Related papers: Thermodynamic Stability of Nanobubbles
Assuming that the electroweak and QCD phase transitions are first order, upon supercooling, bubbles of the new phase appear. These bubbles grow to macroscopic sizes compared to the natural scales associated with the Compton wavelengths of…
Thermodynamical stability of fluid spheres is studied in the presence of a cosmological constant, both in the Newtonian limit, as well as in General Relativity. In all cases, an increase of the cosmological constant tends to stabilize the…
The stability of multi-electron bubbles in liquid helium is investigated theoretically. We find that multi-electron bubbles are unstable against fission whenever the pressure is positive. It is shown that for moving bubbles the Bernoulli…
We present a theoretical model for the experimentally found but counter-intuitive exceptionally long lifetime of surface nanobubbles. We can explain why, under normal experimental conditions, surface nanobubbles are stable for many hours or…
A model for gas nanobubbles is proposed in which their remarkable stability is explained as due to the presence of a qualitatively different form of water covering the nanobubble surface layer which leads to a reduction of the diffusion…
Cavitation, the formation of vapor bubbles in metastable liquids, is highly sensitive to nanoscale surface defects. Using molecular dynamics simulations and classical nucleation theory, we show that pure water confined within defect-free…
Experimental investigations of hydrophobic/water interfaces often return controversial results, possibly due to the unknown role of gas accumulation at the interfaces. Here, during advanced atomic force microscopy of the initial evolution…
Recently-reported data suggest that bubble nucleation on surfaces with nano-sized features (cavities and posts) may occur close to the thermodynamic saturation temperature. However, according to the traditional theory of heterogeneous…
Nanothermodynamics provides the theoretical foundation for understanding stable distributions of statistically independent subsystems inside larger systems. In this review it is emphasized that adapting ideas from nanothermodynamics to…
Quasicrystals whose building blocks are of mesoscopic rather than atomic scale have recently been discovered in several soft-matter systems. Contrary to metallurgic quasicrystals whose source of stability remains a question of great debate…
The stability of multielectron bubbles (MEBs) in liquid helium is investigated using the liquid-drop model for fissioning nuclei. Whereas a critical positive pressure can make the bubble unstable against fissioning, a small negative…
In nanoparticle haloing, charged nanoparticles have been found to enhance the stability of colloidal suspensions by forming a non-adsorbing layer surrounding neutral colloids which induces an electrostatic repulsion between them. However,…
We present experimental investigations of antibubbles. Such an unusual fluid object is a thin spherical air shell surrounding a liquid globule. We explain how to produce them and we study their stability. By overweighting antibubbles with a…
In the study of crystal nucleation via computer simulations, hard spheres are arguably the most extensively explored model system. Nonetheless, even in this simple model system, the complex thermodynamics of crystal nuclei can sometimes…
Experiments show that isochoric (constant-volume) conditions enhance supercooling stability relative to isobaric (constant-pressure) conditions. Here, combining Helmholtz equilibrium thermodynamics with a first-order perturbation…
Theory is presented for the phase stability of mixtures containing nanospheres and non-adsorbing reversible supramolecular polymers. This was made possible by incorporating the depletion thickness and osmotic pressure of reversible…
The global static stability of a Starling Resistor conveying non-Newtonian fluid is considered. The Starling Resistor consists of two rigid circular tubes and axisymmetric collapsible tube mounted between them. Upstream and downstream…
We revisit the classic problem of the stability of drops and jets held by surface tension, while regarding the compressibility of bulk fluids and spatial dimensions as free parameters. By mode analysis, it is shown that there exists a…
In the context of false vacuum decay at zero temperature, it is well known that bubbles expand with uniform proper acceleration. We show that this uniformly accelerating expansion suffers from an instability related to the bubble size. This…
We study surface nanobubbles using molecular dynamics simulation of ternary (gas, liquid, solid) systems of Lennard-Jones fluids. They form for sufficiently low gas solubility in the liquid, i.e., for large relative gas concentration. For…