Chen

We address the microscopic derivation of a quantum master equation in Lindblad form for the dynamics of a massive test particle with internal degrees of freedom interacting through collisions with a background ideal gas. When either…

Quantum Physics · Physics 2010-10-27 Andrea Smirne , Bassano Vacchini

The quantum mechanical version of a classical model for studying the orientational degrees of freedom corresponding to a nematic liquid composed of biaxial molecules is presented. The effective degrees of freedom are described by operators…

Condensed Matter · Physics 2009-10-31 Jorge Alfaro , Oscar Cubero , Luis F. Urrutia

Establishing the precise computational boundary between classically tractable fermionic systems and those capable of genuine quantum advantage is a central challenge in quantum simulation. While injecting non-Gaussian ``magic" inputs into…

Quantum Physics · Physics 2026-05-13 Changhun Oh , Michał Oszmaniec , Oliver Reardon-Smith , Zoltán Zimborás

We present exact solutions for the non-equilibrium steady states of a class of dissipative spinless fermionic systems with arbitrary Hamiltonian pairing terms, global charging energy interactions, and uniform single particle loss on every…

Quantum Physics · Physics 2026-05-12 Andrew Lingenfelter , Aashish A. Clerk