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Hydrogen-rich compounds have been extensively studied both theoretically and experimentally in the quest for novel high-temperature superconductors. Reports on sulfur-hydride attaining metallicity under pressure and exhibiting…

We resolve issues that have plagued reliable prediction of relative phase stability for solid-solutions and compounds. Due to its commercially important phase diagram, we showcase Al-Li system because historically density-functional theory…

Materials Science · Physics 2013-12-25 Aftab Alam , D. D. Johnson

This study presents a computational framework to investigate and predict the complicated multiphase properties of eco-friendly lead-free piezoelectric materials, which are crucial for sustainable technological progress. Although their…

Recent cutting-edge experiments have provided {\it in situ} structure characterization and measurements of the pressure ($P$), density ($\bar{\rho}$) and temperature ($T$) of shock compressed silicon in the 100 GPa range of pressures and…

Materials Science · Physics 2024-12-12 M. W. C. Dharma-wardana , Dennis D. Klug , Hannah Poole , G. Gregori

Understanding the dispersion process of supported catalysts is crucial for synthesizing atomic-level dispersed catalysts and precisely manipulating their chemical state. However, the underlying dispersion mechanism remains elusive due to…

Group I/II materials exhibit unexpected structural phase transitions at high pressures, providing potential insight into the origins of elemental superconductivity. We present here a computational study of elemental barium and binary…

Materials Science · Physics 2012-07-16 Joshua A. Taillon , William W. Tipton , Richard G. Hennig

There currently exist no quantitative methods to determine the appropriate conditions for solid-state synthesis. This not only hinders the experimental realization of novel materials but also complicates the interpretation and understanding…

The correct description of nondynamic correlation by electronic structure methods not belonging to the multireference family is a challenging issue. The transition of $D_{2h}$ to $D_{4h}$ symmetry in H$_4$ molecule is among the most simple…

Chemical Physics · Physics 2017-11-16 Eloy Ramos-Cordoba , Xabier Lopez , Mario Piris , Eduard Matito

Using density functional theory (DFT) within the local density approximation (LDA), we calculate the physical and electronic properties of PbTiO3 (PTO) and a series of hypothetical compounds PbTiO3-xSx x = 0.2, 0.25, 0.33, 0.5, 1, 2, and 3…

Perovskite-type iron oxides with Fe4+ ions have attracted much attention for their versatile helimagnetic phases. While the introduction of a layered A-site ordered structure to AFeO3 with Fe4+ ions potentially lead to novel helimagnetic…

Materials Science · Physics 2025-03-17 Masaho Onose , Hidefumi Takahashi , Hajime Sagayama , Yuichi Yamasaki , Shintaro Ishiwata

In this paper we analyze a PDE system modelling (non-isothermal) phase transitions and damage phenomena in thermoviscoelastic materials. The model is thermodynamically consistent: in particular, no {\em small perturbation assumption} is…

Analysis of PDEs · Mathematics 2014-11-20 Elisabetta Rocca , Riccarda Rossi

Melting is a high temperature process that requires extensive sampling of configuration space, thus making melting temperature prediction computationally very expensive and challenging. Over the past few years, I have built two methods to…

Materials Science · Physics 2022-04-12 Qi-Jun Hong

The conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT) is one of the most researched materials. The 1980s bipolaron model remains the dominant interpretation of the electronic structure of PEDOT. Recent theoretical studies have…

Materials Science · Physics 2024-05-01 Ben Craig , Peter Townsend , Carlos Ponce de Leon , Chris Kriton-Skylaris , Denis Kramer

Structural phase transitions are governed by the underlying atomic transformation mechanism; martensitic transformations can be separated into strain and shuffle components. A systematic pathway generation and sorting algorithm is presented…

Materials Science · Physics 2008-07-24 D. R. Trinkle , D. M. Hatch , H. T. Stokes , R. G. Hennig , R. C. Albers

As an aid to the development of hydrogen separation membranes, we predict the temperature dependent phase diagrams using first principles calculations combined with thermodynamic principles. Our method models the phase diagram without…

Materials Science · Physics 2014-08-07 William Paul Huhn , Michael Widom , Michael C. Gao

The high-pressure melting diagram of iron is a vital ingredient for the geodynamic modeling of planetary interiors. Nonetheless, available data for molten iron show an alarming discrepancy. Herein, we propose an efficient one-phase approach…

Materials Science · Physics 2022-09-20 Tran Dinh Cuong , Nguyen Quang Hoc , Nguyen Duc Trung , Nguyen Thi Thao , Anh D. Phan

Recent experiments have shown that sodium, a prototype simple metal at ambient conditions, exhibits unexpected complexity under high pressure. One of the most puzzling phenomena in the behaviour of dense sodium is the pressure-induced drop…

Materials Science · Physics 2015-05-30 Hagai Eshet , Rustam Z. Khaliullin , Thomas D. Kühne , Jörg Behler , Michele Parrinello

X-rays diffraction pictures time dependence of deformed alloy Pd-Ta being charged with hydrogen has been shown to be possibly caused by multi-pits character of energetic relief in the states space. Phenomenological model representing alloy…

This paper presents a modeling effort to explore the underlying physics of temperature evolution during additive friction stir deposition (AFSD) by a human-AI teaming approach. AFSD is an emerging solid-state additive manufacturing…

Machine Learning · Computer Science 2025-02-11 Tony Shi , Mason Ma , Jiajie Wu , Chase Post , Elijah Charles , Tony Schmitz

We study processes at the transition region between hot (rare) and cold (dense) plasma in the collisionless regime. We use a 3-dimensional electromagnetic particle-in-cell (3-D PIC) relativistic code. Motivated by the transition region in…

Solar and Stellar Astrophysics · Physics 2017-09-25 Marian Karlicky , Frantisek Karlicky
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