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The earliest stars to form in the Universe were the first sources of light, heat and metals after the Big Bang. The products of their evolution will have had a profound impact on subsequent generations of stars. Recent studies of primordial…
Li abundances in the bulk of low-mass metal-poor stars are well reproduced by stellar evolution models adopting a constant initial abundance. However, a small number of stars have exceptionally high Li abundances, for which no convincing…
We present the first large sample of accurate iron abundances and temperatures for clusters at redshifts greater than 0.14. We find that the Fe abundance shows little or no evolution out to redshift 0.3. This and the early formation epoch…
We investigate the possible impact of diffusion on the abundance of helium and other primordial elements during formation of the first structures in the early Universe. We consider the primary collapse of a perturbation and subsequent…
We investigate the evolution of the metallicity of the intergalactic medium (IGM) with particular emphasis on its spatial distribution. We propose that metal enrichment occurs as a two step process. First, supernova (SN) explosions eject…
The prevalence of light element enhancement in the most metal-poor stars is potentially an indication that the Milky Way has a metallicity floor for star formation around $\sim$10$^{-3.5}$ Z$_{\odot}$. We propose that this metallicity floor…
As the Universe emerged from its initial hot and dense phase, its chemical composition was extremely simple, being limited to stable H and He isotopes, and traces of Li. The first stars that formed had such initial composition. However,…
The transition between the nearly smooth initial state of the Universe and its clumpy state today occurred during the epoch when the first stars and low-luminosity quasars formed. For Cold Dark Matter cosmologies, the radiation produced by…
We present abundance measurements from 26 emission-line selected galaxies at z~0.6-0.7. By reaching stellar masses as low as 10^8 M_{\sun}, these observations provide the first measurement of the intermediate redshift mass-metallicity (MZ)…
The first stars fundamentally transformed the early Universe through their production of energetic radiation and the first heavy chemical elements. The impact on cosmic evolution sensitively depends on their initial mass function (IMF),…
Using cosmological volume simulations and a custom built sub-grid model for Pop~III star formation, we examine the baseline dust extinction in the first galaxies due to Pop~III metal enrichment in the first billion years of cosmic history.…
A few topics concerning the early chemical evolution of the Milky Way are critically discussed. In particular, it is argued that: 1) Observed abundance patterns of extremely metal poor stars (of Pop. II) do not constrain the mass range of…
We have examined the metal enrichment of the intergalactic medium (IGM) based on a galactic wind model. A galactic wind driven by supernovae brings metallic gas to the IGM but not so far beyond the gravitational potential. The expanding…
The nitrogen and oxygen abundances in the warm ionized gas of low-mass, metal-poor galaxies appear surprisingly homogeneous considering the prevalence of large HII regions, which contain hundreds of massive stars. Of the six galaxies with…
I review the properties of starburst galaxies, compare the properties of the local ones with more distant starburts and examine their role in the metal enrichment of the interstellar medium and the intergalactic-intracluster medium.…
We present abundance measurements of elements O, C, Si and Fe for three gas-rich galaxies at z~5 using observations from the Very Large Telescope (VLT) and the Keck telescope in order to better constrain the early chemical enrichment of…
The formation of the first generations of stars at redshifts z > 15-20 signaled the transition from the simple initial state of the universe to one of increasing complexity. We here review recent progress in understanding the assembly…
We calculate the stellar mass-metallicity relation at five epochs ranging to z~2.3. We quantify evolution in the shape of the mass-metallicity relation as a function of redshift; the mass-metallicity relation flattens at late times. There…
It now becomes possible to perform multiphase studies of the ISM from hot to molecular phases. HI and HII in star--forming gas-rich galaxies seem to exhibit differences in their metal composition in the sense that HII is less enriched in…
A brief review concludes that there is now good overall agreement between theoretical estimates of the energy associated with the production of the observed metal content of the Universe and the observed extragalactic background light. In…